Engineering Commons^™

Role Of Manganese Oxide In The Formation Of Disinfection Byproducts In Drinking Water Treatment, Arianne A. Bazilio

Doctoral Dissertations

This work examined the role of manganese oxide (MnO_x) in the formation of disinfection byproducts (DBPs) in drinking water treatment. DBPs are of increasing concern as more is being learned about their carcinogenicity and genotoxicity. Studies were performed to determine the impact of MnO_x and free chlorine (Cl₂), used for dissolved manganese (Mn(II) removal, on the formation of these undesirable byproducts. Batch experiment results showed that the presence of MnO_x did not significantly increase the haloacetic acid or trihalomethane concentrations. Rates of DBP formation were also similar in the absence and presence of Mn(II) …

Atomic Layer Deposition Prepared Nanostructured Materials For Various Catalytic Reactions, Xiaofeng Wang

Doctoral Dissertations

"Atomic layer deposition (ALD) has been widely used for thin film coating and metal nanoparticles (NPs) preparation. In this report, the applications of ALD prepared nanostructured materials in catalysis were examined.

Highly dispersed Pt monometallic catalysts with different substrates and multi-walled carbon nanotubes (MWCNTs) supported Pt-Co bimetallic catalysts were synthesized by ALD for selective hydrogenation of α, β-unsaturated aldehydes to unsaturated alcohols (UA). Pt/MWCNTs showed the highest selectivity of UA in selective hydrogenation of citral, as compared to Pt/SiO₂, Pt/ALD-Al₂O₃, and Pt/γ-Al₂O₃. After adding Co, the highest selectivity was achieved …

Microbial Competition In Bioelectrochemical Systems, Varun Srinivasan

Doctoral Dissertations

Bioelectrochemical systems(BESs)/ microbial fuel fells (MFCs) are a well-studied potential technology for bioremediation and decentralized wastewater treatment. However, progress has been somewhat stalled at the bench-scale. In well controlled experiments electron recovery is high. In natural environments, wastewaters are complex and anode-respiring bacteria can be outcompeted in the presence of competing microorganisms, leading to a loss in electron-recovery and power production. Furthermore, the cathode of the MFC plays a vital role in providing flexibility for treatment options but is an understudied part of MFCs. Modelling Intracellular Competition in a Denitrifying Biocathode: One potential MFC configuration uses an organic-oxidizing anode biofilm …

Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel

Doctoral Dissertations

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multi-components, especially for the crosslinking of rigid high-performance materials. In these reactions, miscibility is crucial for curing efficiency. This miscibility is typically enhanced by adding a third component, a plasticizer. For the reaction of the highly crystalline crosslinking agent hexamethylenetetramine (HMTA) with a strongly hydrogen-bonded phenol formaldehyde resin, furfural has been traditionally used as the plasticizer. However, the reason for its effectiveness is not clear. In this doctoral thesis work, miscibility and crosslinking efficiency of plasticizers in phenolic curing reactions are studied by thermal analysis and spectroscopic …

Decision Analytical Methods For Robust Water Infrastructure Planning Under Deep Uncertainty, Mehmet Umit Taner

Doctoral Dissertations

Deep uncertainties resulting from climate change, demographic pressures, and rapidly evolving socioeconomic conditions are challenging the way that water planners design and operate large-scale infrastructure systems. Conventionally, water infrastructures have been developed using stationary methods, assuming that the underlying uncertainties can be derived from historical data or experience. However, these methods are less useful under deeply uncertain climate and socioeconomic conditions, in which the future can be substantially different from the past and cannot be expressed by well-defined probability distributions. The recognition of deep uncertainties in long-term water resources planning has led to the development of “decision-analytical” frameworks that do …

Microbial Dynamics And Design Considerations For Decentralized Microbial Fuel Cell Applications, Cynthia Castro

Doctoral Dissertations

The purpose of this dissertation was to assess the practicality of using microbial fuel cells (MFCs) as alternative sanitation systems for wastewater treatment and energy recovery, focusing on identifying key design considerations for treating high strength wastewater and managing alternative metabolic pathways. We evaluated the energetic outputs of a lab-based pilot MFC designed to treat complex organics present in both synthetic feces and municipal wastewater. The pilot MFC produced two energetic products, methane and electricity, when treating two types of complex wastewaters. The energetic products associated with anode respiration and methanogenesis were simultaneously observed and yielded a combined energy ouput …

