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Predictors And Outcomes Of Occupational Commitment Profiles Among Nurses, Lindsay Sears Dec 2010

Predictors And Outcomes Of Occupational Commitment Profiles Among Nurses, Lindsay Sears

All Dissertations

Occupational turnover is a costly problem afflicting much of the nursing industry, and occupational commitment is a strong predictor of withdrawal from one's profession. Traditional organizational research examines most commitment-behavior relationships from a variable-centered perspective, focusing on the relationships between constructs. The present study adopts a configural, or person-centered approach aimed at identifying and describing clusters of individuals who share a similar set of occupational commitment mindsets. The present study extends current literature by a) investigating the existence of several occupational commitment profiles and describing their characteristics; b) examining situational and demographic predictors of profile membership; and c) testing differences …


Synthesis Of Trimetallic Nitride Endohedral Metallofullerene Derivatives For Enhanced Solar Energy Conversion, Julio Pinzon Joya Dec 2010

Synthesis Of Trimetallic Nitride Endohedral Metallofullerene Derivatives For Enhanced Solar Energy Conversion, Julio Pinzon Joya

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The preparation and electrochemical properties of donor - acceptor systems based on trimetallic nitride endohedral metallofullerenes (TNT-EMFs) for enhanced solar energy conversion is described. It was found that TNT-EMFs have an enhanced ability to stabilize charge separated states formed upon light irradiation when compared to empty cage fullerene analogues. The influence of the linker connecting the donor and acceptor moieties was studied in two different systems. Optimal conditions for preparing cyclopropanated Bingel-Hirsch derivaties of the most common TNT-EMFs were found; this functionalization approach is a very useful alternative to the 1,3-dipolar cycloaddition reactions that yield pyrrolidine derivatives, because the latter …


Uncertainty Of Dimensional Measurments Obtained From Self-Initialized Instruments, Vincent Lee Dec 2010

Uncertainty Of Dimensional Measurments Obtained From Self-Initialized Instruments, Vincent Lee

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Precision dimensional measurement instruments often contain sensors that can only measure displacement of a moving body from some reference position. In order to measure the length of an object they often require a calibrated artifact to initialize their measurement sensors so that they may provide an absolute measurement instead of displacement. Instruments which can realize a null value, i.e. zero length, don't require one; however instruments which can't need to reference an object of known size. These calibration artifacts also serve as part of the chain of metrological traceability.
The group of instruments presented in this dissertation can self-initialize by …


Population Variability Of Rotylenchulus Reniformis In Cotton Agroecosystems, Megan Leach Dec 2010

Population Variability Of Rotylenchulus Reniformis In Cotton Agroecosystems, Megan Leach

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Rotylenchulus reniformis, reniform nematode, is a highly variable species and an economically important pest in many cotton fields across the southeast. Rotation to resistant or poor host crops is a prescribed method for management of reniform nematode. An increase in the incidence and prevalence of the nematode in the United States has been reported over the last two decades. However it is not clear whether the observed increase is related to the emergence of novel populations that are more aggressive or have a higher fitness or shifts in host availability or susceptibility. The objectives of this research were to determine …


Evolutionary Strategies For Data Mining, Rose Lowe Dec 2010

Evolutionary Strategies For Data Mining, Rose Lowe

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Learning classifier systems (LCS) have been successful in generating rules for solving classification problems in data mining. The rules are of the form IF condition THEN action. The condition encodes the features of the input space and the action encodes the class label. What is lacking in those systems is the ability to express each feature using a function that is appropriate for that feature. The genetic algorithm is capable of doing this but cannot because only one type of membership function
is provided. Thus, the genetic algorithm learns only the shape and placement of the membership function, and in …


A Study Of The Statistics Of The Air/Water Interfacial Temperature Field During Mixed Convection Heat Transfer, Jie Kou Dec 2010

A Study Of The Statistics Of The Air/Water Interfacial Temperature Field During Mixed Convection Heat Transfer, Jie Kou

