Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 3 of 3
Full-Text Articles in Engineering
Oxygen Delignification Kinetics And Selectivity Improvement, Steven M. Violette
Oxygen Delignification Kinetics And Selectivity Improvement, Steven M. Violette
Electronic Theses and Dissertations
Pulp strength loss during oxygen delignification is caused by cellulose chain cleavage resulting fiom attack by oxygen-based radicals generated through reactions with lignin. The objective of this research was to improve the lignin-to-cellulose selectivity during oxygen delignification by using radical-scavenging polymeric additives that adsorb on the cellulose surfaces where protection fiom radicals is needed. Among the polymers evaluated were starch, carboxymethyl-cellulose, galactomannan, xylan, and glucomannan. Oxygen delignification experiments were conducted on Northeast softwood Kraft pulps at different temperatures, sodium hydroxide charges, reaction times, and pretreatments. The effect of polymer additives on the selectivity and kinetics was studied. Polymer adsorption on …
Pulp Pretreatments For Improved Selectivity And Extended Oxygen Delignification, Zheng Dang
Pulp Pretreatments For Improved Selectivity And Extended Oxygen Delignification, Zheng Dang
Electronic Theses and Dissertations
Oxygen delignification has developed steadily since it was introduced commercially in 1970 in South Africa and virtually all new fiber lines incorporate an oxygen delignification system following the digester prior to the bleach plant. Currently, the degradation of cellulose and consequently the loss of pulp strength limit the drop in kappa number that can be obtained using an oxygen process. Pulp selectivity, given by the selectivity coefficient (α), relates the reduction in the molecular weight of cellulose to the reduction in the ligin content of the pulp when measured by the kappa number. An evaluation of selectivity of deligification data …
Effect Of Kraft Pulping On Oxygen Delignification, Haixuan Zou
Effect Of Kraft Pulping On Oxygen Delignification, Haixuan Zou
Electronic Theses and Dissertations
The objective of the study reported here was to investigate experimentally the effect of the major Kraft pulping variables on the response of brownstock pulps to medium consistency oxygen delignification. Kraft pulping was performed on mixed Northeastern hardwood chips in a laboratory rocking digester. Kraft pulps of kappa number 16 and 20 mL KMnO4 were produced by pulping under a variety of conditions. The effective alkali (EA) charged to the digester was varied over the range of 12 to 21% while the sodium sulfide content of the pulping liquor was varied between 0 to 30% sulfidity. Cooking temperatures of …