Engineering Commons^™

Rotational Molding Of Acrylonitrile-Butadiene-Styrene Polymers And Blends, Mark Grant Spencer

Theses and Dissertations

The development of acrylonitrile-butadiene-styrene (ABS) resins for use in rotational molding would provide a medium performance material, thus opening doors to new markets for the rotational molding industry. Unfortunately, ABS resins have shown serious problems during the rotational molding process, namely discoloration, bridging, and poor impact strength. It is believed that these effects are due to degradation of the carbon-carbon double bond in the butadiene, through attack by either oxygen or heat. Previous efforts have shown some success in addressing these issues. However, additional improvements are necessary to make ABS resins commercially viable to rotational molders. This study, fourth in …

Generic Transportation Model Applied To Catalytic Steam Gasification Of Poultry Litter And To Rotary Kiln Incineration Of Shredded Tires, Jennifer Fuller English

Masters Theses

Many environmental issues are related to the disposal of both poultry litter and used tires. In an effort to provide a more environmentally friendly alternative to disposal of these substances, work has been done previously at UTSI in the areas of catalytic steam gasification of poultry litter and rotary kiln incineration of shredded tires. The scope of this research is to develop a transportation model that can be used for either of these processes. The model will be used to determine their economic feasibility under changing conditions including traveling distance, feed rate, and price fluctuations in the sales price of …

Thermodynamic Property Prediction For Solid Organic Compounds Based On Molecular Structure, Benjamin T. Goodman

Theses and Dissertations

A knowledge of thermophysical properties is necessary for the design of all process units. Reliable property prediction methods are essential because reliable experimental data are often not available due to concerns about measurement difficulty, cost, scarcity, safety, or environment. In particular, there is a lack of prediction methods for solid properties. Predicted property values can also be used to fill holes in property databases to understand more fully compound characteristics. This work is a comprehensive analysis of the prediction methods available for five commonly needed solid properties. Where satisfactory methods are available, recommendations are made; where methods are unsatisfactory in …

Thermochemistry And Kinetic Analysis On Radicals Of Acetaldehyde + O2, Allyl Radical + O2 And Diethyl And Chlorodiethyl Sulfides, Jongwoo Lee

Dissertations

Thermochemical properties for reactants, intermediates, products and transition states important in the radicals of acetaldehyde + O₂ and allyl radical + O₂ reaction systems are analyzed with density functional and ab initic calculations, to evaluate the reaction paths and kinetics in oxidation and pyrolysis. Ketene is one important product resulting from acetaldehyde oxidation; thus thermochemistry plus isomerization and conversion reactions of ketene are also analyzed. Enthalpies of formation are determined using isodesmic reaction analysis at the CBSQ composite and density functional levels. Entropies and heat capacities are determined using geometric parameters and vibration frequencies obtained at the HF/6-31G(d') …

Production Of Nanocrystalline Nitramine Energetic Materials By Rapid Expansion Of Supercritical Solutions, Victor Stepanov

Theses

Nanotechnology is a rapidly evolving field and has been characterized as "the next industrial revolution". Nanostructured materials are receiving increasing amount of attention in fields ranging from electronics to metallurgy due to their novel and unique properties. This work was focused on exploring the benefits of nanofabrication of high density energetic materials. The work primarily focused on the feasibility and viability of recrystallization of nitramine explosives down to the nanometer crystal size (<100 nm). It is anticipated that properties of the high density energetic materials such as sensitivity, packing density, crystal quality, energetic performance will be benefited.

Rapid Expansion of Supercritical Solutions was chosen as the process most appropriate to realize the objective. Solubility of CL-20 in supercritical solutions was studied. Nitramine crystals with …

Detecting Changes In Global Dynamics With Principal Curves And Information Theory, Sandeep Rajput

Doctoral Dissertations

Two approaches to characterize global dynamics are developed in this dissertation. In particular, the concern is with nonlinear and chaotic time series obtained from physical systems. The objective is to identify the features that adequately characterize a time series, and can consequently be used for fault diagnosis and process monitoring, and for improved control.

