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Full-Text Articles in Architecture
Theoretical Study Of Two States Reactivity Of No Activation On Iron Atom, Xiaoman Wang, Yaxin Su, Wenyu Liao, Wenyi Deng
Theoretical Study Of Two States Reactivity Of No Activation On Iron Atom, Xiaoman Wang, Yaxin Su, Wenyu Liao, Wenyi Deng
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
The mechanism of Fe+NO was calculated by the Density Functional Theory (DFT) with the B3LYP methods combined with the 6-311+G (d, p) basis set. The geometry of reactants, transition states, intermediates and products of two reaction systems were completely optimized, and all the transition states were verified by the vibration analysis and intrinsic reaction coordinate (IRC) calculations. The "Two State Reactivity (TSR)" was used to analyze the reaction mechanisms; Results showed that the reaction system preferentially involves low-spin state entrance channel and the high-spin state exit channel. In the reaction channel, the crossing point appears, which would effectively reduce the …
Evaluation Of Carbonation Resistance Of Paint Coated Concrete For Buildings, Tommy Y. Lo, Wenyu Liao, C. K. Wong, Waiching Tang
Evaluation Of Carbonation Resistance Of Paint Coated Concrete For Buildings, Tommy Y. Lo, Wenyu Liao, C. K. Wong, Waiching Tang
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
When evaluating the carbonation resistance of paint coated concrete, the effects of both the strength grade and the curing conditions (standard curing and accelerated curing) of concrete substrate on carbonation resistance of paint coated concrete were investigated. The concept of the carbonation suppression ratio of paint was presented for evaluation of the anti-carbonation performance of the two types of paints (exterior and interior paints) when applied to a reference concrete substrate. The test results showed a good linear relationship between the carbonation depths of the paint coated concrete and the square root of exposure times. Concrete with higher strength grade …
Properties Of Self-Compacting Concrete With Recycled Coarse Aggregate, W. C. Tang, P. C. Ryan, H. Z. Cui, W. Liao
Properties Of Self-Compacting Concrete With Recycled Coarse Aggregate, W. C. Tang, P. C. Ryan, H. Z. Cui, W. Liao
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
The utilization of recycled concrete aggregate (RCA) in Self-Compacting Concrete (SCC) has the potential to reduce both the environmental impact and financial cost associated with this increasingly popular concrete type. However, to date limited research exists exploring the use of coarse RCA in SCC. The work presented in this paper seeks to build on the existing knowledge in this area by examining the workability, strength, and fracture properties of SCCs containing 0%, 25%, 50%, 75%, and 100% coarse RCA. The experimental programme indicated that at RCA utilization levels of 25% to 50% little or no negative impact was observed for …
Pumping Of Fresh Concrete: Insights And Challenges, Geert De Schutter, Dimitri Feys
Pumping Of Fresh Concrete: Insights And Challenges, Geert De Schutter, Dimitri Feys
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
Pumping of Fresh Concrete is of Utmost Importance for Concrete Practice. Required Pumping Pressures Are Typically Estimated based on Design Charts. However, with the Increased Use of Chemical Admixtures and the Development of More Flowable Concrete Mixtures, the Accuracy of Traditional Design Charts is Questioned. in Recent Years, Significant Progress Has Been Obtained in Understanding the Flow of the Material in the Pumping Pipe, Including the Behavior of the Lubrication Layer Near the Pipe Surface. in Comparison with Traditional Design Charts, This Results in More Reliable Pressure Predictions When Considering Very Fluid Concrete Types Like Self-Consolidating Concrete. Some Remaining Challenges …
No Reduction By Propane Over Monolithic Cordierite-Based Fe/Al2o3 Catalyst: Reaction Mechanism And Effect Of H2o/So2, Hao Zhou, Yaxin Su, Wenyu Liao, Wenyi Deng, Fangchuan Zhong
No Reduction By Propane Over Monolithic Cordierite-Based Fe/Al2o3 Catalyst: Reaction Mechanism And Effect Of H2o/So2, Hao Zhou, Yaxin Su, Wenyu Liao, Wenyi Deng, Fangchuan Zhong
Civil, Architectural and Environmental Engineering Faculty Research & Creative Works
The selective reduction of NO by C3H8and the sensitivity to H2O and SO2have been studied over monolithic cordierite-based Fe/Al2O3catalysts, which were prepared by the sol–gel and impregnation method. The catalysts were investigated by N2 adsorption, X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) techniques. Results showed that NO reduction was more than 90% in the absence of oxygen at 500 °C and in the presence of oxygen at 600 °C respectively. In a continues …