Open Access. Powered by Scholars. Published by Universities.®
- Publication
- Publication Type
- File Type
Articles 91 - 99 of 99
Full-Text Articles in Engineering
Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov
Development Of A New Electrodeposition Process For Plating Of Zn-Ni-X (X = Cd, P) Alloys: I. Corrosion Characteristics Of Zn-Ni-Cd Ternary Alloys, Anand Durairajan, Bala S. Haran, Ralph E. White, Branko N. Popov
Ralph E. White
A new Zn-Ni-Cd plating process was developed which offers a unique way of controlling and optimizing the Ni and Cd contents in the final deposit. Zinc-nickel-cadmium alloy was deposited from a 0.5 M NiSO4 + 0.2 M ZnSO4 bath in the presence of 0.015 M CdSO4 and 1 g/L nonyl phenyl polyethylene oxide. Using this process a Zn-Ni-Cd ternary alloy, with a higher nickel content as compared to that obtained from conventional Zn-Ni baths, was synthesized. The Zn-Ni-Cd alloy coatings deposited from an electrolyte containing 0.015 M (0.3%) CdSO4 has a Zn to Ni ratio of …
Modification Of Newman's Band(J) Subroutine To Multi-Region Systems Containing Interior Boundaries: Mband, D. Fan, Ralph E. White
Modification Of Newman's Band(J) Subroutine To Multi-Region Systems Containing Interior Boundaries: Mband, D. Fan, Ralph E. White
Ralph E. White
Newman's BAND(J) subroutine, which has been used widely to solve models of various electrochemical systems, is extended to solve a system of coupled, ordinary differential equations with interior boundary conditions. A set of coupled, linear ordinary differential equations is used to demonstrate the solution procedure. The results show that the extended technique has the same accuracy as that of using pentadiagonal BAND(J), but the execution speed is about five times faster than that of pentadiagonal BAND(J). Using sparse matrix solver Y12MAF to solve the same set of equations takes even longer time than pentadiagonal BAND(J).
Estimation Of Electrode Kinetic Parameters Of The Lithium/Thionyl Chloride Cell Using A Mathematical Model, T. I. Evans, Ralph E. White
Estimation Of Electrode Kinetic Parameters Of The Lithium/Thionyl Chloride Cell Using A Mathematical Model, T. I. Evans, Ralph E. White
Ralph E. White
A one-dimensional mathematical model for the lithium/thionyl chloride primary cell is used in conjunction with a parameter estimation technique, in order to estimate the electrode kinetic parameters of this electrochemical system. The electrode kinetic parameters include the anodic transfer coefficient and exchange current density of the lithium oxidation, a,1 and i0,1,ref; the cathodic transfer coefficient and the effective exchange current density of the thionyl chloride reduction, c,4 and a0i0,4,ref, and a morphology parameter, . The parameter estimation is performed on simulated data first in order to gain confidence in the method. Data reported in the literature for a high-rate discharge …
Simple Models For Diaphragm-Type Chlorine/Caustic Cells Ii. Effect Of Acidic Anolyte On Steady-State Caustic Yield, John Van Zee, Ralph E. White
Simple Models For Diaphragm-Type Chlorine/Caustic Cells Ii. Effect Of Acidic Anolyte On Steady-State Caustic Yield, John Van Zee, Ralph E. White
Ralph E. White
A simple steady-state model of a diaphragm-type chlorine/caustic cell in which the diaphragm is divided into two regions by a homogeneous acid-base reaction is presented. The location of the reaction affects significantly the caustic yield and effluent concentration. The model is used to predict the location of this reaction as a function of the operating variables, the physical constants, and three measurable properties of the diaphragm. These measurable properties are the MacMullin number or resistivity ratio of electrolyte-filled diaphragm relative to the electrolyte, the Darcy's law diaphragmpermeability, and the diaphragm thickness. The model is used to predict a maximum in …
A Mathematical Model Of Electrochemical Reactions Coupled With Homogeneous Chemical Reactions, Ken-Ming Yen, Taewhan Yeu, Ralph E. White
A Mathematical Model Of Electrochemical Reactions Coupled With Homogeneous Chemical Reactions, Ken-Ming Yen, Taewhan Yeu, Ralph E. White
Ralph E. White
The zinc/bromine (Zn/Br2) flow battery has received considerable
attention in recent years [e.g., (2-4)]. Although it
is agreed that the solution chemistry is important in the
system, most of the work that has been done is concentrated
on the design variables. In this note the basic mass
transfer-solution and surface kinetics are studied to furnish
a better understanding of the system.
