Engineering Commons^™

Improving Sizing Resolution Of Particle Impactors In The Nanoparticle Range, Shivuday Kala

All Dissertations

The application of particle size measurement extends across many fields: air quality measurement, pharmaceutical studies, paint and coating production, and nanoparticle formulation to name a few. Therefore, accurate measurement of nanoparticles is critical to aerosol science. While devices currently exist that can size and count nanoparticles such as electrical mobility spectrometers, dynamic light scattering devices, and small angle X-ray scattering devices, their high costs, complex operation, and lack of outdoor usability, restrict their use in practical applications. Among the devices that can size aerosols down to the nanoscale, cascade impactors stand out because of their robustness, relatively simple design, low …

Thermoplastics 3d Printing Using Fused Deposition Modeling On Fabrics, Maxwell M. Blais

Electronic Theses and Dissertations

The creation of objects with integrated flexibility is desired and this can be achieved by additive manufacturing on fabric. We propose to use a textile fabric as a flexible joint and create to create an entire object with smaller parts called segments. Such a novel technique will bring integrated flexibility and folded assemblies using extrusion based additive manufacturing machines. The proposed process allows segments to be created flat one at a time on a continuous fabric, which will be suitable for flat to folded assemblies and eliminate size limitations of the 3D printer. Techniques considering object segmentation were used to …

Optimizing Build Plate Adhesion Of Polymers In Fused Granule Fabrication Processes, Alex Schroeder, Jason Weaver

Faculty Publications

Perhaps the most crucial element of fused granule fabrication (FGF) is material adhesion; in order to achieve a successful product, the material being printed must adhere to the build plate. For optimal products, the material should only adhere to the build plate until the print is complete, then be easily removable. This paper examines the effects of different build plates, environments, and bonding agents on material adhesion during the FGF process in a CNC mill machine. The force to remove polycarbonate (PC) and polypropylene (PP) from build plates was tested with various bonding agents. Except in one case, the adhesive …

Theoretical Bases Of Diagnostics Of Radiators By Heat Load Of Passenger Cars, U R. Salomov, D A. Moydinov, S M. Yusupov

Scientific-technical journal

This article presents the technical characteristics of the phenomena occurring in the radiator pipes under the influence of the thermal regime of mechanisms determined by the technical condition of the cooling system components of cars with internal combustion engines.

Nanoscratch Study Of Diamond-Like Carbon Coatings With A Polydopamine + Sio2 Adhesive Underlayer, Anna Fisher

Mechanical Engineering Undergraduate Honors Theses

Diamond-like carbon (DLC) coatings have a wide array of desirable characteristics such as low friction, high hardness, and scratch resistance. Due to high residual stress and thermal mismatch, DLC films experience adhesion difficulties when bonded with metallic substrates, leading to cracking and delamination. In this study, the properties of a new coating with a polydopamine underlayer and silica nanoparticles bonded to a stainless-steel substrate (PDA+SiO2/DLC) were studied alongside three other samples, one with a polydopamine underlayer (PDA/DLC), one with a trimethylsilane (TMS) underlayer (TMS/DLC), and one with no underlayer (DLC only). Nanoscratch tests were performed with a 1 μm spheroconical …

Biofilm And Cell Adhesion Strength On Dental Implant Surfaces Via The Laser Spallation Technique, James D. Boyd, Arnold J. Stromberg, Craig S. Miller, Martha E. Grady

Statistics Faculty Publications

OBJECTIVE: The aims of this study are to quantify the adhesion strength differential between an oral bacterial biofilm and an osteoblast-like cell monolayer to a dental implant-simulant surface and develop a metric that quantifies the biocompatible effect of implant surfaces on bacterial and cell adhesion.

METHODS: High-amplitude short-duration stress waves generated by laser pulse absorption are used to spall bacteria and cells from titanium substrates. By carefully controlling laser fluence and calibration of laser fluence with applied stress, the adhesion difference between Streptococcus mutans biofilms and MG 63 osteoblast-like cell monolayers on smooth and rough titanium substrates is obtained. The …

Adhesion And Deformation Mechanisms Of Polydopamine And Polytetrafluoroethylene: A Multiscale Computational Study, Matthew Brownell

Graduate Theses and Dissertations

Polydopamine (PDA) has been shown to bond via covalent bonding, van der Waals forces, and hydrogen bonding and is known to adhere strongly to almost any material. The application of PDA between a substrate and a PTFE surface coating has resulted in low friction and a greatly reduced wear rate. Previous research probing the capabilities and limitations of PDA/PTFE films have studied the wear and mechanical properties of the film, but the overall adhesive and deformation mechanisms remain unclear.

