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Deep Selenium Donors In Zngep2 Crystals: An Electron Paramagnetic Resonance Study Of A Nonlinear Optical Material, Timothy D. Gustafson, Larry E. Halliburton, Nancy C. Giles, Peter G. Schunemann, Kevin T. Zawilski, J. Jesenovec, Kent L. Averett, Jeremy Slagle Apr 2024

Deep Selenium Donors In Zngep2 Crystals: An Electron Paramagnetic Resonance Study Of A Nonlinear Optical Material, Timothy D. Gustafson, Larry E. Halliburton, Nancy C. Giles, Peter G. Schunemann, Kevin T. Zawilski, J. Jesenovec, Kent L. Averett, Jeremy Slagle

Faculty Publications

Zinc germanium diphosphide (ZnGeP2) is a ternary semiconductor best known for its nonlinear optical properties. A primary application is optical parametric oscillators operating in the mid-infrared region. Controlled donor doping provides a method to minimize the acceptor-related absorption bands that limit the output power of these devices. In the present study, a ZnGeP2 crystal is doped with selenium during growth. Selenium substitutes for phosphorus and serves as a deep donor. Significant concentrations of native defects (zinc vacancies, germanium-on-zinc antisites, and phosphorous vacancies) are also present in the crystal. Electron paramagnetic resonance (EPR) is used to establish the …


Processing And Testing Commodity And Engineering Cfrtp Composites, Delia M. Derner, Kristine Osorio Apr 2024

Processing And Testing Commodity And Engineering Cfrtp Composites, Delia M. Derner, Kristine Osorio

Research & Creative Achievement Day

Commodity thermoplastic polymers provide good load transfer to and protection of the reinforcing fibers.  However, their mechanical properties are inferior to high-performance thermoplastic polymer composites.  Findings of preliminary research conducted at WSU showed that continuous fiber reinforced (CFR) commodity polymers such as PETG and PP have better Izod impact resistance than their high-performance CFR counterparts.  Further investigation of these findings is conducted in this research project.  Quasi-isotropic laminates of GF/PETG and GF/PET-am are fabricated and tested in drop weight impact.  The results will be compared with previously determined results of high-performance CF/PPS, CF/PA12 and GF/PPS.  The samples are fabricated using …


Low-Velocity Drop Weight Impact And Compression After Impact Properties Of Symmetric Quasi-Isotropic Cfrtp Composites, Youyi Zhou, Kyungbin Min Apr 2024

Low-Velocity Drop Weight Impact And Compression After Impact Properties Of Symmetric Quasi-Isotropic Cfrtp Composites, Youyi Zhou, Kyungbin Min

Research & Creative Achievement Day

Low-velocity impact properties and residual compression strength after impact performance are used to evaluate composite materials for many applications. In this research, low-velocity drop-weight impact and compression after impact performance of four continuous fiber reinforcement thermoplastic (CFRTP) composites are investigated. Quasi-isotropic samples of GF/PP, CF-PA12, CF-PA6, GF-PA6 were fabricated and tested according to ASTM standards. Three energy levels of 10, 15, and 20 J/mm, were employed in this research. Results indicate that GF/PP exhibits the highest damage resistance and rebound-ability, evidenced by its minimal indentation and damage area, the highest significant damage threshold force, and the highest ratio of impact …


Ergo Carbon Workspace, Ethan C. Atkinson, Joshua N. Hanner, Rachel A. Henderson, Anders Nielsen, Mohamed A. Salat Apr 2024

Ergo Carbon Workspace, Ethan C. Atkinson, Joshua N. Hanner, Rachel A. Henderson, Anders Nielsen, Mohamed A. Salat

Research & Creative Achievement Day

The goal of the Ergo Carbon Workspace is to create a monitor stand that is both lightweight and easily transportable, catering to the needs of modern workspaces. Constructed from carbon fiber, epoxy resin, and a honeycomb core, this design emphasizes portability without sacrificing durability. Incorporating aerospace-grade honeycomb core as well as braided carbon fiber epoxy struts bolsters structural integrity while maintaining a lightweight part. The Ergo Carbon Workspace design facilitates effortless assembly and disassembly, simplifying transportation and packaging. Through the utilization of composite materials, the stand achieves an optimal balance of strength and portability. Ergo Carbon Workspace will also incorporate …


