Engineering Commons^™

Ozonation In Water Reuse: Formation And Mitigation Of N-~Nitrosodimethylamine, Erica J. Marti

UNLV Theses, Dissertations, Professional Papers, and Capstones

Formation of N-nitrosodimethylamine (NDMA) is a substantial concern for drinking water and water reuse. NDMA, a probable human carcinogen, is formed when water is disinfected with chloramines and ozone. This research focused on three issues regarding NDMA formation and mitigation. The first issue involved understanding the compounds (i.e., precursors) present in water and wastewater that react with ozone to form NDMA. Model precursors were identified and molar yields for NDMA formation were determined. The model precursors form high amounts of NDMA with ozone, but form very little NDMA with chloramines, which means there are two distinct groups of NDMA precursors: …

Perchlorate Bioremediation: Controlling Media Loss In Ex-Situ Fluidized Bed Reactors And In-Situ Biological Reduction By Slow-Release Electron Donor, Sichu Shrestha

UNLV Theses, Dissertations, Professional Papers, and Capstones

The main concern of perchlorate exposure through drinking water is its effects on the production of thyroid hormone, which is important for human metabolism and child’s brain development. The US Environmental Protection Agency (EPA) has listed perchlorate in the contaminant list as well as in the Unregulated Contaminant Monitoring rule.

The extent of perchlorate contamination can be categorized by the level of contamination into parts per million (ppm) levels, typically in locations where perchlorate was manufactured, and parts per billion (ppb) levels where perchlorate was used for various purposes. Ion-exchange is generally adopted for treating ppb levels of perchlorate while …

Fluoride And Phosphate Removal From Industrial And Domestic Wastewaters Using Cerium Chloride, John Michael Gonzales

UNLV Theses, Dissertations, Professional Papers, and Capstones

The use of cerium chloride (CeCl3) to remove fluoride and phosphate from waters is addressed in this study. High concentrations of fluoride exist in groundwater especially in developing countries. Consumption drinking water containing high levels of fluoride can lead to serious cases of dental and skeletal fluorosis. Current defluoridation technologies are limited, especially for high levels of fluoride, and are expensive. Industrial wastewaters contribute to the highest fluoride contamination in the world. With the increasing production of electronic materials, the global fluoride concentration and fluoride-contaminated waters have grown tremendously. Excessive discharge of phosphate into the environment promotes eutrophication of lakes …

The Use Of Cod, Toc, Fluorescence, And Absorbance Spectroscopy To Estimate Biochemical Oxygen Demand In Wastewater, Evelyn Aramaine Christian

UNLV Theses, Dissertations, Professional Papers, and Capstones

All wastewater treatment facilities must obtain a National Pollution Discharge Elimination System (NPDES) permit, which regulates the quality of water that is discharged. Common to all NPDES permits is a limit on organic matter, as determined by the five-day biochemical oxygen demand (BOD5) test. More rapid methods, such as chemical oxygen demand (COD), total organic carbon (TOC), fluorescence, and absorbance spectroscopy are also capable of quantifying organic matter. Previous studies indicate it is possible to develop correlations between these parameters. This study explored the correlations using influent, primary clarifier effluent, and finished effluent samples from an operational wastewater treatment plant …

Impacts Of Ozone Dose And Empty Bed Contact Time On Total Organic Carbon Removal Through Ozone-Biological Activated Carbon Treatment, Ashley Selvy

UNLV Theses, Dissertations, Professional Papers, and Capstones

In the face of climate change, pollution, and population growth, water scarcity has become a global threat. Many populations have witnessed their drinking water sources dwindle to an unsustainable level. These severe conditions have sparked interest in potable reuse as an increasingly viable alternative to typical ‘pristine’ drinking water sources. Currently, the California Division of Drinking Water (DDW) provides the most stringent requirements for reuse water quality. The best way to meet these standards is through the use of full advanced treatment (FAT), which consists of reverse osmosis (RO) and an advanced oxidation process (AOP). Alternative treatment trains composed of …

