Engineering Commons^™

Design And Fabrication Of A Trapped Ion Quantum Computing Testbed, Christopher A. Caron

Masters Theses

Here we present the design, assembly and successful ion trapping of a room-temperature ion trap system with a custom designed and fabricated surface electrode ion trap, which allows for rapid prototyping of novel trap designs such that new chips can be installed and reach UHV in under 2 days. The system has demonstrated success at trapping and maintaining both single ions and cold crystals of ions. We achieve this by fabricating our own custom surface Paul traps in the UMass Amherst cleanroom facilities, which are then argon ion milled, diced, mounted and wire bonded to an interposer which is placed …

Thermal Transport Across 2d/3d Van Der Waals Interfaces, Cameron Foss

Doctoral Dissertations

Designing improved field-effect-transistors (FETs) that are mass-producible and meet the fabrication standards set by legacy silicon CMOS manufacturing is required for pushing the microelectronics industry into further enhanced technological generations. Historically, the downscaling of feature sizes in FETs has enabled improved performance, reduced power consumption, and increased packing density in microelectronics for several decades. However, many are claiming Moore's law no longer applies as the era of silicon CMOS scaling potentially nears its end with designs approaching fundamental atomic-scale limits -- that is, the few- to sub-nanometer range. Ultrathin two-dimensional (2D) materials present a new paradigm of materials science and …

Electrothermal Properties Of 2d Materials In Device Applications, Samantha L. Klein

Masters Theses

To keep downsizing transistors, new materials must be explored since traditional 3D materials begin to experience tunneling and other problematic physical phenomena at small sizes. 2D materials are appealing due to their thinness and bandgap. The relatively weak van der Waals forces between layers in 2D materials allow easy exfoliation and device fabrication but they also result in poor heat transfer to the substrate, which is the main path for heat removal. The impaired thermal coupling is exacerbated in few-layer devices where heat dissipated in the layers further from the substrate encounters additional interlayer thermal resistance before reaching the substrate, …

Planar Ultra-Wideband Modular Antenna (Puma) Arrays For High-Volume Manufacturing On Organic Laminates And Bga Interfaces, James R. Lacroix

Masters Theses

This work proposes wideband and broadband Planar Ultra-wideband Modular Antenna (PUMA) arrays designed to improve cost and reliability for high production volume commercial and military applications. The designs feature simplified PCB stack-ups with high dielectric constant (Dk) dimensionally stable materials to improve the manufacturing cost and yield. Additionally, the packages use ball grid array (BGA) interconnects, commonly used in digital electronics, for simple solder reflow integration with radio frequency (RF) electronics. While high Dk materials present practical manufacturing benefits, theoretical background will show how and why PUMA arrays lose frequency bandwidth and scan volume with high Dk materials. Further, a …

Tailoring Interfaces And Composition For Stable And Efficient Perovskite Solar Cells, Hamza Javaid

Doctoral Dissertations

Metal halide perovskite solar cells (PSCs) have revolutionized the field of thin film photovoltaics. Within a decade, the power conversion efficiencies (PCEs) have increased at a phenomenal rate, rising from 3.8% to more than 25% in single-junction devices, moving them ahead of the current silicon-based technology. The high efficiencies of perovskite solar cells (PSCs) and their other unique properties arise from a combination of organic and inorganic components and electronic-ionic conduction, making them excellent candidates for a plethora of applications. However, PSCs face a significant—and ironic—roadblock to commercialization: these light-harvesting materials degrade under sunlight—the very condition they would need …

Modeling And Characterization Of Optical Metasurfaces, Mahsa Torfeh

Masters Theses

Metasurfaces are arrays of subwavelength meta-atoms that shape waves in a compact and planar form factor. During recent years, metasurfaces have gained a lot of attention due to their compact form factor, easy integration with other devices, multi functionality and straightforward fabrication using conventional CMOS techniques. To provide and evaluate an efficient metasurface, an optimized design, high resolution fabrication and accurate measurement is required. Analysis and design of metasurfaces require accurate methods for modeling their interactions with waves. Conventional modeling techniques assume that metasurfaces are locally periodic structures excited by plane waves, restricting their applicability to gradually varying metasurfaces that …