Application Of The Immobilized Low-Activity Waste Glass Corrosion Model To The Static Dissolution Of 24 Statistically-Designed Alkali-Borosilicate Waste Glasses, Sebastien N. Kerisit, James J. Neeway, Charmayne E. Lonergan, Benjamin Parruzot, Jarrod V. Crum, Richard C. Daniel, Gary L. Smith, R. Matthew Asmussen Apr 2024

Application Of The Immobilized Low-Activity Waste Glass Corrosion Model To The Static Dissolution Of 24 Statistically-Designed Alkali-Borosilicate Waste Glasses, Sebastien N. Kerisit, James J. Neeway, Charmayne E. Lonergan, Benjamin Parruzot, Jarrod V. Crum, Richard C. Daniel, Gary L. Smith, R. Matthew Asmussen

Materials Science and Engineering Faculty Research & Creative Works

Glass corrosion models that capture the complex mechanisms of the glass-water reaction enable the prediction of nuclear waste glass durability in disposal scenarios. Parameterization of such models is challenging because of the need to capture changes in corrosion behavior with time, reaction conditions, and glass composition. Here, we describe and employ the ILAW (immobilized low-activity waste) glass corrosion model (IGCM) in geochemical simulations of static dissolution tests, at two temperatures (40 °C and 90 °C), for a matrix of 24 enhanced low-activity waste (eLAW) glasses statistically designed to cover a processable composition space defined by 8 major glass components (Al …


Decoding Crystallization Behavior Of Aluminoborosilicate Glasses: From Structural Descriptors To Quantitative Structure – Property Relationship (Qspr) Based Predictive Models, Yingcheng Zhang, Marco Bertani, Alfonso Pedone, Randall E. Youngman, Gregory Tricot, Aditya Kumar, Ashutosh Goel Apr 2024

Decoding Crystallization Behavior Of Aluminoborosilicate Glasses: From Structural Descriptors To Quantitative Structure – Property Relationship (Qspr) Based Predictive Models, Yingcheng Zhang, Marco Bertani, Alfonso Pedone, Randall E. Youngman, Gregory Tricot, Aditya Kumar, Ashutosh Goel

Materials Science and Engineering Faculty Research & Creative Works

Successful decoding of structural descriptors controlling the crystallization in multicomponent functional glasses can pave the way for the transition from the trial-and-error approach and empirical modeling for glass/glass-ceramic composition design toward more rational and scientifically rigorous Quantitative Structure-Property Relationship (QSPR) based models. However, due to the compositional and structural complexity of multicomponent glasses and the longer time and length scales associated with nucleation, the development and validation of QSPR models are still in it's infancy. The work presented in the article is an attempt to leap forward in this pursuit by combining the strengths of experimental and computational materials science …


Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao Apr 2024

Research On 3d Printing Resin Exposure Properties And Its Application On Centrifugal Microfluidic Platform Based On Fluorescence Detection, Zheng Qiao

LSU Doctoral Dissertations

This dissertation encapsulates significant advancements in the field of SLA 3D printing and centrifugal microfluidics. Central to the research is the development of a novel mathematical model for predicting trapped resin thickness in SLA 3D printing, a groundbreaking contribution that addresses a critical aspect of printing intricate structures. This model, the first to establish a mathematical relationship for resin thickness, is rooted in a comprehensive study of the resin curing process. The research leverages the concept of 'critical dosage' for resin curing, leading to a more refined and theoretically grounded approach for calculating curing thickness. Experimentation further validates the model, …


Synergy Between Ca2+ And High Ionic Field-Strength Cations During The Corrosion Of Alkali Aluminoborosilicate Glasses In Hyper-Alkaline Media, Qianhui Qin, Nicholas Stone-Weiss, Nian Shi, Pinaki Mukherjee, Jinjun Ren, Ashutosh Goel Apr 2024

Synergy Between Ca2+ And High Ionic Field-Strength Cations During The Corrosion Of Alkali Aluminoborosilicate Glasses In Hyper-Alkaline Media, Qianhui Qin, Nicholas Stone-Weiss, Nian Shi, Pinaki Mukherjee, Jinjun Ren, Ashutosh Goel