Sustainable Infrastructure Development: A Holistic System Based Decision Making Framework Integrating Vulnerability Indicators And Stakeholders Objectives, Mohamed Saeid Eid

Doctoral Dissertations

Infrastructure systems enable the host communities to expand, develop, and prosper in adequate socioeconomic conditions and healthy environment. Thus, the strategies for sustainable infrastructure development should aim to increase the individual utility of the local stakeholders, while reducing the vulnerability of the built environment to perturbations. Nevertheless, the available frameworks consider the development of the infrastructure systems as isolated projects and do not simultaneously address the needs of the stakeholders or the vulnerability of the built environment. The goal of this research is to provide decision makers and the research community with a novel infrastructure development framework that holistically balances …

Total Organic Iodine Quantification And Occurrence In Drinking Water, And Toxicity Assessment Of Iodinated Disinfection By-Products, Rassil El Sayess

Doctoral Dissertations

The focus of this work has been placed is on iodinated DBPs (I-DBPs), measured using total organic iodine (TOI), a surrogate measure of iodinated organics. This is due to the growing toxicity literature that places I-DBPs among the most toxic of all DBPs. To measure TOI in water, a new method was developed. This method combines adsorption, combustion, and trapping of combustion products, with an offline inductively coupled plasma/mass spectrometer (ICP-MS) for iodide detection. Three factors were varied across two levels each in order to optimize the method. The chosen method used a sample pH of less than 1 prior …

Contributing Factors To Child Stunting In Guatemala: A Systems Analysis Focused On Enteric Disease Transmission And Mycotoxin Exposure, Lee Emerson Voth-Gaeddert

Doctoral Dissertations

"Child stunting -- low height-for-age -- is a United Nation's indicator for chronic malnutrition that has been linked to both acute and chronic health problems. Data from Guatemala suggests for children under five years of age, 49% are classified as stunted. This dissertation tests the following hypotheses, among children in Guatemala 1) environmental enteric dysfunction (EED) is correlated with height-for-age, 2) aflatoxin B (AFB) exposure is correlated with height-for-age, and 3) AFB exposure is correlated with EED. A network analysis was conducted on data from the US Agency for International Development (USAID) collected in 2012 to identify trends in a …

Phytoforensics: Applications In Vapor Intrusion Assessment, Jordan Lee Wilson

Doctoral Dissertations

"Vapor intrusion (VI) occurs when contaminants in the vapor phase migrate in the shallow subsurface and enter buildings through cracks, seams, and gaps and has been recognized as a serious human-health threat as occupants are exposed to potentially harmful concentrations over long periods of time. The VI pathway has recently (2017) been identified as a primary exposure pathway and implemented into the Hazard Ranking System for inclusion on the Nation Priorities List. However, assessing VI and human exposure is not simple and current methods are time-, cost-, and labor-intensive; intrusive; and temporally and spatially variability. Trees are ideal candidates for …

Bioremediation Of Chlorinated Ethenes: Ph Effects, Novel Dechlorinators And Decision-Making Tools, Yi Yang

Doctoral Dissertations

Chlorinated solvents have been widely used in different areas of modern society. Usage of these chlorinated solvents was not necessarily accompanied with proper handling and disposal of these hazardous compounds, which caused a variety of environmental problems and continues to affect human health. Remediation of chlorinated ethenes contaminated sites has high priority for state regulators and site owners. Among the available treatment technologies, bioremediation shows great promise as a cost-effective corrective strategy for a variety of environmental pollutants. Prerequisites are that the microbiology involved in contaminant degradation and geochemical factors, such as pH, are understood, so that bioremediation technologies can …

Potential Emissions And Exposures Of Toxic Organics From Storage Tanks For Chemical Additions In Hydraulic Fracturing: A Modeling Approach, Huan Chen

Doctoral Dissertations

Hydraulic fracturing has promoted the exploitation of natural gas in the United States (U.S.). However, the storing and emptying of chemical additives in hydraulic fracturing wells may pose adverse effects through inhalation exposures. Based on the information about hydraulic fracturing fluids, this study investigated: 1) water volumes used to mix chemical additives for making up the hydraulic fracturing fluids; 2) chemical species, concentrations and their degradability in the hydraulic fracturing fluids; 3) emissions of organics from chemical storage tanks; and 4) the occupational inhalation exposures by toxic and organic vapors.

