Digital Commons Network^™

Mitigation Impact Of Statewide Non-Pharmaceutical Policies On Covid-19: An Application Of Infectious Disease Transmission Model And Partially Observed Markov Process To New Mexico, Xingya Ma

Mathematics & Statistics ETDs

This thesis is an application of epidemiological models for infectious disease transmission and the use of partially observed Markov process (POMP) for model fitting. It focuses on COVID-19 pandemic in the state of New Mexico. The analysis covered March 2020 to June 2021. Daily data of COVID19 cases and deaths and a daily index of eleven statewide government non-pharmaceutical intervention (NPI) policies were collected from six public sources and were validated. These data were integrated through the Susceptible-Exposed-Infected-Removed (SEIR) model. Estimated daily transmission rates between the model compartments quantify the impact of the mitigation policies, and show that transmission rates …

Hydrologic Modeling With Remote Sensing For The Estimation Of Groundwater Resources Within The Sand River Catchment, South Africa, Sophia Bakar

Electronic Theses and Dissertations

The Sand River Catchment is an important tributary of the transboundary Limpopo River in South Africa, which spans Botswana, Mozambique, South Africa, and Mozambique. Groundwater is a critical resource in the region, especially in the context of population growth and climate change. Data are needed for proper management of these water resources. In regions where groundwater data are sparse in time, space, or both, the most promising solutions come from satellites and hydrologic models. Regional literature suggests that the Soutpansberg Mountains, located within the Sand Catchment, are high-elevation water towers with uncertain groundwater resources. Improved understanding of groundwater resources in …

Assessments Of Water Chemistry And Fish Community Structure In The Buffalo Creek Watershed, Tributary To The Allegheny River In Armstrong And Butler Counties, Pennsylvania, Kathleen Wilson

Electronic Theses and Dissertations

The Buffalo Creek watershed has experienced water quality impairments for various reasons, including but not limited to, agricultural influence, abandoned mine drainage (AMD), on-site wastewater malfunction, and stormwater. The source and cause of the most prevalent impaired areas remains unknown. The goal of this study was to analyze water chemistry using state water quality standards and mass ratio analysis, then to conduct fish community analysis. We found toxic metal pollution across the watershed, with iron, cadmium, copper, and selenium frequently exceeding criteria. We determined which streams are polluted by resource extraction activities by conducting mass ratio analysis. We found conventional …

To Destroy Or Transform? Two Fossil Fuel Transitions Offer Glimpse Into Industry’S Future, Chloe Bennett, Sarah Kerson

Capstones

In 2019, the Philadelphia Energy Solutions oil refinery closed after a dangerous explosion. But for years before the accident, members of the local environmental justice organization Philly Thrive had been advocating for its closure. Neighborhood residents who live near the refinery site had been complaining for years of health problems, ranging from asthma to cancer. “Enough is enough,” says Sylvia Bennett, 79, who lives in the Grays Ferry neighborhood near where the refinery is located. Her two daughters have both been diagnosed with cancer.

What will become of the refinery site remains to be seen as conversations between Hilco and …

Interpretable Network Representations, Shengmin Jin

Dissertations - ALL

Networks (or interchangeably graphs) have been ubiquitous across the globe and within science and engineering: social networks, collaboration networks, protein-protein interaction networks, infrastructure networks, among many others. Machine learning on graphs, especially network representation learning, has shown remarkable performance in network-based applications, such as node/graph classification, graph clustering, and link prediction. Like performance, it is equally crucial for individuals to understand the behavior of machine learning models and be able to explain how these models arrive at a certain decision. Such needs have motivated many studies on interpretability in machine learning. For example, for social network analysis, we may need …

Secondhand Shopping Is Now The Coolest Way To Get Your Clothes, Camryn Quick

Capstones

Shopping secondhand has experienced an uptick in popularity in the past few years. There are a few reasons for this, all of which are examined in the project. One reason for the increase in secondhand shoppers is the daunting news about the state of our environment. Another reason, perhaps even more powerful than the fear of environmental collapse, is that thrifting has become a fashion phenomenon showcased and distributed throughout social media apps like TikTok. Essentially, shopping secondhand has become cool. This project explores these driving forces behind the thrifting boom, as well as the possible impacts, including "thrift store …