Michigan Tech Publications, Part 2

One major factor impeding the design of nuclear waste glasses with enhanced waste loadings is our insufficient understanding of their composition–structure–durability relationships, specifically in the environments the waste form is expected to encounter in a geological repository. In particular, the high field-strength cations (HFSCs) are an integral component of most waste streams. However, their impact on the long-term performance of the glassy waste form remains mostly undeciphered. In this context, the present study aims to understand the impact of some HFSCs (i.e., Nb5+, Zr4+, Ti4+, and La3+) on the dissolution behavior of alkali/alkaline-earth aluminoborosilicate-based model nuclear waste glasses in hyper-alkaline …


Globular Protein For Surface Modification Of Cellulosecontaining Materials, Nodira Saydaliyeva Apr 2024

Globular Protein For Surface Modification Of Cellulosecontaining Materials, Nodira Saydaliyeva

Technical science and innovation

The purpose of this work is the chemical modification of cotton fabrics with natural globular protein. Modification was carried out in the process of finishing cotton fabrics, after decoction and bleaching in a continuous mode. The effect of modification on the strength, protein content and functional groups of cotton fabric has been studied. According to the results obtained using the AUTOGRAPH AGS-N machine, it was found that the modification of cotton fabrics with a solution of globular protein increases the strength of the treated fabrics, depending on the concentration of the modifier and the temperature regime. Treatment with a highly …


A Guide To Fifty Years Of Research At Montana Tech: Part 3-Decontamination Of Ratioactively Contaminated Steel By Melt Refining/Slagging Processing, Larry G. Twidwell, Samuel A. Worcester Apr 2024

A Guide To Fifty Years Of Research At Montana Tech: Part 3-Decontamination Of Ratioactively Contaminated Steel By Melt Refining/Slagging Processing, Larry G. Twidwell, Samuel A. Worcester

Metallurgy

This presentation includes a discussion of the research conducted at Montana Tech in the Department of Metallurgical and Materials Engineering. The discussion is focused on Decontamination of Radioactively Contaminated Steel by Melt Refining/Slagging. This presentation is based on the research of Master of Science graduate students, industrial and academic colleagues, at the Montana College of Mineral Science and Technology (which morphed to Montana Tech [1977], then to Montana Tech of The University of Montana [2000], then to Montana Technological University [2019]). The referenced work of each of the graduate students in this presentation is gratefully acknowledged. The following summary presentation …


Starfish: A Compact, Biomimetic, And Adaptive Shape Memory Alloy Orbital Debris Remover, Katelyn Branaman Apr 2024

Starfish: A Compact, Biomimetic, And Adaptive Shape Memory Alloy Orbital Debris Remover, Katelyn Branaman

Doctoral Dissertations and Master's Theses

This thesis aims to turn the tides on the orbital debris issue through the fabrication and demonstration of a compact, biomimetic, and adaptive shape memory alloy actuated orbital debris remover. The design, referred to as Starfish, is discussed in detail along with its fabrication process and object capture ability. A hard skeleton crafted from PETG was combined with shape memory alloy wires and extension springs to create a biomimetic structure that operates similar to the human hand, capable of gripping a wide range of objects. Relevant simulations were performed and discussed, the iterative fabrication process used to create each component …


Safety Evaluation Of Hawaii Dot Modified Type A-1 Flared Buried In Backslope Guardrail End Terminal, Sina Changizian Apr 2024

Safety Evaluation Of Hawaii Dot Modified Type A-1 Flared Buried In Backslope Guardrail End Terminal, Sina Changizian

Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research

The Hawaii Department of Transportation (HDOT) desired to evaluate the crashworthiness of a guardrail end terminal design in which the upstream guardrail anchorage was connected to a block partially buried in a cut slope, known as a “Buried in Backslope” or BIB design. The HDOT BIB system used an upper W-beam with 8-in. deep blockouts attached to W6x9 steel posts and a lower W-beam rubrail located 3 in. below the upper rail. The system used two horizontal flares: 7.4:1 near the upstream anchor block and a 13:1 flare through the ditch.

