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Synthesis And Toxicity Studies Of Imidazolium-Based Ionic Liquids, Ninu Madria

Masters Theses

"There is a considerable recent interest in the applications of room temperature ionic liquids (RTILs) as green solvents in organic synthesis and as nonvolatile electrolytes in lithium ion batteries. A variety of commercially available imidazolium based RTILs have been used for these applications, mainly due to their negligible vapor pressures, high thermal stabilities, wide liquid range, wide electrochemical windows and high anodic stability. The state of the art lithium ion batteries require the use of electrolytes that have relatively low viscosities at temperatures as low as -35°C. This thesis describes the synthesis of novel oxygenated and fluorinated imidazolium based RTILs …

Hall-Effect Thruster Surface Properties Investigation, David George Zidar

Masters Theses

"Surface properties of Hall-effect thruster channel walls play an important role in the performance and lifetime of the device. Physical models of near-wall effects are beginning to be incorporated into thruster simulations, and these models must account for evolution of channel surface properties due to thruster operation. Results from this study show differences in boron nitride channel surface properties from beginning-of-life and after 100's of hours of operation. Two worn thruster channels of different boron nitride grades are compared with their corresponding pristine and shadow-shielded samples. Pristine HP grade boron nitride surface roughness is 9000±700 Å, while the worn sample …

Novel Transparent Conductive Materials: Understanding And Prediction, Yaou Song

Masters Theses

"Transparent conductive oxides (TCOs) such as doped In₂O₃, ZnO, SnO₂ or CdO are highly attractive due to their special properties, which are electrical conductivity and optical transparency. The lack of complete understanding of the fundamentals behind this unique phenomena and rapidly increasing commercial demand draw a lot of interest in investigating this kind of materials. More efficient, environmentally friendly and less expensive transparent conductive materials are needed for a variety of applications, and a general understanding of the origins of the unusual behavior would help further search for potential transparent conductive (TC) candidates. Understanding the basic properties of conventional TCOs …

Design And Control Of A Multi-Axis Micro-Electro-Mechanical System Array For Coordinated Micro-Manipulation, Patrick Jesse White

Masters Theses

"Micro-electro-mechanical system design and implementation is a field that has received much attention over the past few decades. These robotic systems with features on the micro-scale have an unparalleled opportunity to change the way scientists interact with and understand micro and nano-scale phenomenon. Their capabilities allow experimentation that cannot be achieved with standard macro-scale equipment. Potential applications range from observing biological processes in living cells, to smart materials that automatically detect microcracks. So far, however, only a few truly successful applications have been realized. One of the most elusive goals in MEMS design is creating a system capable of coordinated …

"Long" Carbon Fiber Reinforced Concrete For Impact And Blast Resistance, Benjamin Paul Gliha

Masters Theses

"One of the most commonly used materials for protective structures and construction is traditional reinforced concrete. However, in a blast, conventional reinforced concrete (RC) is susceptible to significant spalling (small to medium size chunks of concrete detaching from the original member). The force of the blast turns spalled concrete into projectiles, resulting in secondary fragmentation and the majority of loss of life. Furthermore, the concrete debris makes for difficult and uncertain footing. Both phenomena endanger personnel and complicate post-blast recovery efforts. A very promising but barely explored change to conventional RC construction is the addition of "long" carbon fibers (fibers …

A Neural Network Based Approach For Path Planning On Costmap, Songjie Chen

Masters Theses

"In this thesis, a path planning method using a three-level hierarchical system model is proposed. In the top level of the hierarchy, the given location points to visit are taken as waypoints. The waypoint navigation process is formulated as a traveling salesman problem (TSP). The Lin-Kernighan algorithm is used to solve the TSP and transfer the solution to the lower level of the hierarchy. In the middle level, the path is represented by a grid-based costmap. A novel modified Grossberg neural network is designed to solve the point-to-point path planning. The bottom level of the hierarchy smoothens the path with …

Intelligent Control Of Smartparks And Wind Farms In Smart Grids, Priyam Chakravarty

Masters Theses

"With development in wind turbine technology, wind energy has become an important contestant in the utility market. However, wind energy has the intrinsic property of variations which causes fluctuations in the power grid.

Plug-in electric vehicles are drawing the attention of researchers and the electric power industry because of its need for charging from the grid and its ability to store energy. With increase in the numbers of plug-in electric vehicles, there will be significant penetration of distributed energy resources and hence plug-in electric vehicles connected to the grid in parking lots (SmartParks) can be used as energy storage sink …

Life Expectancy Evaluation And Replacement Schedule Development For Led Traffic Indicators, Casey Robert Noll

Masters Theses

"LED (light-emitting diode) technology is being widely adopted for use in sustainable traffic signal management. However, the useful life and luminosity characteristics have not been sufficiently studied in the field to provide departments of transportation with cost-effective replacement strategies based on the realities for LED indicators. LED indicators fail when their luminous intensity (LI) falls below a pre-specified threshold, posing a danger to traffic. This research details a field study of LED indicators in Missouri and develops a replacement schedule based on key findings. Rates of degradation and subsequently the useful life of each type of LED indicator were calculated …

Quantitative Oxygen Imaging With A Display Screen And A Color Camera, Sanghan Park

Masters Theses

"Optical oxygen sensing uses luminophores such as metal complex dyes that respond to oxygen when illuminated by their specific excitation wavelengths. Traditional optical instruments are mostly spectrometric instruments based on the measurements of emission, absorption or reflection. There is, however, a great need to develop simple, economical, photometric detection components toward quantitative and two-dimensional imaging instruments.

