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Articles 61 - 90 of 90
Full-Text Articles in Engineering
Light-Activated Photocurrent Degradation And Self-Healing In Perovskite Solar Cells, Wanyi Nie, Jean-Christophe Blancon, Amanda J. Neukirch, Kannatassen Appavoo, Hsinhan Tsai, Manish Chhowalla, Muhammad A. Alam, Matthew Y. Sfeir, Claudine Katan, Jacky Even, Sergei Tretiak, Jared J. Crochet, Gautam Gupta, Aditya D. Mohite
Light-Activated Photocurrent Degradation And Self-Healing In Perovskite Solar Cells, Wanyi Nie, Jean-Christophe Blancon, Amanda J. Neukirch, Kannatassen Appavoo, Hsinhan Tsai, Manish Chhowalla, Muhammad A. Alam, Matthew Y. Sfeir, Claudine Katan, Jacky Even, Sergei Tretiak, Jared J. Crochet, Gautam Gupta, Aditya D. Mohite
Publications and Research
Solution-processed organometallic perovskite solar cells have emerged as one of the most promising thin-film photovoltaic technology. However, a key challenge is their lack of stability over prolonged solar irradiation. Few studies have investigated the effect of light soaking on hybrid perovskites and have attributed the degradation in the optoelectronic properties to photochemical or field-assisted ion migration. Here we show that the slow photocurrent degradation in thin-film photovoltaic devices is due to the formation of light-activated meta-stable deep-level trap states. However, the devices can self-heal completely by resting them in the dark for <1 min or the degradation can be completely prevented by operating the devices at 0°C. We investigate several physical mechanisms to explain the microscopic origin for the formation of these trap states, among which the creation of small polaronic states involving localized cooperative lattice strain and molecular orientations emerges as a credible microscopic mechanism requiring further detailed studies.
Historical Trends In Mean And Extreme Runoff And Streamflow Based On Observations And Climate Models, Behzad Asadieh, Nir Y. Krakauer, Balázs M. Fekete
Historical Trends In Mean And Extreme Runoff And Streamflow Based On Observations And Climate Models, Behzad Asadieh, Nir Y. Krakauer, Balázs M. Fekete
Publications and Research
To understand changes in global mean and extreme streamflow volumes over recent decades, we statistically analyzed runoff and streamflow simulated by the WBM-plus hydrological model using either observational-based meteorological inputs from WATCH Forcing Data (WFD), or bias-corrected inputs from five global climate models (GCMs) provided by the Inter-Sectoral Impact Model Intercomparison Project (ISI-MIP). Results show that the bias-corrected GCM inputs yield very good agreement with the observation-based inputs in average magnitude of runoff and streamflow. On global average, the observation-based simulated mean runoff and streamflow both decreased about 1.3% from 1971 to 2001. However, GCM-based simulations yield increasing trends over …
Satellite Retrievals Of Karenia Brevis Harmful Algal Blooms In The West Florida Shelf Using Neural Networks And Comparisons With Other Techniques, Ahmed El-Habashi, Ioannis Ioannou, Michelle Tomlinson, Richard P. Stumpf, Sam Ahmed
Satellite Retrievals Of Karenia Brevis Harmful Algal Blooms In The West Florida Shelf Using Neural Networks And Comparisons With Other Techniques, Ahmed El-Habashi, Ioannis Ioannou, Michelle Tomlinson, Richard P. Stumpf, Sam Ahmed
Publications and Research
We describe the application of a Neural Network (NN) previously developed by us, to the detection and tracking, of Karenia brevis Harmful Algal Blooms (KB HABs) that plague the coasts of the West Florida Shelf (WFS) using Visible Infrared Imaging Radiometer Suite (VIIRS) satellite observations. Previous approaches for the detection of KB HABs in the WFS primarily used observations from the Moderate Resolution Imaging Spectroradiometer Aqua (MODIS-A) satellite. They depended on the remote sensing reflectance signal at the 678 nm chlorophyll fluorescence band (Rrs678) needed for both the normalized fluorescence height (nFLH) and Red Band Difference algorithms (RBD) currently used. …
Estimating The Probability Of Vegetation To Be Groundwater Dependent Based On The Evaluation Of Tree Models, Isabel C. Pérez Hoyos, Nir Y. Krakauer, Reza Khanbilvardi