Critical impact points (CIPs) were identified and recommended for …


Quasi-Static And Impact Load Response Of Bfrp-Reinforced Concrete Beams And Post-Terrorist-Attack Sub-Assemblages, José Luis Carrasquillo Apr 2024

Quasi-Static And Impact Load Response Of Bfrp-Reinforced Concrete Beams And Post-Terrorist-Attack Sub-Assemblages, José Luis Carrasquillo

Civil & Environmental Engineering Theses & Dissertations

This dissertation presents the outcome of a theoretical and experimental study of Basalt Fiber Reinforced Polymer (BFRP) reinforced concrete beams and post-terrorist-attack subassemblages subjected to either quasi-static or impact load. Both BFRP reinforcement as well as BFRP fabric are used in this investigation. The sub-assemblage consists of an otherwise two-span beam converted to a fixed-end single-span one owing to the loss of a middle column blasted off during the terrorist attack. The simply supported beams are subjected to a midspan quasistatic or an impact load. However, each sub-assemblage is subjected to a quasi-static load up to collapse to simulate the …


Thermo-Elasto-Plastic Stability Of Biaxially Loaded Hollow Rectangular Section Steel Beam-Columns With Applied Torsion, George Adomako Kumi Apr 2024

Thermo-Elasto-Plastic Stability Of Biaxially Loaded Hollow Rectangular Section Steel Beam-Columns With Applied Torsion, George Adomako Kumi

Civil & Environmental Engineering Theses & Dissertations

Presented herein is an experimental and theoretical study of biaxially loaded hollow rectangular section steel beam-columns with applied torsion at elevated temperatures. The theoretical analysis is based on a system of simultaneous materially nonlinear differential equations of equilibrium for which an iterative semi-analytic solution approach is formulated. Although the primary goal of this research is to study the influence of elevated temperatures on the steel member with the complex loading, rigorous analysis is also conducted of the member at ambient temperature for comparison. The experimental part of the study involves conducting tests on the members at both ambient and high …


Longitudinal Solid Polarized Target For Clas12 And Study Of Spin Structure Of Nucleons, Pushpa Pandey Apr 2024

Longitudinal Solid Polarized Target For Clas12 And Study Of Spin Structure Of Nucleons, Pushpa Pandey

Physics Theses & Dissertations

A suite of experiments measuring target-spin observables in electron-nucleon scattering (dubbed Run Group C) was conducted at Jefferson Lab’s Hall B in Newport News, VA with a new polarized nuclear target known as ‘APOLLO’ (Ammonia Polarized Longitudinally). This innovative target is engineered to seamlessly integrate with the advanced 12 GeV CEBAF (Continuous Electron Beam Accelerator Facility) accelerator and the Hall B CLAS12 (12 GeV CEBAF Large Acceptance Spectrometer) detector array. The ‘APOLLO’ target harnesses the power of Dynamic Nuclear Polarization (DNP) to achieve longitudinal polarization of solid ammonia, thereby creating a net polarization in both protons (NH3) and …


Advancements In Characterization Of Ancient Potteries From Southeast Asia: A Review Of Analytical Techniques, Chitnarong Sirisathitkul Mar 2024

Advancements In Characterization Of Ancient Potteries From Southeast Asia: A Review Of Analytical Techniques, Chitnarong Sirisathitkul

Makara Journal of Science

Ancient potteries offer valuable information regarding technological advancements, life dynamics, cultural diversity, and trade routes in the past. Earthenware, stoneware, and porcelain from Southeast Asia have been characterized using several analytical techniques, as reviewed in this article. Fluorescent and diffracted X-rays give rise to elemental and phase compositions, respectively. Examination of molecular bonds requires vibrational spectroscopy, which is useful for the identification of organic materials in ancient potteries. With the advent of portable X-ray fluorescence and Raman spectrometry, on-site analysis of archeological ceramics is now possible. For in-depth analysis, synchrotron light sources can provide new insights into artifacts through X-ray …


A Comparison Of Beamforming Characteristics In Isotropic And Composite Plate Structures For Use In Structural Health Monitoring, Sarah Ketchersid Mar 2024

A Comparison Of Beamforming Characteristics In Isotropic And Composite Plate Structures For Use In Structural Health Monitoring, Sarah Ketchersid