In this research, we investigate the tribological properties of PDA and PTFE molecules and composites from the atomic to the microscale …

Friction And Wear Behaviors Of Mos2-Multi-Walled-Carbon-Nanotube Hybrid Reinforced Polyurethane Composite Coating, Zhaozhu Zhang, Mingming Yang, Junya Yuan, Fang Guo, Xuehu Men

Friction

MoS2-multi-walled-carbon-nanotube (MWCNT) hybrids containing two-dimensional MoS2 and one-dimensional MWCNTs were synthesized through a one-step hydrothermal reaction. X-ray-diffraction and transmission-electron-microscopy results demonstrated that MoS2 nanosheets were successfully synthesized, and uniformly anchored on the MWCNTs' surfaces. Furthermore, the effects of the MoS2-MWCNT hybrids on the tribological performances of polyurethane composite coatings were investigated using a UMT-2MT tribo-tester. Friction and wear test results revealed that the friction coefficient and wear rate of a 3 wt% MoS2-MWCNT-1 filled polyurethane composite coating were reduced by 25.6% and 65.5%, respectively. The outstanding tribological performance of the MoS2-MWCNT-1 reinforced polyurethane composite coating was attributed to the excellent …

Mechanical Properties Of Permanent Foaming Fixatives For Deactivation & Decommissioning Activities, Tristan Maximilian Simoes-Ponce

FIU Electronic Theses and Dissertations

The Department of Energy is investigating fixative technologies that encapsulate and/or immobilize residual contamination in voids during deactivation and decommissioning (D&D). These technologies must have adequate mechanical and adhesion properties to withstand seismic activity that may occur. One solution is the implementation of polyurethane foams used as permanent foaming fixatives (PFF), specifically intumescent foams that contain expandable graphite, making them fire resistant when exposed to extreme heat conditions.

Tensile, compression, seismic, and tensile adhesion testing was done on six commercial-off-the-self polyurethane foams to determine if the expandable graphite and other filler intumescent technologies improve its mechanical limits. It was found …

Adhesion Testing Of Printed Inks While Varying The Surface Treatment Of Polymer Substrates, Clayton Neff, Edwin Elston, Amanda Schrand, Nathan B. Crane

Faculty Publications

Additive manufacturing with conductive materials enables new approaches to printed electronics that are unachievable by standard electronics manufacturing processes. In particular, electronics can be embedded directly into structural components in nearly arbitrary 3D space. While these methods incorporate many of the same materials, the new processing methods require standard test methods to compare materials, processing conditions, and determine design limits. This work demonstrates a test method to quantitatively measure the adhesion failure of printed inks deposited on a substrate without changing the ink printing conditions. The proposed method is an adaption of single lap shear testing in which the lap …

The Design, Manufacture, And Testing Of A Novel Adhesion System For A Climbing Vehicle, Michael William Schier

Master's Theses

We present the design and fabrication of a prototype wall-climbing vehicle employing a unique combined locomotion and adhesion system in which the adhesive vacuum is transmitted through moving, perforated treads. Implementing the adhesion/drive system involved a broad range of design challenges, including: developing reliable sealing of sliding and static interfaces, understanding the frictional interactions between the drive treads and various vehicle components and surfaces on which they ride, as well as designing for lightness, manufacturability, and adjustability. The clean sheet design presented in this thesis was taken from concept to functioning prototype in less than 6 months, requiring a considered …

Fabrication And Characterization Of Thiol-Acrylate Based Polymer For Bone Tissue Engineering Application, Anoosha Forghani

LSU Master's Theses

Thiol-acrylate materials have been demonstrated to have therapeutic potential as biocompatible scaffolds for bone tissue regeneration due to their osteoconductivity, biodegradability, and well-suited mechanical properties. This study connects the mechanical properties and stability of thiol-acrylate polymer with cell adhesion and proliferation of human adipose derived stromal cells. The polymer presented in this study, trimethylolpropane ethoxylate triacrylate-co-trimethylolpropane tris (3-mercaptopropionate) (TMPeTA-co-TMPTMP), was synthesized by an amine-catalyzed Michael addition reaction. Physical, mechanical, and chemical characterizations were performed on the polymeric scaffold, followed by preliminary in vitro cytocompatibility tests. Live/dead staining assays showed significant differences in cell adhesion for TMPeTA (692 and 912 MW). …

Evaluation Techniques And Improvements Of Adhesion Strength For Tin Coating In Tool Applications: A Review

Faculty of Engineering University of Malaya

The adhesion between coating-substrate systems is an important factor in determining the performance and durability of coated engineering components. This paper reviews the microstructures and adhesion strength of titanium nitride (TiN) coating produced using two different processing methods: chemical vapor deposition and physical vapor deposition. Three methods to evaluate the adhesion strength of the coatings, namely the indentation test, laser spallation technique, and scratch test are presented and discussed in terms of their working principles, their advantages and disadvantages. The extrinsic and intrinsic factors influencing the adhesion strength of coating-substrate system, particularly for TiN coating, are also elaborated. The mechanisms …

