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Full-Text Articles in Engineering

Novel Coating Methods On Centrifugally-Spun Polymer Fibers For Applications In Lithium-Ion Batteries, Jonathan G. Ayala May 2021

Novel Coating Methods On Centrifugally-Spun Polymer Fibers For Applications In Lithium-Ion Batteries, Jonathan G. Ayala

Theses and Dissertations

The work presented in this thesis focuses on the processing, characterization, and electrochemical results of centrifugally spun composite carbon fiber electrodes for application as anode material in lithium-ion batteries. The work is presented as a compilation of two major projects. First, the use of novel Co3O4 wet coatings to increase the capacity of carbon fibers produced from Polyacrylonitrile (PAN). In this work, PAN fibers are produced via the Forcespinning method, and were heat treated by oxidation in air at 200 °C for four hours, and subsequent carbonization at 600 °C for six hours. The electrochemical performance of the Co3O4/C composite-fiber …


Centrifugally-Spun Ceramic/Carbon Composite Fibers And Their Use As Anode Materials In Li-Ion Batteries, Gabriel Gonzalez May 2021

Centrifugally-Spun Ceramic/Carbon Composite Fibers And Their Use As Anode Materials In Li-Ion Batteries, Gabriel Gonzalez

Theses and Dissertations

The work in this thesis focuses in the study of Centrifugally Spun Short Fiber Composites and their Implementation as Alternate Anode Material in Li-Ion Batteries. Due to their high theoretical capacity, abundance, and environmental friendliness, metal oxides have been widely studied as alternate anode materials for lithium ion batteries (LIBs). In this research work, the processing of SnO2 and SnO2/TiO2 ceramic short fibers as well as flexible and porous metal oxide carbon fibers (FPMOCFs) by centrifugal spinning followed by an optimized coating technique is reported. In addition, the electrochemical performance of the composites was also investigated and is provided.


Enhanced Kinetics And Modeling Of Pan-Based Carbon Felt Anodes In Vanadium Redox Flow Batteries, Michael Cyrus Daugherty Dec 2020

Enhanced Kinetics And Modeling Of Pan-Based Carbon Felt Anodes In Vanadium Redox Flow Batteries, Michael Cyrus Daugherty

Doctoral Dissertations

All-vanadium redox flow batteries (VRFBs) are a promising technology for grid-level energy storage, however, there are still several limitations in the forms of durability, efficiency, and overall costs, which are barriers to its commercial viability. With both bulk electrolyte flowing through its porous matrix and species flux at the solid-electrolyte interface, electrodes are the component of VRFB systems which host electrochemical reactions and facilitate contact between the liquid phase electrolyte and the electronically conductive solid phase. While the more limiting electrode in VRFB systems is dependent on the material, for polyacrylonitrile (PAN)-based carbon felts, the anode constitutes a larger portion …


Design And Synthesis Of Novel Nanometallic Catalysts And Electrode Materials For Green Fuel Cells, Jing Zhang May 2018

Design And Synthesis Of Novel Nanometallic Catalysts And Electrode Materials For Green Fuel Cells, Jing Zhang

Graduate Dissertations and Theses

The United Nations formally adopted 17 sustainable development goals (SDGs) at its 2015 summit. Many of these goals addressed issues such poverty, hunger, health, education, climate-change, gender equality, water, sanitation, energy, urbanization, environment and social justice. The seventh SDG seeks to ensure access to affordable, reliable, sustainable and modern energy for all. So among all renewable forms of energy, fuel cells with high efficiency have attracted a lot of attention recently. In particular, the direct ethanol fuel cells (DEFCs) and microbial fuel cells (MFCs) are significant due to their green fuel, less waste generated and environmental friendliness. Hence the overall …


Synthesis, Characterization, And Electrochemical Properties Of Polyaniline Thin Films, Soukaina Rami Mar 2015

Synthesis, Characterization, And Electrochemical Properties Of Polyaniline Thin Films, Soukaina Rami

USF Tampa Graduate Theses and Dissertations

Conjugated polymers have been used in various applications (battery, supercapacitor, electromagnetic shielding, chemical sensor, biosensor, nanocomposite, light-emitting-diode, electrochromic display etc.) due to their excellent conductivity, electrochemical and optical properties, and low cost. Polyaniline has attracted the researchers from all disciplines of science, engineering, and industry due to its redox properties, environmental stability, conductivity, and optical properties. Moreover, it is a polymer with fast electroactive switching and reversible properties displayed at low potential, which is an important feature in many applications. The thin oriented polyaniline films have been fabricated using self-assembly, Langmuir-Blodgett, in-situ self-assembly, layer-by-layer, and electrochemical technique. The focus of …


Manufacturing Of Single Solid Oxide Fuel Cells, Jonathan Torres-Caceres Jan 2013

Manufacturing Of Single Solid Oxide Fuel Cells, Jonathan Torres-Caceres

Electronic Theses and Dissertations

Solid oxide fuel cells (SOFCs) are devices that convert chemical energy into electrical energy and have the potential to become a reliable renewable energy source that can be used on a large scale. SOFCs have 3 main components; the electrolyte, the anode, and the cathode. Typically, SOFCs work by reducing oxygen at the cathode into O2- ions which are then transported via the electrolyte to the anode to combine with a fuel such as hydrogen to produce electricity. Research into better materials and manufacturing methods is necessary to reduce costs and improve efficiency to make the technology commercially viable. The …