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Chemical Engineering

Theses/Dissertations

2004

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Articles 31 - 38 of 38

Full-Text Articles in Engineering

Online Heat Transfer Measurement And Analysis For Sugar Mill Evaporators, David Timothy Solberg Jan 2004

Online Heat Transfer Measurement And Analysis For Sugar Mill Evaporators, David Timothy Solberg

LSU Master's Theses

Fouling and scaling in evaporators has been an area of great interest to raw sugar mills for a number of years and many of the mechanisms causing the scale and the rates of scaling are unknown. In an attempt to quantify the scaling rates and measure the scaling, an online model has been developed to model a system of evaporators. Monitoring the heat transfer coefficient as a function of time enabled measurement of the scaling rate by monitoring the heat transfer coefficient as it decreased with time. It is assumed that the scaling on the juice side of the evaporators …


Modeling Of Cane Sugar Colorant Removal In Packed-Bed Ion Exchange Columns And An Investigation Into Pretreatment Methods, Bruce Malcolm Ellis Jan 2004

Modeling Of Cane Sugar Colorant Removal In Packed-Bed Ion Exchange Columns And An Investigation Into Pretreatment Methods, Bruce Malcolm Ellis

LSU Master's Theses

Cane sugar colorants have been extensively researched but still little is known about their exact compositions. Rather than distinct compounds, they are a mixture of many compounds. Some it is assumed can be classified into the pseudo components that have been defined using gel permeation chromatography, based on molecular weight. The defining of these components has allowed the colorants to be modeled independently, instead of as one lumped color parameter. The measured colored components were modeled using a linear driving force adsorption model, which could be applied in the design process for optimizing the decolorizing capacity of the resins. The …


Development And Integration Of New Processes Consuming Carbon Dioxide In Multi-Plant Chemical Production Complexes, Sudheer Indala Jan 2004

Development And Integration Of New Processes Consuming Carbon Dioxide In Multi-Plant Chemical Production Complexes, Sudheer Indala

LSU Master's Theses

New, energy-efficient and environmentally acceptable, catalytic processes have been identified that can use excess high purity CO2 as a raw material from the sources available in a chemical production complex. The chemical complex in the lower Mississippi River Corridor has been used to show how these new plants can be integrated into this existing infrastructure using the Chemical Complex and Cogeneration Analysis System. Eighty six published articles of laboratory and pilot plant experiments were reviewed that describe new methods and catalysts to use CO2 for producing commercially important products. Reactions have been categorized as hydrogenation reactions; hydrocarbon synthesis …


Evaluation Of New Methods For Processing Drilling Data To Determine The Cause Of Changes In Bit Performance, Jaime Solano Jan 2004

Evaluation Of New Methods For Processing Drilling Data To Determine The Cause Of Changes In Bit Performance, Jaime Solano

LSU Master's Theses

Drilling operations represent the major cost in finding and developing new petroleum reserves. Poor drilling performance when drilling deep shale and strong rocks, as evidenced by slow rate of penetration (ROP), has a significant detrimental impact on drilling costs. Also, it has been concluded that bit balling is the main cause of low ROP when drilling deep, clay-rich shale with water-based mud. In addition, it is estimated that a potential saving in drilling cost of hundreds of millions of dollars a year can be obtained if bit balling is mitigated and ROP is improved. Several methods have been developed in …


Metal-Doped Rare Earth Oxide Catalysts For Condensations To Ketones, Arvind Karkal Bhat Jan 2004

Metal-Doped Rare Earth Oxide Catalysts For Condensations To Ketones, Arvind Karkal Bhat

LSU Master's Theses

Metal-doped supported rare earth oxide catalysts were examined to determine their suitability for the decarboxylative condensation of two carboxylic acids to produce ketones. The catalysts were characterized based on chemisorption tests, coke analysis using thermo-gravimetric analysis and X-ray absorption spectroscopy. Effect of catalyst particle size on rate of reaction was studied for various supported cerium oxide catalysts. Catalysts were tested for activity, selectivity, and stability using isothermal fixed bed reactors. Optimal operating conditions for the production of diisopropyl ketone and methyl nonyl ketone were determined. It was found that supported cerium oxide catalysts effectively catalyzed the condensation of isobutyric acid …


Electrodeposition Of Feconicu Quaternary System, Qiang Huang Jan 2004

Electrodeposition Of Feconicu Quaternary System, Qiang Huang

LSU Doctoral Dissertations

Electrodeposition is a cost-effective method to produce thin film materials, which have been used widely in the microelectronic industry, and is advantageous to fabricate metal deposits into recessed and curved areas. In this dissertation, FeCoNiCu quaternary alloy system was investigated, both experimentally and theoretically, for fabrication of multilayers, grating structures, and nanowires. Multilayer structures are composed of alternating ferromagnetic and nonmagnetic nanometric layers, and are of interest due to the giant magnetoresistance (GMR) property it possesses, a change in electric resistance in the presence of an external magnetic field. In addition, the compositional modulation, or the composition contrast, in multilayer …


Closed Material Cycles And Organic Solvent Recovery, Tim De Jong Jan 2004

Closed Material Cycles And Organic Solvent Recovery, Tim De Jong

Theses

A survey was conducted of the pharmaceutical sector in Ireland to establish organic solvent usage, recovery and treatment practices. The eleven companies covered by the survey, which included several of the worlds largest multinational companies, consumed in the region of 122,000 tonnes of organic solvent in 2002. Approximately 53,000 tonnes was recovered on-site while 69,000 tonnes of virgin solvent was brought on-site to replace that which was lost through wastewater treatment, incineration, fugitive emissions and off-site treatment or reuse. The total quantity of virgin solvent consumed by the eleven companies accounted for 75.4 % of organic solvent imports to Ireland. …


The Dependence Of The Overall Drying Time And Product Quality Of A Lyophilization Process On The Relative Position Of Vials On A Tray With Tray Sides And Without Tray Sides For Different Heat Input Control Policies, Kian Hui Gan Jan 2004

The Dependence Of The Overall Drying Time And Product Quality Of A Lyophilization Process On The Relative Position Of Vials On A Tray With Tray Sides And Without Tray Sides For Different Heat Input Control Policies, Kian Hui Gan

Masters Theses

"The dynamic behavior of the primary and secondary drying stages of the lyophilization process were studied when (a) single vials located at different positions on the tray were individually being dried, and (b) the vials on the tray are arranged in clusters of square and hexagonal arrays and all the vials on the tray are simultaneously being dried. For both cases (a) and (b), fast drying times and relatively more uniform distributions of temperature and concentration of bound water at the end of the secondary drying stage are obtained by heat input control that runs the lyophilization process close to …