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Heat transfer across an air/water interface is of particular importance to limnology, oceanography and some industrial applications. The relationship between the statistics of the air/water interfacial temperature field and the interfacial heat flux is poorly understood, particularly for the mixed convection condition, which is a common heat transfer mechanism for small inland lakes. The few studies that have been conducted under mixed convection conditions have been limited to an uncontrolled surfactant condition (tap water). Therefore, in this dissertation research two sets of experiments for wind speeds from 0 to 4 m/s were conducted: controlled surfactant contaminated conditions (with oleyl alcohol) …


Studies Relevant To The Design Of Reliable Automotive Electronics, Hua Zeng Dec 2010

Studies Relevant To The Design Of Reliable Automotive Electronics, Hua Zeng

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This dissertation describes three independent studies related to the design of reliable automotive electronics. The topics covered are: the estimation of the radiated emissions from power bus structures, EM propagation of tire pressure monitoring systems (TPMS), and examinations of corrosion-induced faults in a connector.
The first chapter describes a method for estimating the maximum possible radiated emissions from a printed circuit board power bus. An analysis based on a lossy cavity model is performed to determine the maximum possible radiated field corresponding to a given power bus noise voltage. A closed-form expression relating the maximum power bus noise voltage to …


Production And Characterization Of Aramid Copolymer Fibers For Use In Cut Protection, Jeffrey Moreland Dec 2010

Production And Characterization Of Aramid Copolymer Fibers For Use In Cut Protection, Jeffrey Moreland

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High-performance fibers such as para-aramids are used extensively in gloves for cut protection. However, the inherent cut resistance of these fibers and the relationship between cut resistance and other material properties is not known. To better understand cut resistance at the material level, an experiment was conducted using a lab-scale wet spinning system to produce and characterize aramid copolymer fibers.
To facilitate the use of lab-scale equipment, the experiment was conducted as a four-factor split-plot response surface design. The four treatment factors studied were solvent concentration in the coagulation bath, the amount of salt in the coagulation bath, the degree …


Sequencing And Functional Analysis Of A Multi-Component Dioxygenase From Pah-Degrading Sphingomonas Paucimobilis Epa505, Renuka Miller Dec 2010

Sequencing And Functional Analysis Of A Multi-Component Dioxygenase From Pah-Degrading Sphingomonas Paucimobilis Epa505, Renuka Miller

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Polycyclic aromatic hydrocarbons (PAHs) are hydrophobic organic compounds consisting of two or more fused benzene rings. PAHs derive from many different sources including petroleum refining, wood treatment, and coal coking industries. Because of their structural stability and water insolubility, PAHs are extremely resistant to degradation. These compounds are also believed to have mutagenic, carcinogenic, and teratogenic effects. Therefore, there are currently 16 PAH compounds on the EPA's list of priority pollutants.
Many species of bacteria have the ability to breakdown these persistent pollutants. However, bioremediation strategies using these organisms have many unresolved issues. While laboratory experiments can easily demonstrate the …


Online Reading Comprehension Among Seventh Grade Students With High Incidence Disabilities In Inclusive Settings: A Mixed Methods Study, Katherine Robbins Dec 2010

Online Reading Comprehension Among Seventh Grade Students With High Incidence Disabilities In Inclusive Settings: A Mixed Methods Study, Katherine Robbins

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Because research exploring how students with disabilities read and comprehend on the Internet is scarce, a mixed methods study was implemented to determine if Internet Reciprocal Teaching (IRT) is an effective intervention for improving online reading comprehension among seventh grade students with high-incidence disabilities in inclusive settings. Differences between students with disabilities and their non-disabled peers were also explored.
The intervention included a twenty week (40 lessons) instructional program delivered in three phases in seventh grade English/Language Arts classes from three middle schools in eastern region of the United States. Pre and post intervention data was collected on the Online …


Circuit Modules For Broadband Cmos Six-Port Systems, Chaojiang Li Dec 2010

Circuit Modules For Broadband Cmos Six-Port Systems, Chaojiang Li

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This dissertation investigates four circuit modules used in a CMOS integrated six-port measurement system. The first circuit module is a wideband power source generator, which can be implemented with a voltage controlled ring oscillator. The second circuit module is a low-power 0.5 GHz - 20.5 GHz power detector with an embedded amplifier and a wideband quasi T-coil matching network. The third circuit module is a six-port circuit, which can be implemented with distributed or lumped- lement techniques. The fourth circuit module is the phase sifter used as calibration loads. The theoretical analysis, circuit design, simulated or experimental verifications of each …