Speciated Isotope Dilution Mass Spectrometry In Combination With Thor’S Hammer Metaspike Technology For The Assessment Of Low-Level Biomarkers For Human Health Evaluation, Ashley Ebert

Electronic Theses and Dissertations

Our research team has been focused on quantifying important biological analytes in human blood samples to delineate the biochemical processes underlying certain states of dysfunction and evaluate treatment efficacy. These efforts have been guided by laboratory measurements with the input of medical experts. Speciated isotope dilution mass spectrometry (SIDMS) explained in detail in EPA Method 6800 has been successfully applied in the quantification of an important biomarker analyte for immune function and detoxification processes: glutathione. Past research has proven the molecule a biomarker for autism spectrum disorder (ASD) in the form of the reduced/oxidized glutathione (GSH/GSSG) ratio, and literature has …

Quantum Computations And Molecular Dynamics Simulations: From The Fundamentals Of Antimicrobial Resistance To Neurological Diseases, Angel Tamez

Electronic Theses and Dissertations

Biophysical phenomena are modeled using a combination of quantum and classical methods to interpret and supplement three distinct and diverse problems in this dissertation. In the first project, decarboxylation reactions are ubiquitous across chemical and biological disciplines, yet the origin of non-catalytic solvent effects remains elusive. Specific solvent structure and energetics have not been well described for the monoanion of malonate, nor corrected from the gas-phase charge-assisted intramolecular hydrogen bond model known as “pseudochair”. In the aqueous phase, a low-lying energy conformer known as the “orthogonal conformation” is computed to be preferred by a three-water cluster of hydrogen bonding over …

Sunflower Oil-Based Polyol In Flame-Retardant Rigid Polyurethane Foams, Magdalene Asare

Electronic Theses & Dissertations

The current shift from solely depending on petroleum sources to seeking renewable alternatives is due to their fast depletion, spike in prices, and the need to reduce our carbon footprint. For instance, the polyurethane industry currently calls for renewable and less toxic polyols and isocyanates for their synthesis over the traditionally used ones. To tackle an aspect of this matter, this work investigates the generation of polyol from sunflower oil, and further probes their use in rigid foams, one of the widely utilized polyurethanes. Epoxidation and ring-opening reactions were used to convert the sunflower oil into a more reactive form, …

Bio-Based Uv-Curable Films And The Effect Of Bio-Content On The Properties Of The Films, Sahilkumar Chaudhary

Electronic Theses & Dissertations

The use of renewable resources in film formation has become a new focal point for industry because it is abundantly available and has less carbon emission during production than traditional ones. This has drawn researchers to investigate the functionality of bio-based raw materials and their end-usage. By modifying their chemical structures, the properties of these films like thermal resistance, impact resistance, and chemical resistance can be increased. In this research, limonene was used as a partial replacement for petroleum-based chemicals in film formation. A two-step chemical process was carried out to modify the limonene and the final product was used …

Investigation Of Cryptotephra In Polar Ice Cores, Meredith Helmick

Electronic Theses and Dissertations

Volcanic ash (tephra) present within polar ice cores greatly supplements our understanding of past volcanism and its impacts on society and the state of the climate system. This thesis investigates the utility and limitations of ice core tephrochronology in answering questions related to volcanic source identification of ice core glaciochemical signals, tephrostratigraphy of an Antarctic ice core, and the timing of major and climate forcing eruptions. This thesis explores the efficacy of SEM-EDS measurements on ultra-fine (µm) volcanic particles for the purpose of geochemically characterizing a non-visible ice-embedded tephra and the subsequent identification of the volcanic source. In combination with …

Gold (I) Tetrathiomolybdate Clusters: Synthesis, Characterization, Computational Studies, And Reactivity With Thiophenol And Selenophenol, Dhirgam Humaidy

Electronic Theses and Dissertations

This thesis describes the synthesis and reactivity of heterometallic complexes containing medicinally active Au(I) and tetrathiomolybdate, [MoS₄]^2-. The research is motivated by the idea of multifunctional drugs, which are designed to treat diseases through two or more mechanisms of action. Five clusters of the general form, [MoS₄(AuL)₂] were prepared: C-1 (L=IPr), C-2 (L=IBzMe), C-3 (L=IMes), C-4 (L=PPh₃), and C-5 (L=PEt₃). The clusters with NHC ligands, C-1, C-2, and C-3 were prepared for the first time and thoroughly characterized by ¹H NMR,¹³C{¹H} …