In this work, familiar optoelectronic devices were utilized to demonstrate a simple determination method of gaseous oxygen both quantitatively and qualitatively. A liquid crystal display (LCD) screen and a color charge-coupled device (CCD) camera were employed as a light source for fluorescence excitation and …

Pressed Powdered Titanium And Aluminum Conical Shaped Charge Penetration Of Geological Targets, Dominique John Nolan

Masters Theses

"Conical Shaped Charge penetration into rock is dependent on the physical characteristics of the rock itself and the design and composition of the shaped charge conducting the work. This study looks at the effects of a non-typical conical shaped charge and its penetration into four different rock targets. The shaped charge is made of a liner, which is not a typical solid but instead is a pressed powdered metallic compound of Titanium (Ti) and Aluminum (AI).

The study presents the raw data from testing against rock targets that range in density, uniaxial compressive strength (UCS), tensile strength, hardness scales, and …

Innovative Air Breathing Design And Output Control For Portable Proton Exchange Membrane Fuel Cell, Amar Bala Sridhar

Masters Theses

"Proton Exchange Membrane (PEM) Fuel Cell Technology is an energy source that can provide several times more energy per unit volume than current lithium ion batteries that are available in the market today. The barriers that exist that prevent the fuel cell from entering the world of portable applications are mainly system architecture integration. The idea is to have a fully functioning fuel cell with optimum power output using an innovative chimney design. Tests were conducted to quantify the advantage of using a chimney with the fuel cell. Further research was done to shed light on how different chimney designs …

Development Of Hybrid Composite Bipolar Plates For Proton Exchange Membrane Fuel Cells, Nathaniel James Richie

Masters Theses

"Bipolar plates are one of the most expensive components of a PEM fuel cell and by far the heaviest. Bipolar plates are responsible for providing flow fields for reaction gases, acting as current collectors for electrons liberated during the chemical reaction inside the cell, and providing structural support for the fuel cell stack. Current PEM fuel cell bipolar plate technology is built on the use of sintered graphite which is costly and requires time-consuming machining. Furthermore, due to the brittle nature of graphite, plates must be made relatively thick which adds significant weight and volume to larger stacks, such as …

Experimental Study Of The Interaction Between Surfactants And Preformed Particle Gels, Farag Awadh Muhammed

Masters Theses

"Gel and surfactant treatment are two principle methods to reduce water production and enhance oil recovery (EOR). However, either method by itself has limitations that can be avoided by combining the two. Gel treatment can improve sweep efficiency but has little effect on micro-displacement efficiency. Surfactants are mainly used to improve displacement efficiency but have little effect on sweep efficiency. This research sought to investigate whether the combination of gel and surfactant treatments can be used to significantly enhance oil recovery while reducing water production for extremely heterogeneous mature reservoirs. A newer trend in gel treatments is preformed particle gels …

Relaxation Imaging To Characterize Lightweight Polymer-Crosslinked Aerogels, Emmalou T. Satterfield

Masters Theses

"Silica aerogels are three-dimensional assemblies of silica nanoparticles with extremely low densities. In some instances, the internal void volume is more than 90% of the total volume. The highly porous structure of the aerogels leads to attractive properties for thermal and noise insulation, due to very low thermal conductivity and very high acoustic impedance. The strength of silica aerogels has been substantially improved by casting a thin conformal polymer coating over the entire internal porous surfaces of the nanostructure. The coating reinforces the interparticle connections without significantly compromising the internal void space. To analyze and compare the properties of several …

Calcium Wire Ladle Treatment To Improve Cleanliness Of Centrifugal Cast Steel, Edith Yolanda Martinez Silva

Masters Theses

"Centrifugal casting provides the opportunity of combining large centrifugal forces and directional solidification to reduce non-metallic inclusions in the cast steel product. Calcium treatment in the ladle has the potential of reducing and modifying non-metallic inclusions to achieve better machinability and mechanical properties. The objective of this research is to analyze the combined effects of calcium wire ladle treatment and centrifugal casting on the number, size, composition and morphology of non-metallic inclusions in centrifugally cast steel products.