Modeling The Galactic 511 Kev Positron Annihilation Emission, Production, And Propagation, Bethany Johns Dec 2010

Modeling The Galactic 511 Kev Positron Annihilation Emission, Production, And Propagation, Bethany Johns

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The Galactic 511 keV positron annihilation emission has a strong bulge component to the emission and a weak disk component. The bulge emission is about 1.4 -- 6 times as the disk emission. The bulge emission is defined to be a diffuse emission centered at the Galactic center and extends to about a FWHM of 8 degrees in Galactic longitude and latitude. An asymmetry has also been observed in the disk emission, where the negative longitudes are brighter than the positive longitudes by a factor of 1.8.
This research examines the morphology of the Galactic 511 keV positron annihilation emission …


Nitrosative Stress And Dna Repair In Microorganisms, Sung-Hyun Park Dec 2010

Nitrosative Stress And Dna Repair In Microorganisms, Sung-Hyun Park

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DNA can be damaged by reactive nitrogen intermediates (RNI) and reactive oxygen intermediates (ROI) from both endogenous and exogenous sources. Under nitrosative stress conditions, DNA may be modified through base deamination or crosslinking. Uracil (U), xanthine (X) and oxanine (O), hypoxanthine (I), and thymine (T) are the corresponding deamination products derived from cytosine (C), guanine (G), adenine (A), and 5-methylcytosine, respectively. To remove DNA damage, cells are equipped with a variety of DNA repair enzymes which participate in different repair pathways.
My dissertation work involves studies of genes and enzymes in nucleotide excision repair (NER) and base excision repair (BER) …


Modeling Microbial And Nutrient Dynamics In Zero-Discharge Aquaculture Systems, Kendall Kirk Dec 2010

Modeling Microbial And Nutrient Dynamics In Zero-Discharge Aquaculture Systems, Kendall Kirk

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A finite element, finite difference model was developed to predict nutrient and microbial dynamics in recirculating aquaculture systems. Total ammonia nitrogen, nitrite, nitrate, chemical oxygen demand, and dissolved oxygen concentrations are predicted in addition to growth and decay of algae, Nitrosomonas, Nitrobacter, denitrifying heterotrophs, and aerobic heterotrophs. Inputs to the model include temperature, photosynthetically available radiation, feed application rate, pH, aeration/mixing energy, water exchange configuration, water exchange rate, tilapia biomass, and dissolved oxygen concentration. Up to 10 exchanged units may be included, user-definable as continuous stirred tank reactors or sequencing batch reactors. Demonstration of the model's utility was demonstrated through …


Evaluation Of Factors That Modulate Cellular Adipogenesis For Breast Tissue Engineering Strategies, Cheryl Gomillion Dec 2010

Evaluation Of Factors That Modulate Cellular Adipogenesis For Breast Tissue Engineering Strategies, Cheryl Gomillion

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It is estimated that this year more than 200,000 women in the United States will be diagnosed with breast cancer. Treatment for most occurrences of breast cancer will often include surgical removal of the tumorigenic tissue, resulting in a soft tissue defect within the subcutaneous tissue of the skin. Post-surgical reconstruction methods are often sought by patients to restore the aesthetic function of the breast via cellular or non-cellular methods; however, because of complications associated with currently used methods for breast reconstruction, researchers are investigating tissue engineering methods to produce viable autologous adipose tissue for breast reconstruction.
Previous research in …


Characterization Of Anti-Proteolytic And Anti-Proliferative Activities Of Pentagalloylglucose; Its Potential Application As A Therapeutic Agent In Vascular Diseases, Chaitra Cheluvaraju Dec 2010

Characterization Of Anti-Proteolytic And Anti-Proliferative Activities Of Pentagalloylglucose; Its Potential Application As A Therapeutic Agent In Vascular Diseases, Chaitra Cheluvaraju