Estimating The Probability Of Vegetation To Be Groundwater Dependent Based On The Evaluation Of Tree Models, Isabel C. Pérez Hoyos, Nir Y. Krakauer, Reza Khanbilvardi
Publications and Research
Groundwater Dependent Ecosystems (GDEs) are increasingly threatened by humans’ rising demand for water resources. Consequently, it is imperative to identify the location of GDEs to protect them. This paper develops a methodology to identify the probability of an ecosystem to be groundwater dependent. Probabilities are obtained by modeling the relationship between the known locations of GDEs and factors influencing groundwater dependence, namely water table depth and climatic aridity index. Probabilities are derived for the state of Nevada, USA, using modeled water table depth and aridity index values obtained from the Global Aridity database. The model selected results from the performance …
Ensemble Forecasts: Probabilistic Seasonal Forecasts Based On A Model Ensemble, Hannah Aizenman, Michael D. Grossberg, Nir Y. Krakauer, Irina Gladkova
Ensemble Forecasts: Probabilistic Seasonal Forecasts Based On A Model Ensemble, Hannah Aizenman, Michael D. Grossberg, Nir Y. Krakauer, Irina Gladkova
Publications and Research
Ensembles of general circulation model (GCM) integrations yield predictions for meteorological conditions in future months. Such predictions have implicit uncertainty resulting from model structure, parameter uncertainty, and fundamental randomness in the physical system. In this work, we build probabilistic models for long-term forecasts that include the GCM ensemble values as inputs but incorporate statistical correction of GCM biases and different treatments of uncertainty. Specifically, we present, and evaluate against observations, several versions of a probabilistic forecast for gridded air temperature 1 month ahead based on ensemble members of the National Centers for Environmental Prediction (NCEP) Climate Forecast System Version 2 …
A Review Of Advances In The Identification And Characterization Of Groundwater Dependent Ecosystems Using Geospatial Technologies, Isabel C. Pérez Hoyos, Nir Y. Krakauer, Reza Khanbilvardi, Roy A. Armstrong
A Review Of Advances In The Identification And Characterization Of Groundwater Dependent Ecosystems Using Geospatial Technologies, Isabel C. Pérez Hoyos, Nir Y. Krakauer, Reza Khanbilvardi, Roy A. Armstrong
Publications and Research
Groundwater Dependent Ecosystem (GDE) protection is increasingly being recognized as essential for the sustainable management and allocation of water resources. GDE services are crucial for human well-being and for a variety of flora and fauna. However, the conservation of GDEs is only possible if knowledge about their location and extent is available. Several studies have focused on the identification of GDEs at specific locations using ground-based measurements. However, recent progress in remote sensing technologies and their integration with Geographic Information Systems (GIS) has provided alternative ways to map GDEs at a much larger spatial extent. This paper presents a review …
Sefo: A Package For Generating Probabilistic Forecasts From Nmme Predictive Ensembles, Nir Krakauer
Sefo: A Package For Generating Probabilistic Forecasts From Nmme Predictive Ensembles, Nir Krakauer
Publications and Research
Long-range weather forecasts based on output from ensembles of computer simulations are attracting increasing interest. A variety of methods have been proposed to convert the ensemble outputs to calibrated probabilistic forecasts. The package presented here (SeFo, for Seasonal Forecasting) implements a number of methods for producing forecasts of monthly surface air temperature anomalies up to 9 months in advance using output from the North American Multi-Model Ensemble (NMME). The package contains modules for downloading and reading past observations and ensemble output; producing forecast probability distributions; and verifying and calibrating a user-determined subset of methods using arbitrary past periods. By changing …