Mathematical Equations And System Identification Models For A Portable Pneumatic Bladder System Designed To Reduce Human Exposure To Whole Body Shock And Vibration, Ezzat Aziz Ayyad

UNLV Theses, Dissertations, Professional Papers, and Capstones

A mathematical representation is sought to model the behavior of a portable pneumatic foam bladder designed to mitigate the effects of human exposure to shock and whole body random vibration. Fluid Dynamics principles are used to derive the analytic differential equations used for the physical equations Model. Additionally, combination of Wiener and Hammerstein block oriented representation techniques have been selected to create system identification (SID) block oriented models. A number of algorithms have been iterated to obtain numerical solutions for the system of equations which was found to be coupled and non-linear, with no analytic closed form solution. The purpose …

Transport Properties Of Nano-Silica Contained Self-Consolidating Concrete, Borhan Moradi

UNLV Theses, Dissertations, Professional Papers, and Capstones

In this research study, transport properties of various self-consolidating concretes (SCCs) containing nano-particles (SiO2) were investigated. Nano-silica replaced a portion of the cementitious materials at different replacement levels ranging from 1.5 to 7.5% by weight. For the purpose of this investigation, flow, bulk, and transport properties of SCCs were studied. The investigated transport properties were absorption, water penetration, rapid chloride permeability, capillary absorption, rapid migration, and chloride diffusion. Transport properties of nano-silica SCCs were also compared to those of equivalent silica fume (micro silica) contained concretes, as well as those of control mixture (concrete without nano or micro silica).

Test …

Investigating The Physical Properties And Runoff Treatment Capability Of Pervious Concrete Containing Granular Activated Carbon, Mark Elias Elkouz

UNLV Theses, Dissertations, Professional Papers, and Capstones

A current environmental concern is that of urban stormwater runoff, which can carry a multitude of contaminants and could threaten or impair surface waters. Pervious concrete (PC) is a type of concrete with significant void spaces that can facilitate infiltration and lead to less runoff. The EPA cites previous research to show that pervious pavement structures reduce such contaminants as metals and total suspended solids. Since Granular Activated Carbon (GAC) is a well-known contaminant adsorbent, the purpose of this research was to determine if PC with added GAC would result in improved runoff treatment, while still maintaining its material properties. …

Phosphorus Removal From Ebpr Sludge Dewatering Liquors Using Lanthanum Chloride, Aluminum Sulfate And Ferric Chloride, Michael Strileski

UNLV Theses, Dissertations, Professional Papers, and Capstones

In wastewater treatment, enhanced biological phosphorus removal (EBPR) is becoming an increasingly popular alternative to chemical precipitation (CP) because of its lower costs and reduced sludge production. However, downstream solids handling processes such as digestion, sludge storage and dewatering promote an undesirable release (i.e. secondary release) of polyphosphate that was stored within EBPR sludge. Released phosphate is recycled to the head of the plant with the liquors of sludge dewatering processes. The concentration of phosphate in recycle streams from EBPR systems can be one to two orders of magnitude higher than the influent phosphorus concentration entering the EBPR system. Plants …

Investigating The Feasibility Of Growing Algae For Fuel In Southern Nevada, Faegheh Moazeni

UNLV Theses, Dissertations, Professional Papers, and Capstones

Microalgae capable of growing in waste are adequate to be mass-cultivated for biodiesel, avoiding fertilizers and clean water, two obstacles to sustainability of the feedstock production. This study replaces fertilizers and clean water with waste products. The investigated wastes include (1) the liquid fraction of sewage after solids and particles are removed, known as centrate, and (2) algal biomass residue, i.e. the algae remaining at the end of the lipids extraction process at biofuel plants. These wastes contain sufficient amount of nitrogen and phosphorus required for algal growth. This study proposes a system in which centrate would be used as …

