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Full-Text Articles in Engineering
Ethane Oxidation And Pyrolysis From 5 Bar To 1000 Bar: Experiments And Simulation, Abdul Aziz Abdul Raman
Ethane Oxidation And Pyrolysis From 5 Bar To 1000 Bar: Experiments And Simulation, Abdul Aziz Abdul Raman
Abdul Aziz Abdul Raman
An extensive experimental study of ethane oxidation and pyrolysis has been conducted in the high pressure shock tube at UIC covering reflected shock pressures from 5-1000 bar, reaction temperatures up to 1550 K and stoichiometric (Φ = 1 ), fuel rich (Φ = 5), and pyrolytic mixtures. The experimental data has been used to develop a single model that can simulate the whole dataset very well and is the first ethane model capable of simulating experimental results over such an extensive range of pressure, temperature, and stoichiometry. © 2005 Wiley Periodicals, Inc.
Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole
Halonitromethane Treatment Using Advanced Oxidation Process: Rates, Mechanisms And Kinetic Modeling, Stuart Kirkham Cole
Civil & Environmental Engineering Theses & Dissertations
Halonitromethanes (HNMs) are low molecular weight halogenated disinfection-by-products (DBPs) found to be formed during ozonation, chlorination, or chloramination of waters containing natural bromide ion and nitrogenous organic matter. This work identifies the absolute rate constants for the oxidative hydroxyl radical (•OH) and reductive hydrated electron e- aq extinction of HNM compounds. Three forms of HNMs included in this study are the chlorinated, brominated, and mixed halogenated compounds. Electron pulse radiolysis and transient absorption spectroscopy were used to measure •OH and e- aq radical absolute reaction rate constants for a total of nine HNMs. To elucidate the decomposition reaction …