Design And Analysis Of A Single-Camera Omnistereo Sensor For Quadrotor Micro Aerial Vehicles (Mavs), Carlos Jaramillo, Roberto G. Valenti, Ling Guo, Jizhong Xiao
Design And Analysis Of A Single-Camera Omnistereo Sensor For Quadrotor Micro Aerial Vehicles (Mavs), Carlos Jaramillo, Roberto G. Valenti, Ling Guo, Jizhong Xiao
Publications and Research
We describe the design and 3D sensing performance of an omnidirectional stereo (omnistereo) vision system applied to Micro Aerial Vehicles (MAVs). The proposed omnistereo sensor employs a monocular camera that is co-axially aligned with a pair of hyperboloidal mirrors (a vertically-folded catadioptric configuration). We show that this arrangement provides a compact solution for omnidirectional 3D perception while mounted on top of propeller-based MAVs (not capable of large payloads). The theoretical single viewpoint (SVP) constraint helps us derive analytical solutions for the sensor’s projective geometry and generate SVP-compliant panoramic images to compute 3D information from stereo correspondences (in a truly synchronous …
Band Gap Engineering Of N-Alloyed Ga2o3 Thin Films, Dongyu Song, Li Li, Bingsheng Li, Yu Sui, Aidong Shen
Band Gap Engineering Of N-Alloyed Ga2o3 Thin Films, Dongyu Song, Li Li, Bingsheng Li, Yu Sui, Aidong Shen
Publications and Research
The authors report the tuning of band gap of GaON ternary alloy in a wide range of 2.75 eV. The samples were prepared by a two-step nitridation method. First, the samples were deposited on 2-inch fused silica substrates by megnetron sputtering with NH3 and Ar gas for 60 minutes. Then they were annealed in NH3 ambience at different temperatures. The optical band gap energies are calculated from transmittance measurements. With the increase of nitridation temperature, the band gap gradually decreases from 4.8 eV to 2.05 eV. X-ray diffraction results indicate that as-deposited amorphous samples can crystallize into monoclinic and hexagonal …
Evaluation Of Viirs Land Surface Temperature Using Crest-Safe Air, Snow Surface, And Soil Temperature Data, Carlos L. Pérez Díaz, Tarendra Lakhankar, Peter Romanov, Reza Khanbilvardi, Yunyue Yu
Evaluation Of Viirs Land Surface Temperature Using Crest-Safe Air, Snow Surface, And Soil Temperature Data, Carlos L. Pérez Díaz, Tarendra Lakhankar, Peter Romanov, Reza Khanbilvardi, Yunyue Yu
Publications and Research
In this study, the Visible Infrared Imager Radiometer Suite (VIIRS) Land Surface Temperature (LST) Environmental Data Record (EDR) was evaluated against snow surface (T-skin) and near-surface air temperature (T-air) ground observations recorded at the Cooperative Remote Sensing Science and Technology Center—Snow Analysis and Field Experiment (CREST-SAFE), located in Caribou, ME, USA during the winters of 2013 and 2014. The satellite LST corroboration of snow-covered areas is imperative because high-latitude regions are often physically inaccessible and there is a need to complement the data from the existing meteorological station networks. T-skin is not a standard meteorological parameter commonly observed at synoptic …
Evaluation Of The Snow Thermal Model (Sntherm) Through Continuous In Situ Observations Of Snow’S Physical Properties At The Crest-Safe Field Experiment, José Alberto Infante Corona, Jonathan Muñoz, Tarendra Lakhankar, Peter Romanov, Reza Khanbilvardi
Evaluation Of The Snow Thermal Model (Sntherm) Through Continuous In Situ Observations Of Snow’S Physical Properties At The Crest-Safe Field Experiment, José Alberto Infante Corona, Jonathan Muñoz, Tarendra Lakhankar, Peter Romanov, Reza Khanbilvardi
Publications and Research
Snowpack properties like temperature or density are the result of a complex energy and mass balance process in the snowpack that varies temporally and spatially. The Snow Thermal Model (SNTHERM) is a 1-dimensional model, energy and mass balance-driven, that simulates these properties. This article analyzes the simulated snowpack properties using SNTHERM forced with two datasets, namely measured meteorological data at the Cooperative Remote Sensing Science and Technology-Snow Analysis and Field Experiment (CREST-SAFE) site and the National Land Data Assimilation System (NLDAS). The study area is located on the premises of Caribou Municipal Airport at Caribou (ME, USA). The model evaluation …