Results shows for 80,047 wells fractured between 2008 and 2014 …

The Fate Of Haloacetonitriles In Drinking Waters, Yun Yu

Doctoral Dissertations

The fate of HANs in drinking waters from their precursors in natural waters to their degradation products in consumers’ tap were systematically investigated in this study. Combined amino acids were proved reactive with chlorine to form DCAN under typical drinking water conditions. However, the rate of DCAN formation from bound aspartyl residues was much slower compared to free aspartic acid. The key to DCAN formation from combined amino acids was a chlorine-induced peptide degradation process, which slowly degraded the peptide backbone to continuously produce reactive amine functional groups at the N-terminal end. Particularly, when an N-terminal aspartyl residue …

Integrated Urban Metabolism Analysis Tool (Iumat), Nariman Mostafavi

Doctoral Dissertations

A number of tools are available today for simulating different aspects of urban activity, but these efforts are fragmented and do not effectively reflect the interrelationships between very diverse groups of urban sectors and resource flows. There is a critical need for robust and reliable urban metabolism analysis tools that integrate socio-economic elements of urbanization and physicality of the built environment into evaluating sustainability in cities. This dissertation outlines the development of an Integrated Urban Metabolism Analysis Tool (IUMAT) that dynamically measures the environmental impacts of land cover, transportation, and consumption of energy, water and materials employing a holistic framework. …

Predictive Modeling Of Riverine Constituent Concentrations And Loads Using Historic And Imposed Hydrologic Conditions, Mark Hagemann

Doctoral Dissertations

This research was principally concerned with the task of quantifying dissolved and suspended constituents carried in river water when direct measurements are not available. This is a question of scientific and societal relevance, and one with a long history of study and a great deal of remaining difficulty. The traditional approach to estimating these quantities, linear regression models (LMs), suffers from poor flexibility and high subsequent bias in many applications. This research applied semiparametric generalized additive models (GAMs), a more flexible class of regression models, evaluated their performance in various locations and conditions, and applied them in a proactive modeling …

The Stability Of Ferrate(Vi) In Water And Its Impacts On Disinfection Byproduct Precursors, Yanjun Jiang

Doctoral Dissertations

Ferrate has been proposed as an alternative pre-oxidant in drinking water treatment for many years. Despite extensive studies that examined ferrate oxidation of specific contaminants, little research has been done on the impacts of ferrate in raw waters that include natural organic matter (NOM) and bromide, and that are also treated with coagulants and chlorine. The future of ferrate as a potable water treatment chemical depends on its ability to achieve adequate disinfection while minimizing the formation of disinfection byproducts (DBPs) under these realistic scenarios. In this work, laboratory-scale treatment studies were conducted to (1) clarify the stability of ferrate …

Proactive Assessment Of Climate Change And Contaminant Spill Impacts On Source Water Quality, Lillian C. Jeznach

Doctoral Dissertations

Managing the water quality of surface drinking water sources has become an increasingly difficult task for water suppliers due to increased watershed urbanization and climate change. Changes in source water quality may affect public perceptions, treatment effectiveness, and ultimately costs to treat water to drinking standards. Although there are increased threats to current and future drinking water quality, current approaches to managing these threats are typically reactionary. Prior detailed modeling efforts of hypothetical events that may impair raw water quality allow for an understanding of constituent fate and transport, including potential maximum concentrations and travel times to the drinking water …

Response Of Microbial Community Structure To Clay Flocculation Of Harmful Algal Blooms, Chunyi Chen

Doctoral Dissertations

Harmful algal blooms are cosmopolitan and can produce extremely dangerous toxins that can sicken or kill people and animals, and create dead zones in the water. The U.S. economic loss caused by algal blooms is $82 million every year. Clay-based flocculation techniques have been developed to mitigate algal blooms; however, the potential impacts on the microbial community are poorly understood. This dissertation includes multi-scale experiments (Jar, field, microcosms) to study the response of microbial community structure and function to clay flocculation of algal blooms.