Investigating The Impacts Of Conventional And Advanced Treatment Technologies On Energy Consumption At Satellite Water Reuse Plants, Jonathan Roy Bailey

UNLV Theses, Dissertations, Professional Papers, and Capstones

With the ever increasing world population and the resulting increase in industrialization and agricultural practices, depletion of two of the world's most important natural resources, water and fossil fuels, is inevitable. Water reclamation and reuse is the key to protecting these natural resources. Water reclamation using smaller decentralized wastewater treatment plants, known as satellite water reuse plants (WRP), have become popular in the last decade. With stricter standards and regulations on effluent quality and requirements for a smaller land footprint (i.e. real estate area), additional treatment processes and advanced technologies are needed. This greatly increases the energy consumption of an …

Impact Of Secondary Treatment Types And Sludge Handling Processes On Estrogen Concentration In Wastewater Sludge, Erica J. Marti

UNLV Theses, Dissertations, Professional Papers, and Capstones

Endocrine-disrupting compounds (EDCs), such as estrogen, are known to be present in the aquatic environment at concentrations that negatively affect fish and other wildlife. Wastewater treatment plants (WWTPs) are major contributors of EDCs into the environment. EDCs are released via effluent discharge and land application of biosolids. Estrogen removal in WWTPs has been studied in the aqueous phase; however, few researchers have determined estrogen concentration in sludge. This study focuses on estrogen concentration in wastewater sludge as a result of secondary treatment types and sludge handling processes. Grab samples were collected before and after multiple treatment steps at two WWTPs …

Effects Of Moisture Augmentation Of Municipal Solid Waste Through Addition Of Food Waste Or Wastewater Treatment Biosolids On Bio-Gas Formation For Power Generation, Jared Michael Gore

UNLV Theses, Dissertations, Professional Papers, and Capstones

An investigation into the effect of moisture augmentation by manipulation of food waste proportion or wastewater treatment plant biosolids proportion was undertaken to determine the effects on production of methane and other biogases from municipal solid waste (MSW). Laboratory microcosm experiments were performed to determine the effect of various proportions of influent waste streams on the production of biogas. Results indicated that moisture augmentation through the addition of food waste to MSW increases the overall bio-gas and hydrogen gas formed during fermentation. Moisture augmentation through addition of wastewater treatment bio-solids lead to inconclusive results. Addition of food waste to MSW …

Hydroclimatic Forecasting In The Western United States Using Paleoclimate Reconstructions And Data-Driven Models, Christopher Allen Carrier

UNLV Theses, Dissertations, Professional Papers, and Capstones

This thesis investigated climate variability and their associated hydrologic responses in the western United States. The western United States faces the problem of water scarcity, where the management and mitigation of available water supplies are further complicated by climate variability. Climate variability associated with the phases of oceanic-atmospheric oscillations has been shown to influence streamflow and precipitation, where predictive relationships have led to the possibility of producing long-range forecasts. Based on literature review, four oceanic-atmospheric oscillation indices were identified in having the most prominent influence over the western United States including the El Niño - Southern Oscillation (ENSO), Pacific Decadal …

Automated Procedures For Quantification Of Rhizosphere Physical Properties In Micro Ct Images, Natarajan S. Pillai

UNLV Theses, Dissertations, Professional Papers, and Capstones

The rhizosphere, i.e. the zone of soil immediately surrounding plant roots plays a prominent role in supplying plants with water and nutrients. However, surprisingly little is known about rhizosphere physical properties and how they affect root growth, water and nutrient uptake. The lack of non-invasive and non-destructive imaging techniques necessary to observe living roots growing in undisturbed soil have been a main reason for this shortcoming. Recent advances in synchrotron X-ray micro tomography (CMT) provide the potential to directly observe soil physical properties around living roots in-situ.In this work we develop procedures for assisting scientist to study the soil properties …

