Engineering Commons^™

Understanding Biomass Upgrading Through Hydrogenolysis Reactions: Kinetics And Mechanism, Jalal Tavana

Electronic Theses and Dissertations

This dissertation involves several hydrogenolysis reactions but is mainly focused on hydrodechlorination (HDC) of chlorobenzene (PhCl) and hydrodeoxygenation (HDO) of 2-furancarboxylic acid (FCA). Hydrodechlorination of PhCl has been the subject of research for some time. Here, we used a Pd/C catalyst to study this reaction though rigorous kinetics and mechanistic analyses in a CSTR reactor. The H₂/D₂ kinetic isotope effect (KIE) experiment revealed that H₂ is not involved in a rate controlling step. The kinetics data are in agreement with similar systems reported before and follow a first-order dependence on chlorobenzene, half order for hydrogen and …

Reaction Kinetics And Mechanism Investigations Of Renewable Chemicals Production From Biomass, Hussein Talib Abdulrazzaq

Electronic Theses and Dissertations

The development of the technologies and the improved processes for the production of high value bio-based chemicals is one of the most important challenges at the present time. This new movement is not only important from an environmental perspective, but also it is a profitable approach to provide affordable and efficient processes. Therefore, the chemical catalytic upgrading processes over various homogenous and heterogeneous catalysis could be an outstanding modification to upgrade biomass-derived platform molecule to high value applications. In this dissertation, we highlight our recent progress in developing new chemistries and processes for upgrading biomass-derived molecules and address the challenges …

Hydrogenation Of 2-Methylnaphthalene In A Trickle Bed Reactor Over Bifunctional Nickel Catalysts, Matthew J. Kline

Electronic Theses and Dissertations

Biomass thermal conversion processes, such as pyrolysis, tend to produce mixtures of mono- and poly-aromatic species. While the high aromatic content is desirable in gasoline fractions, middle-distillate cuts, particularly jet fuel and diesel, require upgrading via hydrogenation and ring opening to achieve better combustion characteristics. There have been many proposed methods for producing drop-in fuels from woody biomass, one of them being Thermal DeOxygenation (TDO). The TDO process converts organic acids from cellulose hydrolysis into a low-oxygen bio-oil containing large amounts of substituted naphthalene compounds.

Poly-aromatic molecules, such as those found in TDO oil, have low cetane numbers (CN), particularly …

Fabrication Of Silicon Microneedles For Dermal Interstitial Fluid Extraction In Human Subjects, Caleb A. Berry

Electronic Theses and Dissertations

The goal of this project is to design and develop a fabrication process for silicon microneedle arrays to extract dermal interstitial fluid (ISF) from human skin. ISF is a cell- free, living tissue medium that is known to contain many of the same, clinical biomarkers of general health, stress response and immune status as in blood. However, a significant barrier to adoption of ISF as a diagnostic matrix is the lack of a rapid, minimally invasive method of access and collection for analysis. Microfabricated chips containing arrays of microneedles that can rapidly and painlessly access and collect dermal ISF for …

Selectivity Of The Catalytic Hydrogenation Of Cinnamaldehyde Using A Polymer Cross-Linked Catalyst, Madeline Logan

Honors College

The transition from non-renewable fossil fuel chemical feedstocks to bio-renewable chemical feedstocks will be vital for the health of the environment. The current processing and use of fossil fuels produced by the petroleum industry release greenhouse gasses like carbon dioxide into the air causing heat to get trapped in the atmosphere. If greenhouse gas emissions continue at the rate they are now it is expected to cause polar ice caps to melt, ocean levels to rise, and climate all over the globe to change. By switching to bio-renewable feedstocks, the level of greenhouse gasses emitted would drastically decrease because processing …

Using Cellulose Nanofibrils And Calcium Carbonate In Single-Use Utensils, Sierra Yost

Honors College

As humanity becomes aware of the environmental issues that come from plastics, substitutes for single-use plastic are needed. Straws, expanded polystyrene, and grocery bags especially have been placed under scrutiny, but there is a need to replace other single use plastics such as eating utensils and cup lids. In this thesis, the properties of cellulose nanofibrils and calcium carbonate mixtures are characterized to determine the feasibility of their use as a plastic replacement. Using cellulose nanofibrils poses two challenges: 1) it shrinks when dried causing difficulty in forming an object, and 2) it is produced in a 3 weight percent …