Barriers To And Opportunities For Adoption In Maine’S Aquaculture Industry, Caitlin Cleaver

Electronic Theses and Dissertations

Aquaculture, or the farming of marine species, can diversify coastal economies, but development of this industry is hindered by negative perceptions or regulatory constraints. Commercial fishers are logical adopters of aquaculture, but can also mount opposition to its growth. This dissertation utilized innovation theory to understand fishers’ perceptions of and willingness to adopt aquaculture and drivers of and barriers to scallop aquaculture development in Maine (USA). Through a mail survey, lobster fishers’ perceptions of Maine’s aquaculture industry and their willingness to adopt aquaculture were assessed (Chapter 2). Individuals who were more satisfied with government management of aquaculture held more positive …

Regional Scale Generalizations Of Firn Thickness And Snow Accumulation In Southeast Alaska: An Applied Deep Learning Framework, Jonathan Maurer

Electronic Theses and Dissertations

High elevation mountain glaciers are referred to as the “water towers of the world” due to their ability to store water internally and release it later through melt and runoff. Much of the work to understand these complex environments has focused on cold based polar glaciers in high latitude regions, neglecting temperate glaciers and associated snowpack which are more responsive than polar systems to minor climatic changes. Advancements in the availability of open source data, deep learning theory, and computational efficiency has opened up new methods of “data hungry” modeling that may be well suited to the type of complex …

Holocene And Last Glacial Period Atmospheric Dynamics And Biogeochemistry Based On South Pole Ice Core Microparticle And Trace Element Records, Aaron Chesler

Electronic Theses and Dissertations

I develop and interpret a record of dust deposition from the South Pole ice core (SPC14) to identify changes in atmospheric variability. The SPC14 core was drilled during 2014 – 2016 and provides a high accumulation (~7 cm w.e.q. per year) record in central Antarctica that reaches a depth of 1751 m (~54 ka). My analysis combines microparticle (dust) concentration, size, and shape metrics using continuous and discrete methodologies and high- and low-resolution multifractional Fe analyses that span the past 54 ka.

Results from my dust shape analysis suggest the common assumption of spherical dust particle shape in incorrect and …

Acetylacetone Oxidation At Room Temperature: A Multiplexed Photoionization Mass Spectrometric Investigation, Study Of The Russell Intermediates In Gas Phase Reactions, And The Investigation Of Oxidation Reaction Products Of Ethanol At Room Temperature, Sara Gallarati

Master's Theses

This thesis presents the combustion study of acetyl acetone using synchrotron radiation coupled with multiplexed photoionization mass spectrometry at 298 K. The experiments were performed at the Chemical Dynamics Beamline 9.0.2 at the Advanced Light Source of the Lawrence Berkeley National Laboratory. The reaction of acetyl acetone with chlorine (Cl) radicals was analyzed based on their photoionization spectra and reaction kinetic profiles.

Additionally, a study of the Russell intermediate has been performed. Previous to experimentation at the Advanced Light Source, computational analysis has been investigated to evaluate compounds that could possibly lead to the formation of a stable species. The …

Anthropogenic Effects On Tidal Distortion In A Tidal River, Matthew D. Fischer

Electronic Theses and Dissertations

Tidal rivers are landward portions of estuarine systems constituting the union between coastal, tidally controlled settings and rivers, where fluvial processes dominate. In these reaches, river discharge (mean flow) and tides are the two most important mechanisms in controlling geophysical flows. The processes governing water levels and current amplitudes in tidal rivers are highly nonlinear and modulated by external forcings- thus requiring sophisticated techniques for accurate prediction and forecasting. Physical oceanographers and estuarine physicists tend to limit their study area to the maximum extent of the horizontal tide (salinity intrusion), not the most landward point influenced by tidal water levels. …

Plasma-Assisted Growth And Characterization Of Piezoelectric Aln And Sc(X)Al(1-X)N Films For Microwave Acoustic Sensor Applications, Morton Greenslit