Towards Higher Power Factor In Semiconductor Thermoelectrics: Bandstructure Engineering And Potential Barriers, Adithya Kommini

Doctoral Dissertations

To keep up with the current energy demand and to sustain the growth requires efficient use of existing resources. One of the ways to improve efficiency is by converting waste heat to electricity using thermoelectrics. Thermoelectric devices work on the principle of Seebeck effect, where an applied temperature difference across the material results in a potential difference in the material. The possibility of drastic improvements in the efficiency of thermoelectric (TE) devices using semiconductor nanostructured materials renewed interest in thermoelectrics over the last three decades. Introducing confinement, interfaces, and quantum effects using nanostructures for additional control of charge and phonon …

On Improving Robustness Of Hardware Security Primitives And Resistance To Reverse Engineering Attacks, Vinay C. Patil

Doctoral Dissertations

The continued growth of information technology (IT) industry and proliferation of interconnected devices has aggravated the problem of ensuring security and necessitated the need for novel, robust solutions. Physically unclonable functions (PUFs) have emerged as promising secure hardware primitives that can utilize the disorder introduced during manufacturing process to generate unique keys. They can be utilized as \textit{lightweight} roots-of-trust for use in authentication and key generation systems. Unlike insecure non-volatile memory (NVM) based key storage systems, PUFs provide an advantage -- no party, including the manufacturer, should be able to replicate the physical disorder and thus, effectively clone the PUF. …

Metasurface Design And Optimization With Adjoint Method, Mahdad Mansouree

Doctoral Dissertations

The invention and advancement of optical devices have tremendously changed our life. Devices such as cameras, displays and optical sensors are now an integral part of our lives. Moreover, with the rapid growth in new markets such as virtual reality (VR), augmented reality (AR), autonomous vehicles and internet of things (IoT) the need for optical devices is expected to grow considerably. Recent advances in nano-fabrication techniques have spurred a new wave of interest in optical metasurfaces. Metasurfaces are arrays of wisely selected nano-scattereres that generate desired transformation on the incident light. Metasurfaces provide a new platform for the development of …

Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya

Doctoral Dissertations

The need for alternative energy sources has led to extensive research on optimizing the conversion efficiency of thermoelectric (TE) materials. TE efficiency is governed by figure-of-merit (ZT) and it has been an enormously challenging task to increase ZT > 1 despite decades of research due to the interdependence of material properties. Most doped inorganic semiconductors have a high electrical conductivity and moderate Seebeck coefficient, but ZT is still limited by their high lattice thermal conductivity. One approach to address this problem is to decrease thermal conductivity by means of alloying and nanostructuring, another is to consider materials with an inherently low …

Electro-Thermal Transport In Two-Dimensional Materials And Their Heterostructures, Arnab K. Majee

Doctoral Dissertations

”Smaller is better” is the mantra that has driven semiconductor industry for the past 50 years. The on-going quest for faster electronic switching, higher transistor density, and better device performance, has been driven by a self-fulfilling prophecy popularly known as Moore’s law, according to which the number of transistors per unit area of a chip doubles itself approximately every two years. A modern smartphone has about 8 billion transistors, which is as large as current earth’s population. Although each transistor dissipates negligible power, but the collective power dissipation from all the transistors in an electronic gadget and inefficient heat removing …

Low-Energy Memristors & High-Nonlinearity Selector For Dense Passive Cross-Bar Arrays, Navnidhi K. Upadhyay

Doctoral Dissertations

Memristor or RRAM (Resistive Random Access Memory) based crossbar array architecture (CBA) is considered a leading contender for the next-generation non-volatile memory (NVM) as well as for future computing paradigms, such as in-memory computing, neuromorphic computing, neural networks, analog computing, reconfigurable computing, etc. Among many other attractive properties, memristors’ simple and dense 3D stackable structure is an essential enabler of these promising applications. However, the simplicity and high density of CBA comes at a price. CBA suffers from the so-called sneak path currents flowing through the unselected cells, which severely affects the read margin, makes CBA more power-hungry, increases the …

Thermal Transport Modeling Of Semiconductor Materials From First Principles, Aliya Qureshi