Evaluating The Impacts Of Water Conservation Policies On Water Demand, Availability And Outdoor Water Use In The Las Vegas Valley, Kamal Qaiser

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Las Vegas Valley, located in the arid Southern Nevada region, with a growing population, limited water resources, and a prolonged drought, faces a challenge in meeting its future water needs. Southern Nevada Water Authority (SNWA), the main water management agency in the Valley, is focusing on water conservation to reduce water demand. Current water use is 945 lpcd (250 gpcd) which SNWA aims to reduce to 752 lpcd (199 gpcd) by 2035. Presently the indoor outdoor water use proportion is about 40:60 in the Valley. An important component of the Valley's supply are the return flow credits which SNWA …

Investigation Of Potential Pathways And Multi-Cycle Bioregeneration Of Ion-Exchange Resin Laden With Perchlorate, Mohamadali Sharbatmaleki

UNLV Theses, Dissertations, Professional Papers, and Capstones

Ion-exchange (IX) is possibly the most feasible technology for perchlorate removal and perchlorate-selective and non-selective IX resins are commercially available for this purpose. The use of both resins has shortcomings. Selective resins are incinerated after one time use, and non-selective resins produce a regenerant waste stream that contains high concentration of perchlorate. A process involving directly contacting of spent IX resin containing perchlorate with perchlorate-reducing bacteria (PRB) to bioregenerate the resin has been developed and proven recently. In this process PRB biodegrade perchlorate ions which are attached to the functional groups of the resin.

Although its feasibility has been proven, …

Assessment Of Impacts To Hydroclimatology And River Operations Due To Climate Change Over The Colorado River Basin, William Paul Miller

UNLV Theses, Dissertations, Professional Papers, and Capstones

This dissertation investigated the impacts of climate change to the hydroclimatology and river and reservoir management operations within the Colorado River Basin. Preliminary research indicated observed warming trends throughout the Colorado River Basin and corresponding seasonal trends to the magnitude and timing of runoff in the Colorado River Basin. Subsequent research investigated the changing character of precipitation and corresponding impacts to streamflow over the Colorado River Basin. Analysis of snowpack telemetry (SNOTEL) stations over the American West and Colorado River Basin indicated decreasing trends in annual snowpack, often at least at the 95% confidence interval. A shorter snowpack season was …

Ion-Exchange (Ix): Arsenic And Chromium Removal From Brines And Removal Of Inorganic Contaminants By Specialty Resins, Behrang Pakzadeh

UNLV Theses, Dissertations, Professional Papers, and Capstones

Although ion exchange is highly efficient in removing inorganic contaminants, similar to other water treatment technologies, ion exchange has some drawbacks that need to be studied further. Three issues related to drawbacks of ion-exchange resins in water treatment were addressed in this research. The first issue was the influence of anionic inorganic co-contaminants including nitrate, Cr(VI), Se(VI), and As(V) on the performances of nitrate and perchlorate specialty (selective) resins in water treatment. It was found that nitrate can be removed from waters using perchlorate specialty resins, but the resin is poorly regenerated. Perchlorate was not easily removed from either nitrate …

Investigation Of Feasibility And Potential Mechanisms For The Bioregeneration Of Perchlorate Laden Gel-Type Anion Exchange Resin, Arjun Krishna Venkatesan

UNLV Theses, Dissertations, Professional Papers, and Capstones

The feasibility and potential mechanisms for the bioregeneration of perchlorate laden gel-type anion exchange resin were investigated in this study. Bioregeneration is a sustainable process when compared to one time use of resin and disposal by incineration. Batch and bench-scale bioregeneration experiments were performed to evaluate the feasibility of the process and to gain insight into potential mechanisms that control gel-type resin bioregeneration. The results of the bioregeneration tests suggested that the initial phase of the bioregeneration process is controlled by kinetics, while the later phase is controlled by diffusion. Higher perchlorate load in the resin had a positive effect …