Doctoral Dissertations and Master's Theses

Structural health monitoring in plate-like simple structures using phased array beamsteering of guided Lamb waves is useful in damage detection and evaluation efforts. Lamb waves can be effectively used for beamsteering using a linear array. The experimentation primarily focuses on beamsteering in the aluminum panel, which involves developing a simulation based on extracted data to visualize the dispersion of waves across the panel. By evaluating parameters such as slowness, velocity, and amplitude direction and variation for a specific metallic plate, the wavefront generated by a single wave source can be represented as a function of propagation angle and distance from …


Effect Of Fabrication Parameters On The Ferroelectricity Of Hafnium Zirconium Oxide Films: A Statistical Study, Guillermo A. Salcedo, Ahmad E. Islam, Elizabeth Reichley, Michael Dietz, Christine M. Schubert Kabban, Kevin D. Leedy, Tyson C. Back, Weison Wang, Andrew Green, Timothy S. Wolfe, James M. Sattler Mar 2024

Effect Of Fabrication Parameters On The Ferroelectricity Of Hafnium Zirconium Oxide Films: A Statistical Study, Guillermo A. Salcedo, Ahmad E. Islam, Elizabeth Reichley, Michael Dietz, Christine M. Schubert Kabban, Kevin D. Leedy, Tyson C. Back, Weison Wang, Andrew Green, Timothy S. Wolfe, James M. Sattler

Faculty Publications

Ferroelectricity in hafnium zirconium oxide (Hf1−xZrxO2) and the factors that impact it have been a popular research topic since its discovery in 2011. Although the general trends are known, the interactions between fabrication parameters and their effect on the ferroelectricity of Hf1−xZrxO2 require further investigation. In this paper, we present a statistical study and a model that relates Zr concentration (x), film thickness (tf), and annealing temperature (Ta) with the remanent polarization (Pr) in tungsten (W)-capped Hf1−xZrxO2. …


Micropatterning And Functionalization Of Single Layer Graphene: Tuning Its Electron Transport Properties, Miao-Miao Cui, Lian-Huan Han, Lan-Ping Zeng, Jia-Yao Guo, Wei-Ying Song, Chuan Liu, Yuan-Fei Wu, Shi-Yi Luo, Yun-Hua Liu, Dong-Ping Zhan Mar 2024

Micropatterning And Functionalization Of Single Layer Graphene: Tuning Its Electron Transport Properties, Miao-Miao Cui, Lian-Huan Han, Lan-Ping Zeng, Jia-Yao Guo, Wei-Ying Song, Chuan Liu, Yuan-Fei Wu, Shi-Yi Luo, Yun-Hua Liu, Dong-Ping Zhan

Journal of Electrochemistry

As a promising 2D material, graphene exhibits excellent physical properties including single-atom-scale thickness and remarkably high charge carrier mobility. However, its semi-metallic nature with a zero bandgap poses challenges for its application in high-performance field-effect transistors (FETs). In order to overcome these limitations, various approaches have been explored to modulate graphene's bandgap, including nanoscale confinement, external field induction, doping, and chemical micropatterning. Nevertheless, the stability and controllability still need to be improved. In this study, we propose a feasible method that combines electrochemical bromination and photolithography to precisely tune the electron transport properties of single layer graphene (SLG). Through this …


Recent Advances In Solar Photo(Electro)Catalytic Nitrogen Fixation, Jun-Bo Ma, Sheng Lin, Zhiqun Lin, Lan Sun, Chang-Jian Lin Mar 2024

Recent Advances In Solar Photo(Electro)Catalytic Nitrogen Fixation, Jun-Bo Ma, Sheng Lin, Zhiqun Lin, Lan Sun, Chang-Jian Lin

Journal of Electrochemistry

Ammonia (NH3) is an essential chemical in modern society. It is currently produced in industry by the Haber-Bosch process using H2 and N2 as reactants in the presence of iron-based catalysts at high-temperature (400–600 oC) and extremely highpressure (20–40 MPa) conditions. However, its efficiency is limited to 10% to 15%. At the same time, a large amount of energy is consumed, and CO2 emission is inevitably. The development of a sustainable, clean, and environmentally friendly energy system represents a key strategy to address energy crisis and environmental pollution, ultimately aiming to achieve carbon neutrality. …