Masters Theses

Over the past few years, the size of semiconductor devices has been shrinking whereas the density of transistors has exponentially increased. Thus, thermal management has become a serious concern as device performance and reliability is greatly affected by heat. An understanding of thermal transport properties at device level along with predictive modelling can lead us to design of new systems and materials tailored according to the thermal conductivity. In our work we first review different models used to calculate thermal conductivity and examine their accuracy using the experimentally measured thermal conductivity for Si. Our results suggest that empirically calculated rates …

Molecular Design Of Organic Semiconductors For Interfacial And Emissive Material Applications, Marcus David Cole

Doctoral Dissertations

This dissertation describes the synthesis and characterization of functional optoelectronically active materials. Synthetic techniques were used to prepare polymers containing perylene diimide (PDI) or tetraphenylethylene (TPE) moieties in the polymer backbone. PDI-based structures were prepared with embedded cationic or zwitterionic moieties intended to tailor organic/inorganic interfaces in thin film photovoltaic devices. The aggregation-induced emission (AIE)-active TPE polymers were synthesized to study how AIE properties evolve in π-conjugated polymers. The syntheses discussed here focused on modulation of molecular architecture to give rise to materials with tailored optoelectronic properties. Chapter 1 provides a brief overview of the field of organic electronics and …

Direct Printing Of Conductive Inks For Organic Electronics And Wearable Microfluidics, Aditi Naik

Doctoral Dissertations

This dissertation examines the direct printing of conductive inks on polymeric substrates for applications in organic electronics, microfluidic valving systems, and wearable sweat sensors. The inexpensive production of solution-based electrodes with high electrical conductivity is necessary to enable the next-generation of printed, flexible, and organic electronics. Specifically, the optimization and printing of liquid-phase graphene ink and nanoparticle-based silver ink by soft nanoimprint lithography and inkjet-printing is discussed to achieve printed functional devices. Using scalable low-cost patterning systems, these flexible applications are compatible with roll-to-roll processing, enabling large-scale manufacturing. This research expands the knowledge of high-resolution printing optimization for the direct …

Energy Efficiency Of Computation In All-Spin Logic: Projections And Fundamental Limits, Zongya Chen

Masters Theses

Built with nanomagnets, a spintronic device called the all-spin logic (ASL) device carries information with only spin currents, resulting in a low power supply--10 mV. This voltage is 100 times smaller than the conventional CMOS devices (usually 0.8~1V). The potential for improved energy efficiency made possible by the low operating voltage of ASL makes it one of the most promising devices among its post-CMOS competitors.

The basic working principles of ASL device are introduced in this thesis and two complementary approaches to studying energy efficiency of computation are applied to a common set of ASL circuits: (1) a circuit simulation …

Parallel Algorithms For Time Dependent Density Functional Theory In Real-Space And Real-Time, James Kestyn

Doctoral Dissertations

Density functional theory (DFT) and time dependent density functional theory (TDDFT) have had great success solving for ground state and excited states properties of molecules, solids and nanostructures. However, these problems are particularly hard to scale. Both the size of the discrete system and the number of needed eigenstates increase with the number of electrons. A complete parallel framework for DFT and TDDFT calculations applied to molecules and nanostructures is presented in this dissertation. This includes the development of custom numerical algorithms for eigenvalue problems and linear systems. New functionality in the FEAST eigenvalue solver presents an additional level of …

Skybridge-3d-Cmos: A Fine-Grained Vertical 3d-Cmos Technology Paving New Direction For 3d Ic, Jiajun Shi

Doctoral Dissertations

2D CMOS integrated circuit (IC) technology scaling faces severe challenges that result from device scaling limitations, interconnect bottleneck that dominates power and performance, etc. 3D ICs with die-die and layer-layer stacking using Through Silicon Vias (TSVs) and Monolithic Inter-layer Vias (MIVs) have been explored in recent years to generate circuits with considerable interconnect saving for continuing technology scaling. However, these 3D IC technologies still rely on conventional 2D CMOS’s device, circuit and interconnect mindset showing only incremental benefits while adding new challenges reliability issues, robustness of power delivery network design and short-channel effects as technology node scaling. Skybridge-3D-CMOS (S3DC) is …