This study has two parts. The first part is concerned with obtaining a skeletal description of the data using Cluster-linked principal curves (CLPC). A CLPC is a non-parametric hypercurve that passes through the center of the data cloud, and is obtained through the iterative Expectation-Maximization (E-M) …

Chemical Treatment For Lignin Removal From Non-Wood Pulping Wastewater, Ahmed Abdel-Naby Teaama

Archived Theses and Dissertations

No abstract provided.

Role Of Catalyst And Substrate In Synthesis Of Single Wall Carbon Nanotubes, Amit Goyal

Theses

The synthesis of single wall carbon nanotubes (SWNTs) by the catalyticdisproportionation of carbon monoxide (CO) (i.e., Boudouard reaction) at I atm pressureand 700-800 C, has been systematically investigated in order to determine whether theprocess can be used for the large scale production. SWNT diameter distribution andmorphology were studied by Raman scattering, and scanning and transmission electronmicroscopy, respectively. X-ray diffraction was used to determine levels of the remnantcatalyst and support. Synthesis experiments were conducted using a three-stage processwith hydrogen to reduce the catalyst-precursor and argon to cool the system. Two typesof catalyst/support synthesis were studied: (1) Combustion synthesis to form catalyst …

Modification Of Biodegradable Polyesters With Inorganic Fillers, Georgia Chouzouri

Theses

In attempts to address the growing need of materials with controlled degradation characteristics and good mechanical properties for tissue engineering applications, composites based on biodegradable polymers and a potentially bioactive novel inorganic synthetic filler were produced and characterized. Composites were produced by solution mixing of a commercial polylactic acid, as well as a biodegradable thermoplastic polyester based on butylene adipate/succinate, with synthetic magnesium/aluminum carbonate minerals, known as hydrotalcites. Two types of hydrotalcites, at 30 wto/o filler level, were used: surface coated and uncoated. Composites were also melt-mixed in a twin-screw extruder for comparison.

Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA), …

Molecular Modeling At Interfaces: Phase Equilibria Of Complex Fluids, And Mechanical Properties Of Nanostructures, Jose L. Rivera-Rojas

Doctoral Dissertations

Molecular simulation is a very powerful technique that allows us to predict thermodynamic and transport properties of bulk and confined phases, as well as phase equilibria and interfacial properties. These properties are often crucial to the design of chemical and related industrial processes. Molecular simulation can predict these properties over a wide range of conditions, in contrast with experiments, which at extreme conditions (e.g., high temperature and/or high pressure) are often very difficult and in some cases dangerous. Furthermore, semi-empirical and empirical engineering models can frequently only be used for the specific systems to which they are fitted – that …

Oxygen Delignification Kinetics And Selectivity Improvement, Steven M. Violette

Electronic Theses and Dissertations

Pulp strength loss during oxygen delignification is caused by cellulose chain cleavage resulting fiom attack by oxygen-based radicals generated through reactions with lignin. The objective of this research was to improve the lignin-to-cellulose selectivity during oxygen delignification by using radical-scavenging polymeric additives that adsorb on the cellulose surfaces where protection fiom radicals is needed. Among the polymers evaluated were starch, carboxymethyl-cellulose, galactomannan, xylan, and glucomannan. Oxygen delignification experiments were conducted on Northeast softwood Kraft pulps at different temperatures, sodium hydroxide charges, reaction times, and pretreatments. The effect of polymer additives on the selectivity and kinetics was studied. Polymer adsorption on …

Relationship Between Alkaline Pulp Yield And The Mass Fraction And Degree Of Polymerization Of Cellulose In Pulp, Mehmet Sefik Tunc

Electronic Theses and Dissertations

Wood as a raw material is generally the dominant cost factor for the production of chemical pulp. Therefore, an increase in pulp yield has a major impact on the competitiveness of a mill. In order to optimize pulp yield, for example by changing operating conditions, a mill must be able to monitor the yield accurately. However, an accurate "real-time" pulp yield measurement method is not available at the present time. Pulping yield is presently measured from the amount of pulp produced from a given quantity of wood consumed over a 3 to 6 month time frame. This method is obviously …

