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Full-Text Articles in Engineering
Recent Progress In Two Dimensional Mxenes For Photocatalysis: A Critical Review, Tahir Haneef, Kashif Rasool, Jibran Iqbal, Rab Nawaz, Muhammad Raza Ul Mustafa, Khaled A Mahmoud, Tapati Sarkar, Asif Shahzad
Recent Progress In Two Dimensional Mxenes For Photocatalysis: A Critical Review, Tahir Haneef, Kashif Rasool, Jibran Iqbal, Rab Nawaz, Muhammad Raza Ul Mustafa, Khaled A Mahmoud, Tapati Sarkar, Asif Shahzad
All Works
Transition metal carbides and nitrides, generally known as MXenes have emerged as an alternative to improve photocatalytic performance in renewable energy and environmental remediation applications because of their high surface area, tunable chemistry, and easily adjustable elemental compositions. MXenes have many interlayer groups, surface group operations, and a flexible layer spacing that makes them ideal catalysts. Over 30 different members of the MXenes family have been explored and successfully utilized as catalysts. Particularly, MXenes have achieved success as a photocatalyst for carbon dioxide reduction, nitrogen fixation, hydrogen evolution, and photochemical degradation. The structure of MXenes and the presence of hydrophilic …
Photocatalytic Activity: Experimental Features To Report In Heterogeneous Photocatalysis, Md. Ariful Hoque, Marcelo I. Guzman
Photocatalytic Activity: Experimental Features To Report In Heterogeneous Photocatalysis, Md. Ariful Hoque, Marcelo I. Guzman
Chemistry Faculty Publications
Heterogeneous photocatalysis is a prominent area of research with major applications in solar energy conversion, air pollution mitigation, and removal of contaminants from water. A large number of scientific papers related to the photocatalysis field and its environmental applications are published in different journals specializing in materials and nanomaterials. However, many problems exist in the conception of papers by authors unfamiliar with standard characterization methods of photocatalysts as well as with the procedures needed to determine photocatalytic activities based on the determination of “apparent quantum efficiencies” within a wavelength interval or “apparent quantum yields” in the case of using monochromatic …
Synthesis And Catalytic Applications Of Non-Metal Doped Mesoporous Titania, Syed Z. Islam, Suraj R. Nagpure, Doo Young Kim, Stephen E. Rankin
Synthesis And Catalytic Applications Of Non-Metal Doped Mesoporous Titania, Syed Z. Islam, Suraj R. Nagpure, Doo Young Kim, Stephen E. Rankin
Chemical and Materials Engineering Faculty Publications
Mesoporous titania (mp-TiO2) has drawn tremendous attention for a diverse set of applications due to its high surface area, interfacial structure, and tunable combination of pore size, pore orientation, wall thickness, and pore connectivity. Its pore structure facilitates rapid diffusion of reactants and charge carriers to the photocatalytically active interface of TiO2. However, because the large band gap of TiO2 limits its ability to utilize visible light, non-metal doping has been extensively studied to tune the energy levels of TiO2. While first-principles calculations support the efficacy of this approach, it is challenging to …
Mos2 As A Co-Catalyst For Photocatalytic Hydrogen Production From Water, Bing Han, Yun Hang Hu
Mos2 As A Co-Catalyst For Photocatalytic Hydrogen Production From Water, Bing Han, Yun Hang Hu
Michigan Tech Publications
Solar-to-hydrogen conversion based on photocatalytic water splitting is a promising pathway for sustainable hydrogen production. The photocatalytic process requires highly active, inexpensive, and earth-abundant materials as photocatalysts. As a presentative layer-structured transition metal dichalcogenides, molybdenum disulfide (MoS2) is attracting intensive attention due to its unique electro and photo properties. In this article, we comprehensively review the recent research efforts of exploring MoS2 as a co-catalyst for photocatalytic hydrogen production from water, with emphasis on its combination with CdS, CdSe, graphene, carbon nitride, TiO2, and others. It is shown that MoS2–semiconductor composites are promising photocatalysts for hydrogen evolution from water under …