Analog Signal Processing Solutions And Design Of Memristor-Cmos Analog Co-Processor For Acceleration Of High-Performance Computing Applications, Nihar Athreyas

Doctoral Dissertations

Emerging applications in the field of machine vision, deep learning and scientific simulation require high computational speed and are run on platforms that are size, weight and power constrained. With the transistor scaling coming to an end, existing digital hardware architectures will not be able to meet these ever-increasing demands. Analog computation with its rich set of primitives and inherent parallel architecture can be faster, more efficient and compact for some of these applications. The major contribution of this work is to show that analog processing can be a viable solution to this problem. This is demonstrated in the three …

Memristive Nanodevices And Arrays: Scaling And Novel Applications, Shuang Pi

Doctoral Dissertations

This dissertation addresses the challenges for device scaling and novel application of nanoscale memristive devices and device arrays through demonstrating the first working sub-10 nm memristor array, the first ultra-dense atomic scale working memristor array and the first high performance nanoscale radiofrequency switch based on memristive devices. Nanoimprint lithography is used to generate the sub-10 nm cross-point memristor array. The imprint mold with sub-10 nm features is generated by using wet chemical method to shrink the larger features on a master mold. The imprinting, pattern transfer and metallization process are closely monitored to enforce optimal conditions for sub-1 nm critical …

Materials Engineering, Switching Mechanism And Novel Applications Of Memristive Devices, Hao Jiang

Doctoral Dissertations

Memristive devices have attracted tremendous interests because of their highly desirable properties such as a simple structure, low switching voltage, fast switching speed, excellent scalability, multiple conductance states and great compatibility with the Complementary Metal–Oxide–Semiconductor technology. Hence, they stand out as promising candidates for next-generation non-volatile memory and electronic synapses in artificial neural network. This thesis reports systematic studies of the memristive switching phenomena in oxide based material systems, in aspects of materials engineering, switching mechanism and novel applications. We demonstrated efficient ways of engineering device performances such as metal doping and further presented a highly reliable hafnium oxide based …

Analog Computing Using 1t1r Crossbar Arrays, Yunning Li

Masters Theses

Memristor is a novel passive electronic device and a promising candidate for new generation non-volatile memory and analog computing. Analog computing based on memristors has been explored in this study. Due to the lack of commercial electrical testing instruments for those emerging devices and crossbar arrays, we have designed and built testing circuits to implement analog and parallel computing operations. With the setup developed in this study, we have successfully demonstrated image processing functions utilizing large memristor crossbar arrays. We further designed and experimentally demonstrated the first memristor based field programmable analog array (FPAA), which was successfully configured for audio …

Analyses Of Densely Crosslinked Phenolic Systems Using Low Field Nmr, Jigneshkumar Patel

Doctoral Dissertations

A uniform dispersion of reactants is necessary to achieve a complete reaction involving multi-components, especially for the crosslinking of rigid high-performance materials. In these reactions, miscibility is crucial for curing efficiency. This miscibility is typically enhanced by adding a third component, a plasticizer. For the reaction of the highly crystalline crosslinking agent hexamethylenetetramine (HMTA) with a strongly hydrogen-bonded phenol formaldehyde resin, furfural has been traditionally used as the plasticizer. However, the reason for its effectiveness is not clear. In this doctoral thesis work, miscibility and crosslinking efficiency of plasticizers in phenolic curing reactions are studied by thermal analysis and spectroscopic …

Three-Dimensional Memristor Integrated Circuits And Applications, Peng Lin

Doctoral Dissertations

New computing paradigms are highly demanded in the “Big Data” era to efficiently process, store and extract useful information from overwhelmingly rich amount of data. New computing systems based on large scale memristor circuits emerges as a very promising candidate due to its capability to both store and process information, thus eliminating the von Neumann bottleneck in the conventional complementary metal oxide semiconductor (CMOS) based computers. As the lateral scaling of the device geometry approaching its physical limit, three-dimensional stacking of multiple device layers becomes necessary to further increase the packing density. Moreover, innovations in the 3D circuits design can …