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Cardiovascular diseases are the leading causes of mortality in the United States and will cost around $500 billion this year alone. Elevated proteolytic activity, increased proliferation and migration of vascular smooth muscle cells are hallmarks of atherosclerosis, stenosis and aortic aneurysms. These diseases often manifest the transdifferentiation of vascular smooth muscle cells into osteoblast-like cells followed by deposition of hydroxyapatite–like mineral in the arterial walls.
Currently, there are no standard treatments available for vascular calcification or aneurysms. Atherosclerosis treatment options are limited to statins while balloon angioplasty and stenting – surgical procedures for stenosis, often end in restenosis. Therefore, we …


An Investigation Of The Relationship Between Service Quality, Transaction-Specific Satisfaction, And Overall Satisfaction In Predicting Golfers' Revisit Intentions, Joon Choel Lee Dec 2010

An Investigation Of The Relationship Between Service Quality, Transaction-Specific Satisfaction, And Overall Satisfaction In Predicting Golfers' Revisit Intentions, Joon Choel Lee

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ABSTRACT
Every year, approximately 37 million people play golf and use golf course facilities with friends or family, and each group's perception of satisfaction differs. It is important and worthwhile to examine the variables that influence golfers' perceptions of service quality and satisfaction. Understanding which variables best predict behavioral intentions to revisit certain facilities is an important issue in the tourism industry, but few studies have investigated the relationships between service quality, transaction-specific satisfaction, and overall satisfaction in predicting revisit intention.
The purpose of this study is to compare and investigate conceptual frameworks that represent the relationship between golfers' perceived …


Preparation And Studies Of Fluorescent Carbon Nanomaterials, Xin Wang Dec 2010

Preparation And Studies Of Fluorescent Carbon Nanomaterials, Xin Wang

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There have been rapid advances in the development and applications of semiconductor quantum dots (QDs) represented by CdSe/ZnS. However, a serious limitation of these QDs is the necessary use of toxic heavy metals. Fluorescent 'carbon dots' (surface passivated carbon nanoparticles) are developed as alternative to classical semiconductor QDs.
The carbon dots could be made to be highly fluorescence, with emission quantum yields close to 60%. Their optical properties resemble bandgap transitions found in nanoscale semiconductors, suggesting that carbon particles at the nanoscale acquire essentially semiconductor-like characteristics.
The fluorescence in carbon dots could be quenched efficiently by electron acceptor or donor …


Development And Characterization Of Novel Sub-Coatings With Polymorphic Brookite Titania Nanoparticles: Enhanced Uv/Vis Photocatalytic Antibacterial And Anticancer Properties, Donna Weinbrenner Dec 2010

Development And Characterization Of Novel Sub-Coatings With Polymorphic Brookite Titania Nanoparticles: Enhanced Uv/Vis Photocatalytic Antibacterial And Anticancer Properties, Donna Weinbrenner

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ABSTRACT
Nosocomial and community infections and biofilm formation from bacteria has increased significantly through adaptation combined with overuse of broad spectrum antibiotics. Because the world population continues to escalate, hospitals and long-term managed care will also escalate, thereby increasing transmission of infections, lowering patients' quality of health. Another disease on the rise throughout the world is skin cancer. A treatment modality that would cause less deleterious effects on the patient would be ideal. These two seemingly different issues could be solved with one product. First an inexpensive, safe, and non-selective antimicrobial surface coating would enhance the hospital arena and a …


Modeling Greenhouse Gas Emissions From Conventional Wastewater Treatment Plants In South Carolina, Andrea Hicks Dec 2010

Modeling Greenhouse Gas Emissions From Conventional Wastewater Treatment Plants In South Carolina, Andrea Hicks

All Theses

Wastewater treatment is an essential part of life in the urbanized world. As global climate change becomes a more pressing issue, the greenhouse gas emissions created through wastewater treatment will become a more prominent concern. Tertiary treatment will likely be standard for wastewater treatment plants in the near future, and therefore must be included in a model of greenhouse gas emissions. Also, the geographic location of a WWTP will change the mix of power types (e.g., coal, nuclear, biomass) used to run the plant. Although GHG emissions from the waste sector are small compared to the emissions of the United …


