Engineering Commons^™

Heavy Metal Adsorption On Iron Oxide And Iron Oxide-Coated Silica : Macroscopic, Spectroscopic, And Modeling Studies, Ying Xu

Dissertations

To accurately model metal mobility and bioavailability in soils and sediments, systematic sorption studies are needed using representative and well-characterized minerals. Two important surfaces are iron oxide and silica, which are ubiquitous and associated with one another in the environment playing important roles in metal distribution. The objectives of this research are to develop models for predicting speciation and mobility of toxic trace metal ions in groundwater, soils, and sediments when competing ions are present. A model system for soils and sediments, iron oxide-coated silica, was synthesized; the degree of coatings was highly sensitive to the particle size of silica …

Development Of Adsorption Filtration Process For Virus Removal For Drinking Water Treatment, Vishal Vijay Gawarikar

Dissertations

Recent monitoring studies have indicated that many ground water (GW) sources would benefit from the development of effective technologies for removing viruses. Although reverse osmosis can achieve high log removal it is not economical. The main objective of this study is to test and validate a novel adsorption filtration (AF) technology for removing viruses from GW sources for drinking water production in New Jersey.

The convective diffusion of viruses to adsorbent particle surfaces in flow packed beds (FPB) enhances their removal efficiency if the adsorbent particle size can be decreased to about 100 microns. The development of effective virus removal …

Corrosion Studies On Alpha Tantalum And Beta Tantalum Coated Steel, Sung Min Maeng

Dissertations

Tantalum coating by sputtering, one form of physical vapor deposition (PVD), has been investigated as a replacement for chromium coatings on gun bores to protect them from erosion and corrosion due to its high ductility and high corrosion resistance in aggressive environments. When deposited as a film on steel substrates by sputtering, either α-Ta, β-Ta, or a mixture of both phases have been observed under varying deposition conditions. To evaluate corrosion behavior of Ta coatings, electrochemical impedance spectroscopy and potentiodynamic polarization were conducted as a function of coating thickness. The coating porosity was observed to decrease with increasing coating thickness …

Development And Application Of Fractionation Procedure For Drinking Water Organic Matters, Yong Pu

Dissertations

USEPA mandates a control of disinfection by-products (DBPs) in finished drinking water and recommends reduction of natural organic matters (NOM), DBP precursors, to achieve this regulatory goal. Studies relating NOM with DBP include fractionation of water samples, characterization of collected organic fractions, fractions' formation potential tests, and jar or similar tests to remove NOM. This study discussed a current resin fractionation procedure on principle, procedure, and its efficiency when applied to water samples of low NOM (< 5mgIL). The primary objective of this research is to develop a fractionation procedure intended for water of low NOM by carefully applying mass balance concept through each fraction's fractionation and a selection of stable ion exchange resins. A new protocol was presented with triple columns of XAD-8 adsorption resin, one column of AG-MP-50 cationic resin, and another column of WA 10 weak anionic resin in sequence. This protocol was experimented and confirmed for its efficiency (±10% loss of mass) with samples from Canal Road (CR) and Raritan Millstone (RM) surface water treatment plants (WTPs) in central New Jersey. The second objective of this study is to develop a statistical model with a potential of online delineation of organic fractions of NOM. The resulting model based on samples of Passaic Valley Water Commission (PVWC) WTP in northern New Jersey was applied to predict organic fractions of samples from CR and RM plants. Paired T-test (paired t ratio 1.15 < t critical 2.02) indicated a good correlation between the predicted and actual fraction concentration. Finally, samples of Middlesex Water Company (MWC) were fractionated and Trihalomethane formation potential tests (THMFP) on collected fraction showed hydrophilic matters possessed a higher potential to produce TTHM in finished water than hydrophobic matter. Jar tests indicated while coagulation was effective in removing hydrophobic matter, it may not be optimum for removal of hydrophilic matter.

This study developed an accurate fractionation procedure for low NOM waters. It provided a better understanding of organic matter transformation at different treatment …

Tide-Influenced Contaminant Transport In Coastal Aquifers, Yong Peng

Dissertations

Coastal aquifers are distinguished from other aquifers because of tidal effects which cause complicated groundwater flow and contaminant transport phenomena in regions immediately adjacent to the coast. This study is designed to address the significance of tidal influence on contaminant transport by focusing on one-dimensional homogeneous coastal aquifers.

This study formulates a conceptual model and corresponding flow and transport equations, analyzes coastal boundary conditions, solves numerically the transport equation, and uses experiments to verify the numerical results.

Results of numerical and experimental studies conclude that tides can have a significant impact on contaminant transport, especially when under unconfined conditions, subject …