The Rate Of Fluid Absorption In Porous Media, Ran Wei Rioux

Electronic Theses and Dissertations

Fluid flow in porous media is an important process for many applications such as oil recovery, packed bed absorption colun~ns and filtration. Short time fluid uptake is important for processes such as textile sizing, paper coating and printing. But more work is needed to characterize the parameters that determine the absorption rate. This work is focused on short time absorption rate on uncoated and coated paper. Absorption rate is measured with a Bristow Wheel device for seven different uncoated papers and eleven coated papers. Gloss dynamics of freshly printed samples and tack dynamics are measured with two novel devices. Various …

Viscoelastic Roll Coating Flows, Mitchell A. Johnson

Electronic Theses and Dissertations

The physics of a fluid flow between two rotating cylinders is important in processes such as bearing lubrication, roll coating, and printing. A small amount of dissolved polymer in the fluid can have a large impact on the behavior of the process. Viscoelasticity affects the stability of application and metering processes, and reduces the maximum speed at which a uniform film can be coated onto a substrate. The goal of this work is to characterize the effect of viscoelasticity on the forward roll coating operation. A bench-top apparatus simulated the process. Measurements of the gap between the roll surfaces, pressure …

Effect Of Surface Treatment On The Conductivity Of Polyurethane-Carbon Composites, Leina Barros Tocchetto

Masters Theses

The effect of plasma surface treatment on the mechanical and electrical properties was investigated by comparing untreated particulate carbon filler and treated carbon filler in a polyurethane matrix. For achieving this goal, samples of the composites were prepared with different percentages of carbon fillers (0 – 50 wt %) and conductivity measurements, dynamic mechanical analysis, mechanical properties, infrared spectroscopy and scanning electron microscopy were used to determine the effect of surface modification and concentration. The conductivity measurements showed that the percolation threshold was shifted to lower concentrations of carbon as compared to the predicted value especially for the untreated carbon …

Co2 Separation And Fuel Desulfurization Involving Room-Temperature Ionic Liquids, Benjamin Culbertson

Masters Theses

Imidazolium based room-temperature ionic liquids were used to investigate the technical and economic feasibility of energy-related chemical separations. The separations conducted for this work are sulfur-removal from fuels and carbon dioxide removal from flue gas emissions. In the sulfur-removal experiments, the sulfurcontaining compound dibenzothiophene was removed from octane by liquid-liquid extraction, yielding partition coefficients with ionic liquid around 1.5. Attempts to regenerate the ionic liquid using vacuum filtration were not fully successful in removing dibenzothiophene; extractions with the regenerated ionic liquid had a 50% decreased capacity. For this process to become economically feasible in comparison to the currently used hydrotreating, …

Microreactor System With Immobilized Enzyme On Polydimethylsiloxane (Pdms) Polymers, Zonghuan Lu

Doctoral Dissertations

Microsystems, specifically microreactors, open the gate to new, improved analytical techniques while offering many advantages for a large number of applications in chemical engineering, pharmacy, medicine, and biotechnology. This study explored the feasibility of fabrication of microreactors using polydimethylsiloxane (PDMS) as a support for enzyme immobilization. Urease enzyme was used for catalyzing the conversion of urea to ammonia.

PDMS (polydimethylsiloxane) is a silicone-based elastomeric polymer. Traditional micromanufacturing technology was employed for reactor mold fabrication. The mold was fabricated based on photolithography techniques, and SU-8 photoresist was used to construct reactor structure templates. The resulting silicon-wafer based reactor molds were then …

A Reactive Melt Modification Of Polyethylene Terephthalate, Rahul Ramesh Dhavalikar

Dissertations

This work investigates the structural and chemorheological modification of polyethylene terephthalate in the melt phase with low molecular weight multifunctional glycidyl compounds as reactive additives. Polyethylene terephthalate undergoes chain extension and/or branching reactions with the additives that result in modified rheological properties suitable for certain polymer processing operations such as extrusion blow molding or extrusion foaming to low densities.