Molecular Helices As Electron Acceptors In High-Performance Bulk Heterojunction Solar Cells, Yu Zhong, M. Tuan Trinh, Rongsheng Chen, Geoffrey E. Purdum, Petr P. Khlyabich, Melda Sezen, Seokjoon Oh, Haiming Zhu, Brandon Fowler, Boyuan Zhang, Wei Wang, Chang-Yong Nam, Matthew Y. Sfeir, Charles T. Black, Michael L. Steigerwald, Yueh-Lin Loo, Fay Ng, X.-Y. Zhu, Colin Nuckolls
Molecular Helices As Electron Acceptors In High-Performance Bulk Heterojunction Solar Cells, Yu Zhong, M. Tuan Trinh, Rongsheng Chen, Geoffrey E. Purdum, Petr P. Khlyabich, Melda Sezen, Seokjoon Oh, Haiming Zhu, Brandon Fowler, Boyuan Zhang, Wei Wang, Chang-Yong Nam, Matthew Y. Sfeir, Charles T. Black, Michael L. Steigerwald, Yueh-Lin Loo, Fay Ng, X.-Y. Zhu, Colin Nuckolls
Publications and Research
Despite numerous organic semiconducting materials synthesized for organic photovoltaics in the past decade, fullerenes are widely used as electron acceptors in highly efficient bulk-heterojunction solar cells. None of the non-fullerene bulk heterojunction solar cells have achieved efficiencies as high as fullerene-based solar cells. Design principles for fullerene-free acceptors remain unclear in the field. Here we report examples of helical molecular semiconductors as electron acceptors that are on par with fullerene derivatives in efficient solar cells. We achieved an 8.3% power conversion efficiency in a solar cell, which is a record high for non-fullerene bulk heterojunctions. Femtosecond transient absorption spectroscopy revealed …
Mapping Regional Inundation With Spaceborne L-Band Sar, Bruce Chapman, Kyle Macdonald, Masanobu Shimada, Ake Rosenqvist, Ronny Schroeder, Laura Hess
Mapping Regional Inundation With Spaceborne L-Band Sar, Bruce Chapman, Kyle Macdonald, Masanobu Shimada, Ake Rosenqvist, Ronny Schroeder, Laura Hess
Publications and Research
Shortly after the launch of ALOS PALSAR L-band SAR by the Japan Space Exploration Agency (JAXA), a program to develop an Earth Science Data Record (ESDR) for inundated wetlands was funded by NASA. Using established methodologies, extensive multi-temporal L-band ALOS ScanSAR data acquired bi-monthly by the PALSAR instrument onboard ALOS were used to classify the inundation state for South America for delivery as a component of this Inundated Wetlands ESDR (IW-ESDR) and in collaboration with JAXA’s ALOS Kyoto and Carbon Initiative science programme. We describe these methodologies and the final classification of the inundation state, then compared this with results …
Probabilistic Precipitation Estimation With A Satellite Product, Nir Y. Krakauer, Soni M. Pradhanang, Jeeban Panthi, Tarendra Lakhankar, Ajay K. Jha
Probabilistic Precipitation Estimation With A Satellite Product, Nir Y. Krakauer, Soni M. Pradhanang, Jeeban Panthi, Tarendra Lakhankar, Ajay K. Jha
Publications and Research
Satellite-based precipitation products have been shown to represent precipitation well over Nepal at monthly resolution, compared to ground-based stations. Here, we extend our analysis to the daily and subdaily timescales, which are relevant for mapping the hazards caused by storms as well as drought. We compared the Tropical Rainfall Measuring Mission (TRMM) Multi-satellite Precipitation Analysis (TMPA) 3B42RT product with individual stations and with the gridded APHRODITE product to evaluate its ability to retrieve different precipitation intensities. We find that 3B42RT, which is freely available in near real time, has reasonable correspondence with ground-based precipitation products on a daily timescale; rank …
Structural Patterns At All Scales In A Nonmetallic Chiral Au_133(Sr)_52 Nanoparticle, Chenjie Zeng, Yuxiang Chen, Kristin Kirschbaum, Kannatassen Appavoo, Matthew Y. Sfeir, Rongchao Jin
Structural Patterns At All Scales In A Nonmetallic Chiral Au_133(Sr)_52 Nanoparticle, Chenjie Zeng, Yuxiang Chen, Kristin Kirschbaum, Kannatassen Appavoo, Matthew Y. Sfeir, Rongchao Jin
Publications and Research
