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Full-Text Articles in Engineering
A Model Compound Study In Syngas Tar Reforming, Jaren Lee
A Model Compound Study In Syngas Tar Reforming, Jaren Lee
LSU Master's Theses
Biomass or coal gasification are promising processes for renewable energy. However, a major operating problem in gasification is what to do with syngas byproducts such as H2S and tars (heavy hydrocarbons) that cause catalyst deactivation downstream. Studies have shown that rare earth oxides (REOs) doped with transition metals are promising catalysts for tar reforming in the presence of sulfur.(R. Li, Roy, Bridges, & Dooley, 2014) In Chapter 1, propane is studied as a model compound for tar reforming with transition metal-doped (e.g., Mn, Fe) REOs. These are compared to a typical commercial Ni/Al2O3 catalyst. The results showed that REO/TM catalysts …
Fluidized Bed Combustion Of C1-C4 N-Alkanes, Jean-Philippe Laviolette, Gregory S. Patience, Jamal Chaouki
Fluidized Bed Combustion Of C1-C4 N-Alkanes, Jean-Philippe Laviolette, Gregory S. Patience, Jamal Chaouki
The 13th International Conference on Fluidization - New Paradigm in Fluidization Engineering
The non-premixed combustion of C1 to C4 n-alkanes was investigated inside a bubbling fluidized bed of inert sand particles at intermediate temperatures: 923 K (650oC) ≤ TB ≤ 1123 K (850oC). Lower (T1) and upper (T2) critical transition bed temperatures were measured for ethane, propane and n-butane as 923 K (650oC) and 1073 K (800oC), respectively. The values for methane were significantly higher with T1 = 1023 K (750oC) and T2 > 1123 K (850oC). Alkane conversion was accurately modeled with first-order kinetics and C2 to C4 n-alkanes combustion rates were characterized by a uniform Arrhenius expression: (. The reaction rate …