Electronic Theses and Dissertations

The use of surface acoustic wave (SAW) sensors in high temperature harsh environments such as those found in power plants, industrial manufacturing, or aerospace applications allows for monitoring of internal conditions at locations where traditional sensors do not operate or are unreliable. Surface acoustic wave resonator (SAWR) sensors are based on piezoelectric materials and feature a small passive low-profile self-powered design that can operate and wirelessly transmit data to monitor parameters such as temperature, pressure, or strain. SAWR sensors typically consist of a series of metal electrodes fabricated onto a bulk crystal piezoelectric such as langasite (La3Ga5SiO14). However, there are …

First-Row Transition Element Distribution Across The Blueschist-Eclogite Transition: A Case Study From New Caledonia, Natalie M. Harmon

Electronic Theses and Dissertations

The first-row transition elements (FRTE), namely Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, are potential redox tracers in the solid Earth due to their general compatibility during crustal processes, and the redox-sensitive nature of certain elements. Despite widespread interest in the FRTEs, their distribution and behavior in subduction zones, particularly across the blueschist-eclogite transition, are still poorly constrained. New Caledonia preserves a prograde subduction zone with largely coherent continuous progression in metamorphic grade. Although the metamorphic sequence has been disrupted to some extent, this is the closest natural example of blueschist and eclogite that was sourced …

Understanding The Impacts Of Anthropogenic Effects An Habitat Variability Interactions On Maine's Rocky Intertidal Ecosystem, Laura Braun

Electronic Theses and Dissertations

The rocky intertidal ecosystem is an important ecological and cultural aspect of the picturesque Maine coast, playing a vital role in not only Maine’s coastal ecosystem, but also to Maine’s economy. It’s distinct community structure along the sharp elevational gradient and the presence of daily stressors (wave action, heat, and desiccation), make the rocky intertidal ecosystem an important model ecosystem to monitor for effects from anthropogenic impacts. In this thesis, I describe attempts to monitor and understand the impacts of two of these anthropogenic impacts on this system: climate change and industrial harvesting of Ascophyllum nodosum along Maine’s coast. For …

Carbon Dioxide Emissions From Deadwood In Forests Of The Northeastern United States, Zoe Read

Electronic Theses and Dissertations

As the climate changes, understanding the sources and sinks of greenhouse gases such as carbon dioxide (CO₂) is increasingly important. However, several components of the carbon cycle within forests remain poorly understood. For example, knowledge gaps exist in our understanding of CO₂ emissions from coarse woody material (CWM; logs and stumps), including how emissions change over time, how they are influenced by environmental variables, and how they compare to soil and ecosystem-level CO₂ emissions.

To fill these knowledge gaps, we examined CO₂ emissions from CWM at three sites. We sampled 18 red spruce (Picea …

Evaluating Equity In Transportation Greenhouse Gas Emission Reduction Strategies In Local Climate Action Planning In Oakland, California, Eliza J. Kane

Master's Projects and Capstones

Emissions from California’s transportation sector contribute to global climate change and impact local air quality and public health. Forty-one percent of California’s greenhouse gas emissions in 2019 were from transportation. Transportation emissions are also a source of many health-harming air pollutants such as carbon monoxide, volatile organic compounds, and particulate matter. Disadvantaged communities in California experience disproportionate impacts from transportation emissions and suffer worse health effects, including higher incidences of asthma, cardiovascular disease, and premature death. Cities have led the way in policymaking to mitigate and adapt to climate change, including creating Climate Action Plans (CAPs) to propose strategies to …

Analyzing The Effects Of Climate Impacts In El Salvador And How They Influence Pollution, Ecosystems And Communities, Veronica Norio-Tomasino

Master's Projects and Capstones

Due to projections of rising temperatures and increased frequency and severity of extreme weather events, the rate at which climate change is impacting nations is devastating. However, developing countries and vulnerable communities are not the primary contributors to climate change, but they are at a greater risk for climate impacts by industrialized nations. As a result of increased human activity, developing nations such as El Salvador are particularly susceptible to climate-related events. Deforestation, water pollution, and human health risks are some activities that have contributed to El Salvador's vulnerability to climate change, drastically affecting rural communities suffering from multidimensional poverty. …

Development Of Novel Nucleophile-Intercepted Beckmann Fragmentations And Progress Toward The Total Synthesis Of 2(S)-Cathafoline, Evan M. Dunkley

Dartmouth College Master’s Theses

This thesis is comprised of two chapters, the first being the discovery of a novel nucleophile-intercepted Beckmann fragmentation of [2.2.1] indoline systems that resulted in highly stereo- and regioselective reactions. Chapter one details the exploration of this reaction as well as its relevant background information detailing its significance. Chapter two describes the application of the novel nucleophile-intercepted Beckmann fragmentation in the context of a total synthesis of akuammilline alkaloid 2(S)-cathafoline. While the target natural product was never synthesized, unpredicted reactivity resulted in interesting discoveries worthy of discussion.