Structural ordering is widely present in molecules and materials. However, the organization of molecules on the curved surface of nanoparticles is still the least understood owing to the major limitations of the current surface characterization tools. By the merits of x-ray crystallography, we reveal the structural ordering at all scales in a super robust 133–gold atom nanoparticle protected by 52 thiolate ligands, which is manifested in self-assembled hierarchical patterns starting from the metal core to the interfacial –S–Au–S– ladder-like helical “stripes” and further to the “swirls” of carbon tails. These complex surface patterns have not been observed in the smaller …
Spatial And Temporal Variability Of Rainfall In The Gandaki River Basin Of Nepal Himalaya, Jeeban Panthi, Piyush Dahal, Madan Lall Shrestha, Suman Aryal, Nir Y. Krakauer, Soni M. Pradhanang, Tarendra Lakhankar, Ajay K. Jha, Mohan Sharma, Ramchandra Karki
Spatial And Temporal Variability Of Rainfall In The Gandaki River Basin Of Nepal Himalaya, Jeeban Panthi, Piyush Dahal, Madan Lall Shrestha, Suman Aryal, Nir Y. Krakauer, Soni M. Pradhanang, Tarendra Lakhankar, Ajay K. Jha, Mohan Sharma, Ramchandra Karki
Publications and Research
Landslides, floods, and droughts are recurring natural disasters in Nepal related to too much or too little water. The summer monsoon contributes more than 80% of annual rainfall, and rainfall spatial and inter-annual variation is very high. The Gandaki River, one of the three major rivers of Nepal and one of the major tributaries of the Ganges River, covers all agro-ecological zones in the central part of Nepal. Time series tests were applied for different agro-ecological zones of the Gandaki River Basin (GRB) for rainfall trends of four seasons (pre-monsoon, monsoon, post-monsoon and winter) from 1981 to 2012. The non-parametric …
Framing The Question, "Who Governs The Internet?", Robert J. Domanski
Framing The Question, "Who Governs The Internet?", Robert J. Domanski
Publications and Research
There remains a widespread perception among both the public and elements of academia that the Internet is “ungovernable”. However, this idea, as well as the notion that the Internet has become some type of cyber-libertarian utopia, is wholly inaccurate. Governments may certainly encounter tremendous difficulty in attempting to regulate the Internet, but numerous types of authority have nevertheless become pervasive. So who, then, governs the Internet? This book will contend that the Internet is, in fact, being governed, that it is being governed by specific and identifiable networks of policy actors, and that an argument can be made as to …
Performance Analysis Of A Hybrid Raman Optical Parametric Amplifier In The O- And E-Bands For Cwdm Pons, Sasanthi Peiris, Nicolas Madamopoulos, Neophytos A. Antoniades, Dwight Richards, Roger Dorsinville
Performance Analysis Of A Hybrid Raman Optical Parametric Amplifier In The O- And E-Bands For Cwdm Pons, Sasanthi Peiris, Nicolas Madamopoulos, Neophytos A. Antoniades, Dwight Richards, Roger Dorsinville
Publications and Research
We describe a hybrid Raman-optical parametric amplifier (HROPA) operating at the O- and E-bands and designed for coarse wavelength division multiplexed (CWDM) passive optical networks (PONs). We present the mathematical model and simulation results for the optimization of this HROPA design. Our analysis shows that separating the two amplification processes allows for optimization of each one separately, e.g., proper selection of pump optical powers and wavelengths to achieve maximum gain bandwidth and low gain ripple. Furthermore, we show that the proper design of optical filters incorporated in the HROPA architecture can suppress idlers generated during the OPA process, as well …
Economic Growth Assumptions In Climate And Energy Policy, Nir Y. Krakauer
Economic Growth Assumptions In Climate And Energy Policy, Nir Y. Krakauer
Publications and Research
The assumption that the economic growth seen in recent decades will continue has dominated the discussion of future greenhouse gas emissions and the mitigation of and adaptation to climate change. Given that long-term economic growth is uncertain, the impacts of a wide range of growth trajectories should be considered. In particular, slower economic growth would imply that future generations will be relatively less able to invest in emissions controls or adapt to the detrimental impacts of climate change. Taking into consideration the possibility of economic slowdown therefore heightens the urgency of reducing greenhouse gas emissions now by moving to renewable …