Tio2 Nanotube Coating On Stainless Steel 304 For Biomedical Applications

Faculty of Engineering University of Malaya

The present study describes the anodic growth of TiO2 nanotube thin layer on stainless steel 304 in ethylene glycol/water/ammonium fluoride electrolyte. In this regard, pure titanium was coated on stainless steel 304 substrates by a physical vapor deposition magnetron sputtering (PVDMS) technique. The adhesion strength of the coating to the substrate was investigated. TiO2 nanotubes were generated on the top of the Ti coated substrates by means of anodization technique at a 25 V potential and times of 20, 40, and 60 min in an ammonium fluoride electrolyte solution. The anodized Ti-coated samples were heat-treated at 280 degrees C, 430 …

Enhance Diamond Coating Adhesion By Oriented Interlayer Microcracking, Habio Guo, Xingcheng Xiao, Yue Qi, Zhi-Hui Xu, Xiaodong Li

Xiaodong Li

In this paper, we report a microcrack toughening mechanism for enhancing the adhesion of diamondcoating. The oriented microcracks were formed within the TiC interlayer to dissipate strain energy and accommodate deformation via the crack opening-closing mechanism, thus enhancing the coating/substrate interfacial toughness. The delamination of diamondcoating was effectively prevented when the parallel microcracks were confined within the interlayer and arrested at interfaces of coating/interlayer/substrate. Density functional theory calculations revealed that the highly anisotropicfracture strength of the TiC phase energetically favors crack initiation and propagation along (100) planes only, which are 54.7° away from the interface. These microcracks are constrained inside …

Thermal And Dynamic Mechanical Properties Of Grafted Kenaf Filled Poly (Vinyl Chloride)/Ethylene Vinyl Acetate Composites

Faculty of Engineering University of Malaya

The effects of kenaf and poly (methyl methacrylate grafted kenaf on the thermal and dynamic mechanical properties of poly (vinyl chloride), PVC and ethylene vinyl acetate, EVA blends were investigated. The PVC/EVA/kenaf composites were prepared by mixing the grafted and ungrafted kenaf fiber and PVC/ EVA blend using HAAKE Rheomixer at a temperature of 150 degrees C and the rotor speed at 50 rpm for 20 min. The composites were subjected to Differential Scanning Calorimetric (DSC), Thermogravimetric analysis (TGA), dynamic mechanical analysis (DMA), Fourier transform infrared (FTIR) and Scanning Electron Microscopy (SEM) studies. The DSC data revealed that the crystallinity …

Highly Transparent, Self-Cleaning, And Antireflective Nanoparticle Coatings, Corey Seth Thompson

Graduate Theses and Dissertations

Current solar panel technologies require a sheet of glass to serve as both mechanical support and to protect the cells from the environment. The reflection from the glass sheet can reflect up to 8% of the incident light, reducing the power output of the panel. Antireflective coatings can be used to allow more light to enter the panel to be converted into usable electricity. However, no solid thin film materials exhibit a low enough index of refraction to serve as antireflective coatings for common solar glass. The main goal of this research was to investigate the self-cleaning, antifogging, and antireflective …

Scaling Reversible Adhesion In Synthetic And Biological Systems, Michael David Bartlett

Open Access Dissertations

Geckos and other insects have fascinated scientists and casual observers with their ability to effortlessly climb up walls and across ceilings. This capability has inspired high capacity, easy release synthetic adhesives, which have focused on mimicking the fibrillar features found on the foot pads of these climbing organisms. However, without a fundamental framework that connects biological and synthetic adhesives from nanoscopic to macroscopic features, synthetic mimics have failed to perform favorably at large contact areas. In this thesis, we present a scaling approach which leads to an understanding of reversible adhesion in both synthetic and biological systems over multiple length …

Numerical Evaluation And Analysis Of The Adhesion Phenomena In Thermal Barrier Coating Systems Through Bio-Mimicking Plasma Process, Naser Imran Hossain

LSU Master's Theses

Thermal Barrier Coatings or TBCs when abbreviated are an imperative part of the thermal protection system of expensive equipment and machinery in the automobile and aeronautics industry. They provide protection to expensive alloy materials upto a temperature of 2700° C without expensive metallurgical additions. Unfortunately, the problem of coating adhesion has plagued the TBC field for years, leading to catastrophic failures in critical TBC systems. Efforts to chemically improve bond strength has not been entirely successful, so the only other efficient way to do this would be some kind of mechanical interlocking that occurs at micro/nano scales. This research work …

Interface Engineered Diamond Coatings For Dry Machining Applications, Humberto Arturo Gomez Vega

