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Predictive Peridynamic 3d Models Of Pitting Corrosion In Stainless Steel With Formation Of Lacy Covers, Siavash Jafarzadeh, Florin Bobaru, Ziguang Chen
Predictive Peridynamic 3d Models Of Pitting Corrosion In Stainless Steel With Formation Of Lacy Covers, Siavash Jafarzadeh, Florin Bobaru, Ziguang Chen
Department of Mechanical and Materials Engineering: Faculty Publications
In this work, the peridynamic corrosion model is used for 3D simulation of pitting corrosion in stainless steel. Models for passivation and salt layer formation are employed to predict detailed characteristics of pit growth kinetic in stainless steels, such as lacy cover formation on top of the pit, and the diffusion-controlled regime at the pit bottom. The model is validated against an experimentally grown pit on 316L stainless steel in NaCl solution. Lacy covers in this model are formed autonomously during the simulation process. They are remarkably similar to the covers observed on top of the real pits.
Predictive Peridynamic 3d Models Of Pitting Corrosion In Stainless Steel With Formation Of Lacy Covers, Siavash Jafarzadeh, Florin Bobaru, Ziguang Chen
Predictive Peridynamic 3d Models Of Pitting Corrosion In Stainless Steel With Formation Of Lacy Covers, Siavash Jafarzadeh, Florin Bobaru, Ziguang Chen
Department of Mechanical and Materials Engineering: Faculty Publications
In this work, the peridynamic corrosion model is used for 3D simulation of pitting corrosion in stainless steel. Models for passivation and salt layer formation are employed to predict detailed characteristics of pit growth kinetic in stainless steels, such as lacy cover formation on top of the pit, and the diffusion-controlled regime at the pit bottom. The model is validated against an experimentally grown pit on 316L stainless steel in NaCl solution. Lacy covers in this model are formed autonomously during the simulation process. They are remarkably similar to the covers observed on top of the real pits.
Electrochemical Explanation For Asymmetric Electrowetting Response, Mehdi Khodayari, Nathan B. Crane, Alex A. Volinsky
Electrochemical Explanation For Asymmetric Electrowetting Response, Mehdi Khodayari, Nathan B. Crane, Alex A. Volinsky
Faculty Publications
In electrowetting, a droplet/substrate contact angle is modulated by applying a potential difference between the droplet and the substrate. Typically, the droplet potential is changed via an auxiliary electrode dipped in the droplet. Here, it is shown that electrochemical reactions lead to a potential drop on the auxiliary electrode in electrowetting, which degrades the droplet contact angle modulation. The magnitude of this effect depends on the voltage polarity. This problem can be addressed by using a dielectric layer, such as SiO2, which can prevent electrochemical reactions with the electrowetting substrate and the auxiliary electrode.