Among five different low MW difunctional and trifunctional epoxy compounds, triglycidyl isocyanurate is shown to be an efficient reactive melt modifier for commercially available polyethylene terephthalate polymers. Its stability at the polyethylene terephthalate melt temperatures is confirmed offline through thermogravimetric and …

Study Of Vapor/Gas Permeation Using Thin Immobilized Liquid Membrane, Gordana Obuskovic

Dissertations

To improve liquid membrane selectivity and stability for removal of vapor and gases from a gas stream, a thin immobilized liquid membrane (ILM) has been studied. Low vapor pressure liquid solvent/solutions were immobilized in part of the micropores of a hydrophilic, hydrophobic or ceramic hollow fiber substrate. To prepare such thin ILMs, three approaches were used: evaporation of the a volatile solvent; acrylic acid-grafted hollow fibers providing a thin hydrophilic layer; pressurization technique.

For removal of volatile organic compound (VOC), a thin ILM of silicone oil incorporated in the micropores of a hydrophobic hollow fiber with a silicone rubber coating …

Liquid-Liquid Mixing In Stirred Tanks With Varying Liquid Depths, Sunil Mehta

Theses

Considerable attention has been devoted in the past to the determination of the minimum agitation speed, N_cd, required for the complete dispersion of two immiscible liquids in mechanically stirred tanks. When this situation is achieved the dispersed phase is no longer present as a distinct layer, such as a light oil phase above an aqueous solution, but becomes completely dispersed, in the form of droplets, throughout the continuous phase. The achievement of the dispersed state is of significant importance in many industrial operations. Nevertheless, the effect on N_cd of a number of operating variables remains poorly understood. …

Reaction Control In Quiescent Systems Of Free-Radical Retrograde-Precipitation Polymerization, Vijaya Raghavan Tirumala

Dissertations, Master's Theses and Master's Reports - Open

Free-radical retrograde-precipitation polymerization, FRRPP in short, is a novel polymerization process discovered by Dr. Gerard Caneba in the late 1980s. The current study is aimed at gaining a better understanding of the reaction mechanism of the FRRPP and its thermodynamically-driven features that are predominant in controlling the chain reaction.

A previously developed mathematical model to represent free radical polymerization kinetics was used to simulate a classic bulk polymerization system from the literature. Unlike other existing models, such a sparse-matrix-based representation allows one to explicitly accommodate the chain length dependent kinetic parameters.

Extrapolating from the past results, mixing was experimentally shown …

Silica Coating Of Gold Nanoparticles, Milind Laxman Surve

Masters Theses

“Gold colloids have been homogenously coated with silica using silane coupling agents as a primer to make the gold surface vitreophilic. After adding active silica, the particles are transferred in ethanol for uniform silica coating by using the Stober method. Gold nanoparticles used for this study ranged from 5 nm up to 40 nm with mixed results. Silica condensation can be controlled to produce different silica thicknesses on gold. The main problem while coating smaller particles (5 nm and 10 nm) was the final coagulation or necking of silica after coating the gold surface. The possible causes for this effect …

Extraction Of A Valuable Compound From A Waste Stream For Adm Ringaskiddy, Colin G. Burkley

Theses

This thesis was originally conceived as a potential Masters Degree research programme by the management of ADM Ringaskiddy as a means of maximizing throughput through the plant’s wastewater treatment facility. This facility is a major producer of citric acid using beet molasses and a fermentation process. It was proposed that removal of a compound, known as betaine, from the citric acid process waste stream would reduce the Chemical Oxygen Demand (COD) content of the waste requiring treatment before disposal. This would be achieved by using the citric acid process waste as the feedstock for a betaine extraction process. The wastewater …

Environmental Management Of Waste Electrical & Electronic Equipment (Weee) In Ireland, Simon Wilkinson

Theses

This thesis follows two previous studies by the Author on the calculation of theoretical WEEE arisings, and an assessment of ecodesign practices in Ireland. It has established collection trials in five different locations throughout Ireland in order to characterise and quantify WEEE arisings, and to examine outlets for collected WEEE. Overall, during the twelve months of collection at the project locations, more than 450 tonnes of WEEE was collected from the public and recycled. Within the catchments of each facility, collection rates of between 2.1 and 3.5 kg/person/year were achieved during the twelve-month trial period. With further public awareness raising …