Low-Resource Machine Learning Techniques For The Analysis Of Online Social Media Textual Data, Toktam Amanzadeh Oghaz

Electronic Theses and Dissertations, 2020-

Low-resource and label-efficient machine learning methods can be described as the family of statistical and machine learning techniques that can achieve high performance without needing a substantial amount of labeled data. These methods include both unsupervised learning techniques, such as LDA, and supervised methods, such as active learning, each providing different benefits. Thus, this dissertation is devoted to the design and analysis of unsupervised and supervised techniques to provide solutions for the following problems: Unsupervised narrative summary extraction for social media content, Social media text classification with Active Learning (AL), Investigating restrictions and benefits of using Curriculum Learning (CL) for …

Observation Of Novel Phases Of Quantum Matter Beyond Topological Insulator, Sabin Regmi

Electronic Theses and Dissertations, 2020-

Because of the unique electronic properties, intriguing novel phenomena, and potentiality in quantum device applications, the quantum materials with non-trivial band structures have enticed a bulk of research works over the last two decades. The experimental discovery of the three-dimensional topological insulators (TIs) - bulk insulators with surface conduction via spin-polarized electrons - kicked off the flurry of research interests towards such materials, which resulted in the experimental discovery of new topological phases of matter beyond TIs. The topological semimetallic phase in Dirac, Weyl, and nodal-line semimetals is an example, where the classification depends on the dimensionality, degeneracy, and symmetry …

Full-Text Search Using Elasticsearch, Akash Shrestha

Culminating Experience Projects

Search engines have changed the way we use the internet. They can search or filter out relevant and valuable content of interest to the users. But many of the applications we use today lack search or are just poor. So how can we leverage the same power of search engines in our applications? This project aims to look at “Full-Text Search” which allows us to do a text-based search in text-intensive data. The search will be performed by matching any, or all words of the query exactly or with some relevancy against the indexes created by the searching tool. The …

Effect Of X-Ray Illumination On Magnetic Domain Memory In [Co/Pd]/Irmn Multilayers, Colby Singint Walker

Theses and Dissertations

This thesis focuses on investigating the possible x-ray illumination effects on the magnetic domain memory (MDM) in magnetic [Co/Pd]IrMn multilayers. In this material, MDM is induced via exchange couplings between the ferromagnetic Co/Pd layer and the antiferromagnetic IrMn layer. To carry out this investigation, we have used magneto-transport and x-ray resonant magnetic scattering. The use of magneto-transport in-situ at synchrotron x-ray scattering facility has allowed us to follow the gradual effect of x-ray illumination on the amount of exchange bias, initially present after field cooling the material. With our in-situ measurements we have been able to see that x-ray illumination …

Muse: A Genetic Algorithm For Musical Chord Progression Generation, Griffin Going

Culminating Experience Projects

Foundational to our understanding and enjoyment of music is the intersection of harmony and movement. This intersection manifests as chord progressions which themselves underscore the rhythm and melody of a piece. In musical compositions, these progressions often follow a set of rules and patterns which are themselves frequently broken for the sake of novelty. In this work, we developed a genetic algorithm which learns these rules and patterns (and how to break them) from a dataset of 890 songs from various periods of the Billboard Top 100 rankings. The algorithm learned to generate increasingly valid, yet interesting chord progressions via …

Devops: Course Development, James Lee Vanderzouwen

Culminating Experience Projects

DevOps has become somewhat of a buzzword amongst software engineers in the industry. Often developers do not have a dedicated DevOps engineer let alone a DevOps team. Developers benefit when they know what happens between ‘works on my machine’ and production. Making sure those steps make sense and are safe benefits the operations team. From compliance to code review to regression testing, understanding the full SDLC, employing DevOps concepts, and minimizing overhead from dependencies is quickly becoming a pre-requisite for the modern software engineer. This project attempts to bridge the gap between buzzword and best practice by developing a college-level …