USF Tampa Graduate Theses and Dissertations

Several studies have been propose to improve the adhesion of diamond films on cemented carbide tool materials, however a systematic study in identifying the role of the factors that affect the final diamond adhesion and the resulting machining performance of the tool under real manufacturing conditions is still unexplored. CVD diamond film's extraordinary qualities bring little benefit if the film fails to adhere sufficiently to the substrate. Inadequate adhesion undermines tool performance and longevity, causing unpredictable behavior under load and possibly leading to unexpected failure of the tool in the production line. This dissertation investigates the effects of different surface …

Structural And Mechanical Properties Of Nanostructured Tio2 Thin Films Deposited By Rf Sputtering

A.S. Md Abdul Haseeb

This study mainly aims to evaluate the effects of substrate temperatures on the mechanical properties of TiO2 thin films deposited on glass substrates by radio-frequency (RF) magnetron sputtering. All titania films possess anatase structure having a nodular morphology. AES results reveal that Si and Na ions from glass diffuse into TiO2 films at higher substrate temperatures. Micro-scratch and wear tests were conducted to evaluate their mechanical and tribological properties. The adhesion critical loads of TiO2 films deposited at room temperature, 200 and 300°C are found to be 1.51, 1.54 and 1.08N, respectively. Scratch hardness also increases from 11.5 to 13.6GPa …

Finite Element Analysis Of Cracks In Aging Aircraft Structures With Bonded Composite-Patch Repairs, Linxia Gu, Ananth Ram Mahanth Kasavajhala, Shijia Zhao

Department of Mechanical and Materials Engineering: Faculty Publications

Bonded composite-patch repair has been used to transfer load from cracked structures to the reinforcement such that subsequent crack propagation is reduced. In this study,the mechanical behavior of a single edge v-notch A17075-T6 plate repaired with 1-ply and 4-ply composite patches was investigated through the finite element method. Contour integral method was used to define and evaluate the stress intensity factors at the crack tip. The effect of the adhesive epoxy film, patch material, thickness and ply orientations on the evolution of the stress intensity factor (SIF) of the repaired structure was examined. The results indicated that the SIF of …

Enhance Diamond Coating Adhesion By Oriented Interlayer Microcracking, Habio Guo, Xingcheng Xiao, Yue Qi, Zhi-Hui Xu, Xiaodong Li

Faculty Publications

In this paper, we report a microcrack toughening mechanism for enhancing the adhesion of diamondcoating. The oriented microcracks were formed within the TiC interlayer to dissipate strain energy and accommodate deformation via the crack opening-closing mechanism, thus enhancing the coating/substrate interfacial toughness. The delamination of diamondcoating was effectively prevented when the parallel microcracks were confined within the interlayer and arrested at interfaces of coating/interlayer/substrate. Density functional theory calculations revealed that the highly anisotropicfracture strength of the TiC phase energetically favors crack initiation and propagation along (100) planes only, which are 54.7° away from the interface. These microcracks are constrained inside …

The Dissipated Power In Atomic Force Microscopy Due To Interactions With A Capillary Fluid Layer, Nicole N. Hashemi, M.R. Paul, H. Dankowicz, W. Jhe

Nastaran Hashemi

We study the power dissipated by the tip of an oscillating micron-scale cantilever as it interacts with a sample using a nonlinear model of the tip-surface force interactions that includes attractive, adhesive, repulsive, and capillary contributions. The force interactions of the model are entirely conservative and the dissipated power is due to the hysteretic nature of the interaction with the capillary fluid layer. Using numerical techniques tailored for nonlinear and discontinuous dynamical systems we compute the exact dissipated power over a range of experimentally relevant conditions. This is accomplished by computing precisely the fraction of oscillations that break the fluid …

Direct Simulations Of Cells Motions And Deformations In Flow, Quan Jin

Dissertations

Direct numerical simulations (DNS) are used to study the motions and deformations of blood cells, especially leukocytes, in pressure driven flows in parallel plate channels with both smooth and uneven walls under adhesion force between the leukocytes and the channel wall.

Leukocytes are represented by two composite fluid models. The first model is the compound-drop model in which the cytoplasm and the nucleus are modeled as fluids, and the second one is the drop-rigid-particle model in which the cytoplasm is modeled as a fluid and the nucleus as a rigid particle. The adhesion force is computed using two adhesion force …

Modeling The Mechanical Effects Of Liquid Mediated Adhesion Between The Human Vocal Folds, Gifford Zach Decker

Theses and Dissertations

The vocal folds are a complex self-oscillating biological system. In the current research, an equation was developed to model viscous adhesion forces that occur when the collision of the vocal folds results in the formation of a liquid bridge. The adhesion equation was validated using experimental data, and simplified to a one-dimensional approximation with an included correction factor that adjusted the predicted pressure in situations where the one-dimensional approximation was invalid. A non-oscillating vocal fold model with a modeled liquid bridge was used to study stress resulting from viscous adhesion. The vertical normal stress magnitude ranged from about 80 to …