The Synthesis, Characterization, And Electrochemical Study Of Tris(Pyrazolyl)-Type Iron(Ii) Complexes, Iron(Ii) Sulfur- And Selenium-Containing Complexes, And Tris(Pyrazolyl)-Type Ruthenium(Ii) Complexes, Christopher Underwood Dec 2010

The Synthesis, Characterization, And Electrochemical Study Of Tris(Pyrazolyl)-Type Iron(Ii) Complexes, Iron(Ii) Sulfur- And Selenium-Containing Complexes, And Tris(Pyrazolyl)-Type Ruthenium(Ii) Complexes, Christopher Underwood

All Theses

Highly reactive radical species such as hydroxyl radical cause oxidative stress, resulting in chronic or degenerative diseases. In the biological Fenton reaction, iron(II) generates hydroxyl radical, OH, but only within a specific electrochemical potential window (-324 mV to 640 mV). Selenium and sulfur compounds have been extensively studied for their antioxidant properties, and they may exert their effects by binding iron(II) and shifting its electrochemical potential out of this window. This work has investigated the synthesis and electrochemical characterization of iron(II) chalcogenate complexes and iron(II) chalcogenone complexes. Cyclic voltammetry (CV) of [Fe(EPh)4][(PPh4)2] (E = S, Se) complexes shows Fe2+/3+ redox …


Mapping Problem And Requirements To Solution: Document Analysis Of Senior Design Projects, Shraddha Joshi Dec 2010

Mapping Problem And Requirements To Solution: Document Analysis Of Senior Design Projects, Shraddha Joshi

All Theses

Formulating and solving engineering problems and designing solutions that meet the established requirements are important skills that graduating engineering students need to possess. However, there are noticeable gaps in the literature with respect to understanding how the formulation of design problems and establishment of requirements affect the final design solution. This thesis is an initial attempt to understand the influence of level of detail of problem statement and requirements on the level of detail of final solution. In doing so, a document analysis of final reports from senior design class collected over a period of ten years from 1999 to …


Correcting Liquefaction Resistance Of Partially Saturated Soil Using Compression Wave Velocity, Md Hossain Dec 2010

Correcting Liquefaction Resistance Of Partially Saturated Soil Using Compression Wave Velocity, Md Hossain

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Empirical relationships for correcting liquefaction resistance of partially saturated soil using longitudinal (P-) wave velocity (VP) and shear (S-) wave velocity (VS) are developed and evaluated in this thesis. The relationships are based on the laboratory test results for four different types of sands and one silt published by other investigators. The data used to develop the relationship with VP exhibit less scatter than the data used to develop the relationship with VP/VS. For this reason, the VP based relationship is recommended for correcting liquefaction resistance of partially saturated soil. …


Pulse Echo Ultrasonic Testing Of Adhesive Bonded Joints For Automotive Applications, Arun Ganapathi Dec 2010

Pulse Echo Ultrasonic Testing Of Adhesive Bonded Joints For Automotive Applications, Arun Ganapathi

All Theses

The growing prominence of adhesive bonding technology in automotive manufacture has necessitated the development of reliable and robust quality assurance techniques. Of the different Nondestructive testing technologies available, Ultrasonic testing has shown itself to be the most promising technique to satisfy the requirements in automobile production. The current work attempts to apply two variations of the Ultrasonic Pulse Echo technique namely Contact and Immersion testing for inspecting typical hem bonded automotive joints. The joints have been tested for disbond at the various metal-adhesive interfaces by using an ultrasonic scan comparison method which compares the acquired signals against a reference scan …


Analysis Of Part Consolidation Techniques For Automotive Body In White Panels Based On Advanced Sheet Metal Forming Technologies, Harish Thiruvengadam Dec 2010

Analysis Of Part Consolidation Techniques For Automotive Body In White Panels Based On Advanced Sheet Metal Forming Technologies, Harish Thiruvengadam