Removal Of Sustained Casing Pressure Utilizing A Workover Rig, Kevin Soter

LSU Master's Theses

This thesis will analyze the techniques used during the 1989 and 1990 workover programs as well as subsequent operations in 1991/1992. It will also present the techniques and results of the most recent 1999 workover program undertaken to alleviate the most persistent sustained casing pressure (SCP) in a mature Gulf of Mexico field. An extensive literature review is included to better illustrate the complexity of the issues involved and possible SCP mechanisms. The field was drilled during the 1980’s and SCP has been prevalent in some cases previous to initial completion operations. Previous remedial programs resulted in limited success in …

Electrodeposition Of Nickel-Copper Alloys And Nickel-Copper-Alumina Nanocomposites Into Deep Recesses For Mems, Amrit Panda

LSU Doctoral Dissertations

Electrodeposition is an important component in the fabrication of micro electro mechanical systems (MEMS). Nickel is the most commonly used material to produce three dimensional microstructures and few material alternatives have been demonstrated. In this dissertation, electrodeposited Ni-Cu alloys and nanocomposites are investigated as possible replacements for nickel in microsystems. Ni-Cu alloys are attractive for their corrosion resistance, magnetic and thermophysical properties. Alumina nanoparticulates included into metal matrices improve hardness and tribology of deposits. The Ni-Cu alloys and Ni-Cu-g-Al2O3 nanocomposites were electrodeposited from a citrate electrolyte, both at low and high pH. Electrodeposition experiments were performed in recessed microelectrodes 500 …

Dynamic Modeling And Parameter Estimation For An Ethlyene-Propylene-Diene Polymerization Process, Rujun Li

LSU Doctoral Dissertations

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A general dynamic model for continuous EPDM polymerization in which crosslinking and gel formation are attributable to reactions between pendant double bonds has been developed. A pseudo-kinetic rate constant method is introduced to construct a moment model for a pseudo-homopolymer that approximates the behavior of the actual terpolymer under long chain and quasi-steady state assumptions. The pseudo-homopolymer model is then used as the basis for application of the numerical fractionation method. The proposed dynamic model is capable of predicting polydispersities and molecular weight distributions near the gel point with as few as eleven generations, and in the …

Improved Bottomhole Pressure Control For Underbalanced Drilling Operations, Carlos Perez-Tellez

LSU Doctoral Dissertations

Maintaining underbalanced conditions from the beginning to the end of the drilling process is necessary to guarantee the success of jointed-pipe underbalanced drilling (UBD) operations by avoiding formation damage and potential hazardous drilling problems such as lost circulation and differential sticking. However, maintaining these conditions is an unmet challenge that continues motivating not only research but also technological developments. This research proposes an UBD flow control procedure, which represents an economical method for maintaining continuous underbalanced conditions and, therefore, to increase well productivity by preventing formation damage. It is applicable to wells that can flow without artificial lift and within …

Bioavailability And Bioaccumulation Of Sediment-Associated, Desorption-Resistant Fraction Of Polycyclic Aromatic Hydrocarbon Contaminants, Xiaoxia Lu

LSU Doctoral Dissertations

This study is directed toward identifying and characterizing the bioavailability of both reversibly sorbed and desorption-resistant fraction of hydrophobic organic contaminants in natural biologically active sediments and the corresponding consequences to prediction, control and regulation of these contaminants. The focus is on polycyclic aromatic hydrocarbons (PAHs) with particular emphasis on phenanthrene and benzo[a]pyrene. A quantity of well-characterized and extensively desorbed sediments was prepared by desorbing the lab-inoculated sediment with an isopropanol and electrolyte solution. This procedure was proved to be a very effective method to prepare sediments containing contaminants largely limited to a desorption-resistant compartment. Accumulation of contaminants in the …

Mechanisms And Control Of Water Inflow To Wells In Gas Reservoirs With Bottom Water Drive, Miguel Armenta

LSU Doctoral Dissertations

Water inflow may cease production of gas wells, leaving a significant amount of gas in the reservoir. Conventional technologies of gas well dewatering remove water from inside the wellbore without controlling water at its source. This study addresses mechanisms of water inflow to gas wells and a new completion method to control it. In a vertical oil well, the water cone top is horizontal, but in a gas well, the gas/water interface tends to bend downwards. It could be economically possible to produce gas-water systems without water breakthrough. Non-Darcy flow effect (NDFE), vertical permeability, aquifer size, density of well perforation, …