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Environmental Engineering

Dissertations

2005

Magnetron sputtering

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Corrosion Studies On Alpha Tantalum And Beta Tantalum Coated Steel, Sung Min Maeng Jan 2005

Corrosion Studies On Alpha Tantalum And Beta Tantalum Coated Steel, Sung Min Maeng

Dissertations

Tantalum coating by sputtering, one form of physical vapor deposition (PVD), has been investigated as a replacement for chromium coatings on gun bores to protect them from erosion and corrosion due to its high ductility and high corrosion resistance in aggressive environments. When deposited as a film on steel substrates by sputtering, either α-Ta, β-Ta, or a mixture of both phases have been observed under varying deposition conditions. To evaluate corrosion behavior of Ta coatings, electrochemical impedance spectroscopy and potentiodynamic polarization were conducted as a function of coating thickness. The coating porosity was observed to decrease with increasing coating thickness …