Effects Of Polymer-Nanoparticle Interactions On The Dynamics Of Attractive Polyhedral Oligomeric Silsesquioxane Nanocomposites, Walter W. Young Mar 2024

Effects Of Polymer-Nanoparticle Interactions On The Dynamics Of Attractive Polyhedral Oligomeric Silsesquioxane Nanocomposites, Walter W. Young

Doctoral Dissertations

Polyhedral oligomeric silsesquioxane (POSS) had long been recognized as a critical building block for inorganic-organic hybrid materials with unique and desirable properties and performance. Through synthesis and characterization of polymer/POSS nanocomposites, direct insights into the significant effects of the polymer/POSS interactions on the resulting material properties are obtained. Random copolymers of a hydrogen-bond accepting monomer and a non-interacting monomer are synthesized and loaded with a model amine-functionalized hydrogen bond donating POSS molecule via solution casting, to create a material with well-controlled dynamical heterogeneity. The increase in the glass transition temperature (Tg) of these materials is found to strongly depend on …


La1-Xsrxcoo3 Perovskite Nanomaterial: Synthesis, Characterization, And Its Biomedical Application, Adhira Tippur, Anyet Shohag, Luke Franco, Ahmed Touhami, Swati Mohan, Mohammed Uddin Mar 2024

La1-Xsrxcoo3 Perovskite Nanomaterial: Synthesis, Characterization, And Its Biomedical Application, Adhira Tippur, Anyet Shohag, Luke Franco, Ahmed Touhami, Swati Mohan, Mohammed Uddin

Research Symposium

Early cancer detection is paramount for effective treatment and potential cures. This research explores the application of perovskite materials, specifically Sr2+-doped Lanthanum Cobaltite (La1-xSrxCoO3) nanomaterials, in cancer detection, with a focus on rats as an experimental model. The ferroelectric nature of these materials, synthesized through a combination of sol-gel and molten-salt processes, was examined at varying Sr2+ doping levels (1-20 wt%). Rigorous characterization, employing X-ray diffraction and scanning electron microscopy, confirmed the uniform morphology of nano cubes, laying the foundation for subsequent investigations. The magnetic properties of the perovskite nanoparticles were probed, suggesting their potential as a diagnostic tool for …


High Energy Approximation For Monte Carlo Event Generator, A. N. Ismailova, Yu. L. Parfenova, P. G. Sharov, D. M. Janseitov Mar 2024

High Energy Approximation For Monte Carlo Event Generator, A. N. Ismailova, Yu. L. Parfenova, P. G. Sharov, D. M. Janseitov

Eurasian Journal of Physics and Functional Materials

Analysis of the nuclear physics experiment often requires Monte Carlo simulation of the detector setup. Such kind of simulations often requires a quite advanced model of nuclear interaction. In this work we describe application of Monte Carlo simulation in the nuclear physic experiment, and discuss on example of elastic scattering how to apply well known High Energy Approximation (or Glauber model) to Monte Carlo simulation of the experimental setup.


Determination Of Phase Boundaries And Diffusion Coefficients Of Copper In Spinel Cucr2se4 And Delafossite Cucrse2 By Galvanostatic Intermittent Titration Technique (Gitt), A. O. Onishenko, E. A. Suslov, M. S. Postnikov, A. S. Shkvarin, A. N. Titov, A. I. Merentsov Mar 2024

Determination Of Phase Boundaries And Diffusion Coefficients Of Copper In Spinel Cucr2se4 And Delafossite Cucrse2 By Galvanostatic Intermittent Titration Technique (Gitt), A. O. Onishenko, E. A. Suslov, M. S. Postnikov, A. S. Shkvarin, A. N. Titov, A. I. Merentsov

Eurasian Journal of Physics and Functional Materials

Cux CrSe2 materials can exist in the form of delafossite with a layered structure and exhibit multiferroic properties, or in the form of spinel and exhibit ferromagnetic properties, depending on the copper concentration. The stability of both forms of Cux CrSe2 has been studied with regards to defectivity in the copper sublattice. The boundaries of the Cux CrSe2 homogeneity regions for the delafossite- like structure and for the cubic spinel CuCr2Se4 were determined by coulometric titration at room temperature. Analysis of the time dependence of cell polarization allowed us to estimate the diffusion coefficients in these materials