All Theses

The automotive industry is looking to move from mass production to mass customization in order to manufacture and sell a variety of products in different markets on a global scale. This requires a robust and cost effective manufacturing system which would help design new products in the shortest possible lead time. This thesis tries to investigate the current sheet metal forming process for body in white, identify the limitations and propose an alternative which would help the industry cut down product lead time and costs. Decision making tools are used to identify the technical requirements of a BIW manufacturing system …


Letting The Light In, Owen Riley Dec 2010

Letting The Light In, Owen Riley

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LETTING THE LIGHT IN
Owen Riley Jr.
December 2010
ABSTRACT
'Forget your perfect offering, there is a crack in everything. That's how the light gets in.' Leonard Cohen
My thesis is a visual meditation on the transitions of life, death, love and emotion that come with age and responsibility. It is what I can touch and feel viewed through the frame of domesticity. It is a ballad of introspection, melancholy and hope redefining the beauty that has been masked by the fractures of time.
My thesis presents my self-created visions of the reality that surrounds me channeled through the 19th. …


Between Spaces, Holes, And Absences, Hanna Kozlowski Slone Dec 2010

Between Spaces, Holes, And Absences, Hanna Kozlowski Slone

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In this work, I investigate the fragmentary nature of my family history as perceived
through second and third hand experiences. Rather than functioning as an authoritative
documentation of the past, the resulting works emphasize the disconnection between direct and imagined experience. In the paper cut pieces and corresponding oil paintings,
photographs are excavated from the historical archive and strategically reassembled to create narratives. These partial accounts are accessed through the 'memory of a memory', extruded from a mental collection of stories that have been imparted to me at various times throughout my life. The experiences of my grandfather, great uncles, …


Fuor And Exor Variables: A Nir High-Resolution Spectroscopic Survey, Joseph Liskowsky Dec 2010

Fuor And Exor Variables: A Nir High-Resolution Spectroscopic Survey, Joseph Liskowsky

All Theses

To better understand the labyrinth of heating and cooling processes in YSOs (young stellar objects), we study systems where there exists a large variability in the heating of this gas due to accretion. This research project focuses on several classes of early young eruptable T-Tauri stars, namely the FUors, the EXors and the so-called FU Ori-like, which all have the property of large amplitude oscillations in accretion rate. Each of these categories may well represent specific stages in early low-mass stellar evolution. While these objects have specific spectroscopic and circumstellar diagnostics (as means of identification) our research suggests that there …


Explicit Level Lowering Of 2-Dimensional Modular Galois Representations, Rodney Keaton Dec 2010

Explicit Level Lowering Of 2-Dimensional Modular Galois Representations, Rodney Keaton

All Theses

Let f be a normalized eigenform of level Npα for some positive integer α and some odd prime p satisfying gcd(p,N)=1. A construction of Deligne, Shimura, et. al., attaches a p-adic continuous two-dimensional Galois representation to f. The Refined Conjecture of Serre states that such a representation should in fact arise from a normalized eigenform of level prime to p.
In this presentation we present a proof of Ribet which allows us to 'strip' these powers of p from the level while still retaining the original Galois representation, i.e., the residual of our new representation arising from level N will …


In Vitro Boosting And Expansion Of Tumor Infiltrating Killer T Cells, Chunlei Mei Dec 2010

In Vitro Boosting And Expansion Of Tumor Infiltrating Killer T Cells, Chunlei Mei

All Theses

Immune cell tumor infiltration represents one of the mechanisms that the immune system responds to tumor cells. The tumor infiltrated immune cells include lymphocytes (TIL), dendritic cells (DCs), macrophages, and natural killer (NK) cells. Although TILs have been extensively studied in order to develop adoptive transfer based immunotherapies, how to effectively isolate, culture, and in vitro boosting the killer cells from TILs remains a challenge. Meanwhile, OK-432, a heat and penicillin-treated lyophilized preparation of the low-virulence strain of Streptococcus pyogenes, has been shown to exhibit immunomodulatory activities and potential antitumor therapeutic function, including the activation of DCs, neutrophils, macrophages, lymphocytes, …