Dynamic Range Limitations Of Low-Noise Microwave Transistors At Cryogenic Temperatures, Ahmet Hakan Coskun

Doctoral Dissertations

Dynamic range is an important metric that specifies the limits of input signal amplitude for the ideal operation of a given receiver. The low end of dynamic range is defined by the noise floor whereas the upper limit is determined by large-signal distortion. While dynamic range can be predicted in the temperature range where compact transistor models are valid, the lack of large-signal models at temperatures below -55 C prevents the prediction and optimization of dynamic range for applications that require cryogenic cooling. For decades, the main goal concerning the performance of these applications was lowering the noise floor of …

The Impact Of Quantum Size Effects On Thermoelectric Performance In Semiconductor Nanostructures, Adithya Kommini

Masters Theses

An increasing need for effective thermal sensors, together with dwindling energy resources, have created renewed interests in thermoelectric (TE), or solid-state, energy conversion and refrigeration using semiconductor-based nanostructures. Effective control of electron and phonon transport due to confinement, interface, and quantum effects has made nanostructures a good way to achieve more efficient thermoelectric energy conversion. This thesis studies the two well-known approaches: confinement and energy filtering, and implements improvements to achieve higher thermoelectric performance. The effect of confinement is evaluated using a 2D material with a gate and utilizing the features in the density of states. In addition to that, …

Skybridge: A New Nanoscale 3-D Computing Framework For Future Integrated Circuits, Mostafizur Rahman

Doctoral Dissertations

Continuous scaling of CMOS has been the major catalyst in miniaturization of integrated circuits (ICs) and crucial for global socio-economic progress. However, continuing the traditional way of scaling to sub-20nm technologies is proving to be very difficult as MOSFETs are reaching their fundamental performance limits [1] and interconnection bottleneck is dominating IC operational power and performance [2]. Migrating to 3-D, as a way to advance scaling, has been elusive due to inherent customization and manufacturing requirements in CMOS architecture that are incompatible with 3-D organization. Partial attempts with die-die [3] and layer-layer [4] stacking have their own limitations [5]. We …

Architecting Np-Dynamic Skybridge, Jiajun Shi

Masters Theses

With the scaling of technology nodes, modern CMOS integrated circuits face severe fundamental challenges that stem from device scaling limitations, interconnection bottlenecks and increasing manufacturing complexities. These challenges drive researchers to look for revolutionary technologies beyond the end of CMOS roadmap. Towards this end, a new nanoscale 3-D computing fabric for future integrated circuits, Skybridge, has been proposed [1]. In this new fabric, core aspects from device to circuit style, connectivity, thermal management and manufacturing pathway are co-architected in a 3-D fabric-centric manner.

However, the Skybridge fabric uses only n-type transistors in a dynamic circuit style for logic and memory …

Architecting Skybridge-Cmos, Mingyu Li

Masters Theses

As the scaling of CMOS approaches fundamental limits, revolutionary technology beyond the end of CMOS roadmap is essential to continue the progress and miniaturization of integrated circuits. Recent research efforts in 3-D circuit integration explore pathways of continuing the scaling by co-designing for device, circuit, connectivity, heat and manufacturing challenges in a 3-D fabric-centric manner. SkyBridge fabric is one such approach that addresses fine-grained integration in 3-D, achieves orders of magnitude benefits over projected scaled 2-D CMOS, and provides a pathway for continuing scaling beyond 2-D CMOS.

However, SkyBridge fabric utilizes only single type transistors in order to reduce manufacture …

Development Of Infrared And Terahertz Bolometers Based On Palladium And Carbon Nanotubes Using Roll To Roll Process, Amulya Gullapalli

Masters Theses

Terahertz region in the electromagnetic spectrum is the region between Infrared and Microwave. As the Terahertz region has both wave and particle nature, it is difficult to make a room temperature, fast, and sensitive detector in this region. In this work, we fabricated a Palladium based IR detector and a CNT based THz bolometer.

In Chapter 1, I give a brief introduction of the Terahertz region, the detectors already available in the market and different techniques I can use to test my detector. In Chapter 2, I explain about the Palladium IR bolometer, the fabrication technique I have used, and …