Jar tests of removal of Microcystis aeruginosa by chitosan and two types of commercially available clays …

Investigation Of Effluent Nitrogen Derived From Conventional Activated Sludge (Cas) And Biological Nutrient Removal (Bnr) Systems And Its Impact On Algal Growth In Receiving Waters, Heonseop Eom

Doctoral Dissertations

The main objective of this research was to evaluate the effects of effluent nitrogen from conventional activated sludge (CAS) and biological nutrient removal (BNR) processes on eutrophication in receiving estuaries. To investigate differences in effluent nitrogen from CAS and BNR processes, lab-scale wastewater treatment systems having identical influent were operated under controlled conditions. This reactor study showed that the BNR system decreased nitrogen discharge by removing dissolved inorganic nitrogen (DIN) from wastewater but generated more effluent dissolved organic nitrogen (DON) than did the CAS system. The transition of treatment conditions from anoxic to oxic within the BNR process facilitated the …

Assessment Of Biomass Burning And Mineral Dust Impacts On Air Quality And Regional Climate, Xinyi Dong

Doctoral Dissertations

East Asia is frequently influenced by dust storms and biomass burning. This study conducts a comprehensive investigation of its kind based on data analysis with surface measurements, satellite products, and model simulations. The objective of this study is to improve the understanding of the impacts of biomass burning and dust on air quality and regional climate. The study period covers March and April from 2006 to 2010. Biomass burning from Peninsular Southeast Asia (PSEA) has significant annual variations by up to 60% within the study period. The impact of biomass burning on air quality is mainly confined within the upper …

Evaluation Of Ferrate Preoxidation For Drinking Water Treatment, Joseph E. Goodwill

Doctoral Dissertations

Ferrate (Fe(IV)) has been proposed as a viable alternative for pre-oxidation in drinking water treatment (Jiang & Lloyd, 2002; Sharma, Kazama, Jiangyong, & Ray, 2005). The primary advantages of ferrate include a strong oxidation potential without the formation of halogenated by-products. In addition, the by-product of ferrate oxidation, ferric iron (Fe(III)), may have beneficial impacts on downstream particle destabilization and removal processes. Also, ferrate has disinfectant properties and may also provide pathogen inactivation in drinking water (Sharma et al., 2005). However, despite these advantages, there is a dearth of research experience that examines the implications of using ferrate for treating …

Toward Understanding The Physiological Determinants Of Microbial Competitiveness In Methanogenic Processes, Si Chen

Doctoral Dissertations

Methanogenesis is of great significance in both natural and engineered processes. Anaerobic digestion technology represents the engineering-scale implementation of methanogenesis in waste treatment processes. Despite the broad application of anaerobic digestion as a common waste treatment option, much remains to be learned on the anaerobic food web underlying methanogenesis for more effective process modeling and control.

Following an initial screening of various substrates, six continuous lab-scale anaerobic digesters were developed with animal waste as the substrate. The linkage between microbial community composition and process performance was studied by initiating process imbalance with organic overloading. As a result, accumulation of short …

Impacts Of Climate Change On The Evolution Of The Electrical Grid, Melissa Ree Allen

Doctoral Dissertations

Maintaining interdependent infrastructures exposed to a changing climate requires understanding 1) the local impact on power assets; 2) how the infrastructure will evolve as the demand for infrastructure changes location and volume and; 3) what vulnerabilities are introduced by these changing infrastructure topologies. This dissertation attempts to develop a methodology that will a) downscale the climate direct effect on the infrastructure; b) allow population to redistribute in response to increasing extreme events that will increase under climate impacts; and c) project new distributions of electricity demand in the mid-21^st century.

The research was structured in three parts. The first …

Stability, Erosion, And Morphology Considerations For Sustainable Slope Design, Isaac Andres Jeldes Halty

Doctoral Dissertations

The construction of more natural and sustainable earth slopes requires the consideration of erosion and runoff characteristics as an integral part of the design. These effects not only result in high costs for removal of sediment, but also a profound damage to the ecosystem. In this dissertation, innovative techniques are developed such that more natural appearing slopes can be designed to minimize sediment delivery, while meeting mechanical equilibrium requirements. This was accomplished by: a) examining the fundamental failure modes of slopes built with minimum compaction (FRA) to enhance quick establishment of forest, b) investigating the geomechanical and erosion stability of …

Evaluating Predictability In The Community Earth System Model In Response To The Eruption Of Mount Pinatubo, Abigail Laurel Gaddis