A Comparison Of Newman's Numerical Technique And Deboor's Algorithm, D. A. Curtis, T. I. Evans, Ralph E. White
A Comparison Of Newman's Numerical Technique And Deboor's Algorithm, D. A. Curtis, T. I. Evans, Ralph E. White
Ralph E. White
Newman's numerical technique (1-4) has been used extensivelyto solve two-point boundary value problems consistingof coupled, ordinary differential equations#12;. Unfortunately,his method does not always yield a solution to asystem of independent equations#12;. Sometimes his algorithm(BAND) signals incorrectly that the coefficientmatrix is singular (e.g., DETERMINANT = 0 AT J = 2),and no solution is obtained to the system of equations#12;.This problem sometimes occurs when one tries to useBAND to solve a two-point boundary value problemwhich consists of a set of mixed order ordinary differentialequations. For example, the battery model equations presentedrecently by Evans and White (5) are representativeof this type of equation …
Anomalous Codeposition Of Fe-Ni Alloys And Fe-Ni-Sio2 Composites Under Potentiostatic Conditions, M. Ramasubramanian, S. N. Popova, Branko N. Popov, Ralph E. White, K. M. Yin
Anomalous Codeposition Of Fe-Ni Alloys And Fe-Ni-Sio2 Composites Under Potentiostatic Conditions, M. Ramasubramanian, S. N. Popova, Branko N. Popov, Ralph E. White, K. M. Yin
Ralph E. White
A mathematical model has been developed to describe the electrodeposition of Fe-Ni alloys and Fe-Ni-SiO2 composites under potentiostatic conditions. This model can be used to predict the polarization behavior, partial current densities, and alloy composition of each of the components as a function of the applied potential. Fe-Ni-SiO2 samples were deposited on platinum rotating disk electrodes from sulfate electrolytes under potentiostatic conditions, and the results obtained were compared to the model. The model predictions were found to agree well with the experimental observations for the Fe-Ni and Fe-Ni-SiO2 systems.
A Mathematical Model Of The Self-Discharge Of A Ni-H2 Battery, Z. Mao, Ralph E. White
A Mathematical Model Of The Self-Discharge Of A Ni-H2 Battery, Z. Mao, Ralph E. White
Ralph E. White
A simple mathematical model is presented and used to characterize the self-discharge of a nickel oxyhydroxide(NiOOH) electrode in a hydrogen environment. This model includes diffusion of dissolved hydrogen in an electrolyte film which covers a flooded electrode, electrochemical oxidation of hydrogen, reduction of nickel oxyhydroxide, and changes of surface area and of porosity of the electrode during the self-discharge process. Although the self-discharge process is complicated, the predictions of the model are consistent with experimental results reported in the literature, which include linear relationships between the logarithm of hydrogen pressure and time and between the logarithm of the capacity remaining …
Creation Of An Annotated Library On Fda Approved Nanomedicines, Marley R. Hodson, Tanin Izadi, Nastassja Lewinski Ph.D, Bridget T. Mcinnes Ph.D
Creation Of An Annotated Library On Fda Approved Nanomedicines, Marley R. Hodson, Tanin Izadi, Nastassja Lewinski Ph.D, Bridget T. Mcinnes Ph.D
Undergraduate Research Posters
Nanomedicine is a type of nanotechnology used in the medical field to limit the dosage amount and target drug delivery to specific cells. Nanomedicines that are approved and used tend to be extremely successful; however despite over a decade of research, only a limited number of nanomedicines have advanced for clinical use. A possible reason for the numerous nanomedicine failures is lack of easily accessible information and research on previous nanomedicines. In this project, we have compiled nanomedicine labeling information from the Drugs@FDA website. We have extracted phrases/sentences from labels relating to keywords on nanomaterial properties and drug profile characteristics. …