Assessing The Performance Of A Northern Gulf Of Mexico Tidal Model Using Satellite Imagery, Stephen C. Medeiros, Scott C. Hagen, Naira Chaouch, Jesse Feyen, Marouane Temimi, John F. Weishampel, Yuji Funakoshi, Reza Khanbilvardi
Assessing The Performance Of A Northern Gulf Of Mexico Tidal Model Using Satellite Imagery, Stephen C. Medeiros, Scott C. Hagen, Naira Chaouch, Jesse Feyen, Marouane Temimi, John F. Weishampel, Yuji Funakoshi, Reza Khanbilvardi
Publications and Research
Tidal harmonic analysis simulations along with simulations spanning four specific historical time periods in 2003 and 2004 were conducted to test the performance of a northern Gulf of Mexico tidal model. A recently developed method for detecting inundated areas based on integrated remotely sensed data (i.e., Radarsat-1, aerial imagery, LiDAR, Landsat 7 ETM+) was applied to assess the performance of the tidal model. The analysis demonstrates the applicability of the method and its agreement with traditional performance assessment techniques such as harmonic resynthesis and water level time series analysis. Based on the flooded/non-flooded coastal areas estimated by the integrated remotely …
Development Of A Ground Based Remote Sensing Approach For Direct Evaluation Of Aerosol-Cloud Interaction, Bomidi Lakshmi Madhavan, Yuzhe He, Yonghua Wu, Barry Gross, Fred Moshary, Samir Ahmed
Development Of A Ground Based Remote Sensing Approach For Direct Evaluation Of Aerosol-Cloud Interaction, Bomidi Lakshmi Madhavan, Yuzhe He, Yonghua Wu, Barry Gross, Fred Moshary, Samir Ahmed
Publications and Research
The possible interaction and modification of cloud properties due to aerosols is one of the most poorly understood mechanisms within climate studies, resulting in the most significant uncertainty as regards radiation budgeting. In this study, we explore direct ground based remote sensing methods to assess the Aerosol-Cloud Indirect Effect directly, as space-borne retrievals are not directly suitable for simultaneous aerosol/cloud retrievals. To illustrate some of these difficulties, a statistical assessment of existing multispectral imagers on geostationary (e.g., GOES)/Moderate Resolution Imaging Spectroradiometer (MODIS) satellite retrievals of the Cloud Droplet Effective Radius (Reff) showed significant biases especially at larger solar zenith angles, …
Potential Significance Of Photoexcited No2 On Global Air Quality With The Nmmb/Bsc Chemical Transport Model, O. Jorba, D. Dabdub, Christopher S. Blaszczak-Boxe, C. Pérez, Z. Janjic, J. M. Baldasano, M. Spada, A. Badia, M. Gonçalves
Potential Significance Of Photoexcited No2 On Global Air Quality With The Nmmb/Bsc Chemical Transport Model, O. Jorba, D. Dabdub, Christopher S. Blaszczak-Boxe, C. Pérez, Z. Janjic, J. M. Baldasano, M. Spada, A. Badia, M. Gonçalves
Publications and Research
Atmospheric chemists have recently focused on the relevance of the NO2* + H2O → OH + HONO reaction to local air quality. This chemistry has been considered not relevant for the troposphere from known reaction rates until nowadays. New experiments suggested a rate constant of 1.7 × 10−13 cm3 molecule−1 s−1, which is an order of magnitude faster than the previously estimated upper limit of 1.2 × 10−14 cm3 molecule−1 s−1, determined by Crowley and Carl (1997). Using the new global model, NMMB/BSC Chemical Transport Model (NMMB/BSC-CTM), simulations are presented that assess the potential significance of this chemistry on global …
Validation Of Noaa-Interactive Multisensor Snow And Ice Mapping System (Ims) By Comparison With Ground-Based Measurements Over Continental United States, Christine Chen, Tarendra Lakhankar, Peter Romanov, Sean Helfrich, Al Powell, Reza Khanbilvardi
Validation Of Noaa-Interactive Multisensor Snow And Ice Mapping System (Ims) By Comparison With Ground-Based Measurements Over Continental United States, Christine Chen, Tarendra Lakhankar, Peter Romanov, Sean Helfrich, Al Powell, Reza Khanbilvardi