All experiments were completed at an industrial foundry. The experiments involved feeding calcium wire into the ladle after argon oxygen decarburization (AOD) and …

Using Conditional Probability To Predict Solar-Powered Pump-And-Treat Performance, Erica RenéE Collins

Masters Theses

"Green and sustainable remediation can be further environmentally friendly by using renewable energy systems in place of utility-provided power. This project includes the installation of a single-axis tracking photovoltaic (PV) array at a former dry cleaning site that is undergoing remediation under the Missouri Department of Natural Resources (MODNR) Dry cleaning Environmental Response Trust (DERT) Fund program. The PV array provided power to a positive displacement piston pump that extracted ground water from a 15 m deep monitoring well. The tetrachloroethene (PCE)-contaminated ground water was treated using granular activated carbon (GAC) units prior to discharge to the local publicly owned …

Eyes Don't Lie: Understanding Users' First Impressions On Website Design Using Eye Tracking, Sirjana Dahal

Masters Theses

"Websites are becoming more prevalent these days. They need to create a favorable first impression on the users during initial exposure. After allocating their attention to stimuli, users form a cognitive representation of the visual information leading to first impression. Hence, first impression is important to evaluate the effectiveness of a website. This research tries to examine the amount of exposure time needed to form first impression; identify the web design factors that influence the formation of users' first impression; study the emotional responses of users on website design; and finally understand the relationship between first impression and eye movement. …

Influence Of Particle Size And Specimen Preparation On The Iowa Pore Index, Christopher Paul Davis

Masters Theses

"This study was performed in order to identify a size correction that would allow aggregate of different sizes, other than the standard 1/2-3/4-inch fraction, to be used in the Iowa Pore Index (IPI) test. This size correction would allow for the IPI to be determined for aggregate gradations of material that have a nominal maximum size (NMS) smaller than 3/4-inch. The interest in a size correction for the IPI developed from its use in a Durability Factor (DF) estimation equation. The estimation equation was developed with the use of 19 different DF from Missouri aggregate sources, where eight aggregates had …

Production And Characterization Of Supported Palladium Nanoparticles On Multiwalled Carbon Nanotubes By Gamma Irradiation, Jessika Viviana Rojas Marin

Masters Theses

"Carbon nanotubes are being studied for a variety of applications due to their outstanding mechanical, chemical, electrical, and optical properties that make them interesting in different areas. Nowadays, different methods to modify the structure of the nanotubes are being developed in order to expand the application fields of such materials. In this work, palladium nanoparticles were directly produced and supported on multi-walled carbon nanotubes (MWCNT) by gamma irradiation. A solution with a 2:1 water-isopropanol ratio was prepared and mixed with palladium chloride as precursor of palladium ions. Radiolysis of water produces certain species that reduce the ions down to a …

Categorization And Experimental Evaluation Of Anchorage Systems For Fiber-Reinforced Polymer Laminates Bonded To Reinforced Concrete Structures, Stephen V. Grelle

Masters Theses

"While externally-bonded fiber-reinforced polymer (FRP) composites are commonly used for the strengthening of structurally deficient reinforced concrete (RC) members, the topic of anchoring FRP to concrete to achieve higher design strengths has not been addressed. Many innovative systems have been developed to anchor FRP to concrete, but the research involving these anchorage systems is not centralized and is therefore difficult to access. Additionally, systematic testing procedures for evaluating the strength of an anchorage system have not been widely used. To aid in the organization of anchorage system research and facilitate a better understanding of anchorage system behavior, a categorization system …

Quantifying The Carbon Footprint Of Lean Waste, Kristen Donovan Balinski

Masters Theses

"The objective of this paper is to provide a method of quantifying lean wastes in terms of carbon dioxide emissions by using value stream mapping. Lean manufacturing, a process based on waste identification and reduction, is a growing trend in industry and a proven method of lowering costs. The environmental impact of these wastes can be quantified by identifying the metrics associated with them, and using existing reports to convert those metrics into measurements of carbon dioxide. Growing environmental concerns are prompting federal government regulation of greenhouse gas or carbon dioxide emissions, as seen in the American Clean Energy and …

Development And Testing Of Chemically-Based Self-Consolidating Concrete, Mark Daniel Ezzell

Masters Theses

"Self-consolidating concrete (SCC) possesses several characteristics that can benefit the concrete construction industry including accelerated construction, a reduction in labor and equipment, and a reduction in construction noise through eliminating or reducing the need to vibrate the concrete. However, SCC has some potential downsides. These problems can usually be attributed to higher paste content, higher fines content, rounder aggregate, and higher water to cement (w/c) ratios used to increase the flow of the concrete. The goal of this research project was to develop a SCC that had improved material properties through the use of chemical admixtures instead of modifications to …

Integration Of Model-Based Systems Engineering And Virtual Engineering Tools For Detailed Design, Akshay Kande

Masters Theses

"Design and development of a system can be viewed as a process of transferring and transforming data using a set of tools that form the system's development environment. Conversion of the systems engineering data into useful information is one of the prime objectives of the tools used in the process. With complex systems, the objective is further augmented with a need to represent the information in an accessible and comprehensible manner. The importance of representation is easily understood in light of the fact that the stakeholder's ability to make prompt and appropriate decisions is directly related to his understanding of …