Doctoral Dissertations

A central goal of climate research is to determine the perceptible effects of climate change on humans; in other words, the regional and decadal scale effects of carbon dioxide forcing. Identifying the most pronounced and long-lasting responses of climate variables to forcing is important for decadal prediction since forcing terms are a source of predictability on those time scales. Powerful volcanic eruptions provide a transient forcing on the climate system, creating a test bed for climate models. In this study, the Mount Pinatubo eruption is simulated in the Community Earth System Model, CESM1.0, for three model configurations: fully coupled T85 …

Industrial Robustness: Understanding The Mechanism Of Tolerance For The Populus Hydrolysate Tolerant Strain Of Clostridium Thermocellum, Jessica Leigh Linville

Doctoral Dissertations

An industrially robust microorganism that can efficiently degrade and convert lignocellulosic biomass into ethanol and next-generation fuels is required to economically produce future sustainable liquid transportation fuels. The anaerobic, thermophilic, cellulolytic bacterium Clostridium thermocellum is a candidate microorganism for such conversions but it, like many bacteria, is sensitive to potential toxic inhibitors developed in the hydrolysate produced during biomass processing. Microbial processes leading to tolerance of the inhibitory compounds found in the pretreated biomass hydrolysate are likely complex and involve multiple genes. In this study, a 17.5% v/v Populus hydrolysate tolerant mutant strain of C. thermocellum was developed by directed …

Investigating The Prediction Of High Resolution Heat Waves And Extreme Precipitation And The Impact Of Heat Waves On Air Quality In U.S. In The 21st Century, Yang Gao

Doctoral Dissertations

In this study, the perennial problem of scale is addressed with an updated set of modeling tools that include global climate, atmospheric chemistry simulation, mesoscale weather, and air quality simulations. The evaluation of coupled model performance across geographic scales and the assessment of local scale climate change impacts under a fossil fuel intensive climate change scenario Representative Concentration Pathway (RCP 8.5) was achieved by linking the global climate model Community Earth System Model (CESM), with the regional climate model Weather Research and Forecasting (WRF) Model. This study is the first evaluation of dynamical downscaling using WRF on a 4km by …

Study Of The Driving Cycle For Heavy Duty Trucks In Hilly Terrain And Its Effect On Calculated Emissions, And Comparison Of Two Mobile Emission Models, Jeongran Yun

Doctoral Dissertations

Vehicle emissions were estimated using MOVES2010a and MOBILE6.2 for a Pittsburgh case study involving a modal shift in freight transportion. MOVES2010a (hereafter referred to as MOVES) is currently the USEPA official mobile source emissions computer model; it replaced the older model, MOBILE6.2. Changing the method of hauling freight from highway to waterway is the transport modal shift. Results from this part of the study showed that emission estimates for all vehicle types using MOVES were higher than emissions estimated using MOBILE6.2/NMIM for CO, NO_X, PM₁₀, PM_2.5, and VOC, but emissions were lower for CO …

Hydrologic Reconstructions Using Dendroclimatology, Climate Signals, And Pacific Ocean Sea Surface Temperature Variability, Sallyrose Anderson

Doctoral Dissertations

The Colorado River provides water to over 25 million people. Given the importance of this water supply, it is critical to understand the hydrologic variables in the Colorado River Basin. In this dissertation, I reconstructed hydrologic conditions (soil moisture, snowpack) in the Upper Colorado River Basin (UCRB) and examined different factors that influence water supply in the region (climate oscillations, oceanic-atmospheric variability).

Firstly, I reconstructed soil moisture in the UCRB. Principal components analysis (PCA) and k-Nearest Neighbor (k-NN) techniques were used to regionalize the gridded data. Correlated tree-ring chronologies (TRCs) were used as predictor variables in stepwise linear regression (SLR) …

Hydrology, Soil Erosion And Climate Interactions On Low Compaction Steep-Sloped Reclaimed Sites In The Southern Appalachian Coal Fields, Tennessee, Siavash Hoomehr

Doctoral Dissertations

The use of loose spoil on steep slopes for surface coal mining reclamation sites has been promoted by the US Department of Interior, Office of Surface Mining for the establishment of native forest. Although low-compaction spoils improve tree survival and growth, the erodibility and hydrology of steep slopes may change due to this practice. The purpose of this study was to quantify the erodibility (K factor), and the Curve Number (CN) value for low compaction, steep-sloped (> 20%) reclaimed mine lands in the Appalachian region, USA. This study also investigated the performance of the SEDCAD model in estimating erosion and …