Publications and Research
In this study, daily maps of snow cover distribution and sea ice extent produced by NOAA’s interactive multisensor snow and ice mapping system (IMS) were validated using in situ snow depth data from observing stations obtained from NOAA’s National Climatic Data Center (NCDC) for calendar years 2006 to 2010. IMS provides daily maps of snow and sea ice extent within the Northern Hemisphere using data from combination of geostationary and polar orbiting satellites in visible, infrared and microwave spectrums. Statistical correspondence between the IMS and in situ point measurements has been evaluated assuming that ground measurements are discrete and continuously …
Aligned Layers Of Silver Nano-Fibers, Andrii B. Golovin, Jeremy Stromer, Liubov Kreminska
Aligned Layers Of Silver Nano-Fibers, Andrii B. Golovin, Jeremy Stromer, Liubov Kreminska
Publications and Research
We describe a new dichroic polarizers made by ordering silver nano-fibers to aligned layers. The aligned layers consist of nano-fibers and self-assembled molecular aggregates of lyotropic liquid crystals. Unidirectional alignment of the layers is achieved by means of mechanical shearing. Aligned layers of silver nano-fibers are partially transparent to a linearly polarized electromagnetic radiation. The unidirectional alignment and density of the silver nano-fibers determine degree of polarization of transmitted light. The aligned layers of silver nano-fibers might be used in optics, microwave applications, and organic electronics.
Fabrication Of Size-Tunable Metallic Nanoparticles Using Plasmid Dna As A Biomolecular Reactor, Jacopo Samson, Irene Piscopo, Alex Yampolski, Patrick Nahirney, Andrea Parpas, Amit Aggarwal, Raihan Saleh, Charles Michael Drain
Fabrication Of Size-Tunable Metallic Nanoparticles Using Plasmid Dna As A Biomolecular Reactor, Jacopo Samson, Irene Piscopo, Alex Yampolski, Patrick Nahirney, Andrea Parpas, Amit Aggarwal, Raihan Saleh, Charles Michael Drain
Publications and Research
Plasmid DNA can be used as a template to yield gold, palladium, silver, and chromium nanoparticles of different sizes based on variations in incubation time at 70 °C with gold phosphine complexes, with the acetates of silver or palladium, or chromium acetylacetonate. The employment of mild synthetic conditions, minimal procedural steps, and aqueous solvents makes this method environmentally greener and ensures general feasibility. The use of plasmids exploits the capabilities of the biotechnology industry as a source of nanoreactor materials.
Dissemination Of Geological Information In Avoiding Geotechnical Risks Associated With Tunnel Construction: Lessons Learned From Deep Voids In Marble In Lower Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Leah Scott
Dissemination Of Geological Information In Avoiding Geotechnical Risks Associated With Tunnel Construction: Lessons Learned From Deep Voids In Marble In Lower Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Leah Scott
Publications and Research
Test boring associated with the recently accomplished City Water Tunnel # 3 in Manhattan, New York City revealed moderately to highly weathered marble with insoluble silicate residues composed mostly of phlogopite, chlorite, and tremolite. Apparent control on the weatherability of the marble was in response to original mineral constituents dominating this lithology. Encountered marble samples ranged between pure calcitic to mixed dolomitic/siliceous types. Fresh marble samples collected from adjacent boring locations revealed characteristic geochemical data: Lime (25-45%), Silica (4-7%), Alumina (1-3%), MgO (5-20%), and LOI (35-42%); compressive strength of unweathered marble varied between 2000-3000 Kg/cm2. Relict foliations with …
Sensitivity Analysis Of B-Factor In Microwave Emission Model For Soil Moisture Retrieval: A Case Study For Smap Mission, Dugwon Seo, Tarendra Lakhankar, Reza Khanbilvardi
Sensitivity Analysis Of B-Factor In Microwave Emission Model For Soil Moisture Retrieval: A Case Study For Smap Mission, Dugwon Seo, Tarendra Lakhankar, Reza Khanbilvardi
Publications and Research
