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Full-Text Articles in Engineering

Faceted Nanomaterial Synthesis, Characterizations And Applications In Reactive Electrochemical Membrane Filtration, Qingquan Ma Dec 2022

Faceted Nanomaterial Synthesis, Characterizations And Applications In Reactive Electrochemical Membrane Filtration, Qingquan Ma

Dissertations

Facet engineering of nanomaterials, especially metals and metal oxides has become an important strategy for tuning catalytic properties and functions from heterogeneous catalysis to electrochemical catalysis, photocatalysis, biomedicine, fuel cells, and gas sensors. The catalytic properties are highly related to the surface electronic structures, surface electron transport characteristics, and active center structures of catalysts, which can be tailored by surface facet control. The aim of this doctoral dissertation research is to study the facet-dependent properties of metal or metal oxide nanoparticles using multiple advanced characterization techniques. Specifically, the novel atomic force microscope-scanning electrochemical microscope (AFM-SECM) and density functional theory (DFT) …


Morphology And Detection Of Corrosion On Stainless Steel Reinforcement In Concrete, Julio J. Saire Yanez Jun 2019

Morphology And Detection Of Corrosion On Stainless Steel Reinforcement In Concrete, Julio J. Saire Yanez

USF Tampa Graduate Theses and Dissertations

Stainless steel (SS) has emerged as an alternative corrosion-resistant reinforcement in concrete instead of the commonly used carbon steel (CS). The biggest advantage of SS is that it takes more time for corrosion to initiate than for CS. An additional benefit from the use of SS in concrete may be derived from the period after the corrosion started until the concrete structure reaches a limit state. This period is called corrosion propagation stage (CPS) and it has been hardly studied in SS reinforced structures. The duration of this period could be related, among other factors, to the morphology of corrosion …


Feasibility Of Cathodic Protection In Grouted Post Tensioned Tendons - Exploratory Model Calculations, Jacob Dharma Bumgardner Nov 2015

Feasibility Of Cathodic Protection In Grouted Post Tensioned Tendons - Exploratory Model Calculations, Jacob Dharma Bumgardner

USF Tampa Graduate Theses and Dissertations

Recent corrosion related failures of grouted post tensioned tendons, even after the introduction of improved grouts, have led to renewed interest in supplemental or backup means of corrosion control for these systems. A finite element model is presented to explore feasibility of impressed current cathodic protection of strand in grouted tendons. The model examines polarization evolution as function of service time and includes consideration of anode placement and size, grout porosity, pore water alkalinity, electrochemical species diffusivity and applied voltage on the polarization efficacy and durability of such a system. The exploratory model projections suggested that, within the context of …


Fundamentals Of Electro-Flotation And Electrophoresis And Applications In Oil Sand Tailings Management, Raquibul Alam Sep 2015

Fundamentals Of Electro-Flotation And Electrophoresis And Applications In Oil Sand Tailings Management, Raquibul Alam

Electronic Thesis and Dissertation Repository

This thesis addresses two challenges facing the management of mature fine tailings (MFT) from oil sand processing. The first challenge is the high concentration of residual bitumen in tailings ponds, which poses a hazard to aquatic biota and impact to the environment. A laboratory scale study is carried out to assess the suitability of electro-flotation (EF) for removal of bitumen from oil sand tailings slurry. The results of the study confirm that EF is effective to reduce bitumen contents of tailings slurry. At a current density 150 A/m2, the bitumen concentration is reduced from 106.8 mg/L to less …


The Theory Of Alloy Deposition And The Effect Of A Rotating Cathode Upon Such Deposition, With Special Attention To The Possibility Of Depositing Sterling Silver, Kenneth J. Stodden May 1941

The Theory Of Alloy Deposition And The Effect Of A Rotating Cathode Upon Such Deposition, With Special Attention To The Possibility Of Depositing Sterling Silver, Kenneth J. Stodden

Bachelors Theses and Reports, 1928 - 1970

In the past few years a great deal of atten­tion has been given to the electrodeposition of alloys. For the main part, this investigation has been of scien­tific interest only; but in a few instances, such work has attained commercial importance.