Sensitivity analysis is critically needed to better understand the microwave emission model for soil moisture retrieval using passive microwave remote sensing data. The vegetation b-factor along with vegetation water content and surface characteristics has significant impact in model prediction. This study evaluates the sensitivity of the b-factor, which is function of vegetation type. The analysis is carried out using Passive and Active L and S-band airborne sensor (PALS) and measured field soil moisture from Southern Great Plains experiment (SGP99). The results show that the relative sensitivity of the b-factor is 86% in wet soil condition and 88% in high vegetated …
Validation Of Tropospheric Emission Spectrometer (Tes) Nadir Ozone Profiles Using Ozonesonde Measurements, Ray Nassar, Jennifer A. Logan, Helen M. Worden, Inna A. Megretskaia, Kevin W. Bowman, Gregory B. Osterman, Anne M. Thompson, David W. Tarasick, Shermane Austin, Hans Claude, Manvendra K. Dubey, Wayne K. Hocking, Bryan J. Johnson, Everette Joseph, John Merrill, Gary A. Morris, Mike Newchurch, Samuel J. Oltmans, Françoise Posny, F. J. Schmidlin, Holger Vömel, David N. Whiteman, Jacquelyn C. Witte
Validation Of Tropospheric Emission Spectrometer (Tes) Nadir Ozone Profiles Using Ozonesonde Measurements, Ray Nassar, Jennifer A. Logan, Helen M. Worden, Inna A. Megretskaia, Kevin W. Bowman, Gregory B. Osterman, Anne M. Thompson, David W. Tarasick, Shermane Austin, Hans Claude, Manvendra K. Dubey, Wayne K. Hocking, Bryan J. Johnson, Everette Joseph, John Merrill, Gary A. Morris, Mike Newchurch, Samuel J. Oltmans, Françoise Posny, F. J. Schmidlin, Holger Vömel, David N. Whiteman, Jacquelyn C. Witte
Publications and Research
We compare Tropospheric Emission Spectrometer (TES) version 2 (V002) nadir ozone profiles with ozonesonde profiles from the Intercontinental Chemical Transport Experiment Ozonesonde Network Study, the World Ozone and Ultraviolet Data Center, the Global Monitoring Division of the Earth System Research Laboratory, and the Southern Hemisphere Additional Ozonesonde archives. Approximately 1600 coincidences spanning 72.5°S–80.3°N from October 2004 to October 2006 are found. The TES averaging kernel and constraint are applied to the ozonesonde data to account for the TES measurement sensitivity and vertical resolution. TES sonde differences are examined in six latitude zones after excluding profiles with thick high clouds. Values …
Tunnel Geology As Seen By Geologists: Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Alan R. Slaughter, Belal A. Sayeed, Dorean J. Flores, Mario Jo-Ramirez
Tunnel Geology As Seen By Geologists: Manhattan, New York City, Nazrul I. Khandaker, Stanley Schleifer, Masud Ahmed, Alan R. Slaughter, Belal A. Sayeed, Dorean J. Flores, Mario Jo-Ramirez
Publications and Research
Current exploratory boring operations in and around Manhattan, New York City are providing geologists and geotechnical engineers with a plethora of new and interesting geological information, which has not been previously reported. The rocks encountered, mostly medium to high-grade metamorphic rocks, with both mafic and felsic intrusives, are highly variable in competency and mechanical durability. One of the most frequently encountered rock types is a garnetiferous-muscovite-biotite schist which grades into schistose gneiss and displays a wide variety of structural, compositional, and textural attributes. Metamorphic minerals showing the variable degree of metamorphism include graphite, talc, garnet, kyanite, tourmaline, emory, and occasionally …
Novel Carbon-Carbon Bond Oxidative Cleavage Of Hexabenzyl-Hexaazaisowurtzitane By N-Buono And (Nh4)2ce(No3)6, Xiao-Pei Guan, Hong Yan, Jian-Guang Sun, Yong-Zhong Yu
Novel Carbon-Carbon Bond Oxidative Cleavage Of Hexabenzyl-Hexaazaisowurtzitane By N-Buono And (Nh4)2ce(No3)6, Xiao-Pei Guan, Hong Yan, Jian-Guang Sun, Yong-Zhong Yu
Publications and Research
Treatment of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo-[5.5.0.05,9.03,11]dodecane with n-butyl nitrite or ammonium cerium nitrate results in novel C(1)-C(7) oxidative cleavage to give 1,3,4,5,7,8-hexabenzyl-cis-cisoid-cis-hexahydro-1H,5H-diimidazolinium[4,5-b:4′,5′-e]pyrazine dinitrate.