Concentration Polarization And Ionic Conductivity Of Nanocomposite Thermoelectric Materials K0.01cu1.94s, K0.02cu1.94s, K0.03cu1.94s, M. M. Kubenova, M. Kh. Balapanov, K. A. Kuterbekov, B. Akhmetgaliev, R. Kh. Ishembetov, R. F. Almukhametov, M. Zeleev, A. M. Kabyshev, K. Zh. Bekmyrza, R. Alina, R. E. Kondakirov, M. K. Kenzhebek Mar 2024

Concentration Polarization And Ionic Conductivity Of Nanocomposite Thermoelectric Materials K0.01cu1.94s, K0.02cu1.94s, K0.03cu1.94s, M. M. Kubenova, M. Kh. Balapanov, K. A. Kuterbekov, B. Akhmetgaliev, R. Kh. Ishembetov, R. F. Almukhametov, M. Zeleev, A. M. Kabyshev, K. Zh. Bekmyrza, R. Alina, R. E. Kondakirov, M. K. Kenzhebek

Eurasian Journal of Physics and Functional Materials

The paper presents experimental results of concentration polarization and ionic conductivity of nanocom- posite thermoelectric materials K0.01Cu1.94S , K0.02Cu1.94S , K0.03Cu1.94S . According to X-ray phase analysis, the synthesized samples are monoclinic jarleite Cu1.93÷1.97S with an admixture of oxygen ox- ide Cu2S and monoclinic chalcocyte. High values of total ionic conductivity are observed, ranging from 0.86 to 1.5 Cm/cm. The lowest ionic conductivity (0.86 Cm/cm at 355 ◦ C) is observed for alloy K0.02Cu1.94S . In addition, it was found that with an increase in the concentration of potassium in the studied materials, ionic conductivity tends to decrease, activation energy …


Study Of The Effect Of Combined Reinforcement And Modification Of Epoxy Resin With Rubbers On The Impact Strength Of Carbon Fiber-Reinforced Plastic, M. N. Meiirbekov, M. B. Ismailov, A. K. Kenzhegulov, L. M. Mustafa, I. B. Tashmukhanbetova Mar 2024

Study Of The Effect Of Combined Reinforcement And Modification Of Epoxy Resin With Rubbers On The Impact Strength Of Carbon Fiber-Reinforced Plastic, M. N. Meiirbekov, M. B. Ismailov, A. K. Kenzhegulov, L. M. Mustafa, I. B. Tashmukhanbetova

Eurasian Journal of Physics and Functional Materials

The effect of modified epoxy resin with polyurethane, silicone, and butadiene rubber and combined reinforcement with fiberglass and Kevlar on the strength properties of carbon fiber-reinforced plastic was studied. It was found that when rubber is introduced into the composition of the epoxy resin, polyurethane, and combined reinforcement according to the carbon fiber/Kevlar scheme in a ratio of 10:10 leads to an increase in impact strength by 42% to 273 kJ/m2 and compressive strength increases by 35% to 575 MPa


Luminescence And Creation Of Electron-Hole Trapping Centers In Alkali Metal Sulfates Activated By Pb2+ Impurity, T. N. Nurakhmetov, R. K. Shamieva, Zh. M. Salikhodzha, N. I. Temirkulova, T. T. Alibay, B. M. Sadykova, B. N. Yussupbekova, A. A. Kabdulkak Mar 2024

Luminescence And Creation Of Electron-Hole Trapping Centers In Alkali Metal Sulfates Activated By Pb2+ Impurity, T. N. Nurakhmetov, R. K. Shamieva, Zh. M. Salikhodzha, N. I. Temirkulova, T. T. Alibay, B. M. Sadykova, B. N. Yussupbekova, A. A. Kabdulkak

Eurasian Journal of Physics and Functional Materials

The nature of the impurity emission and the process of creating intrinsic and impurity electron-hole trapping centers were studied by spectroscopic and thermal activation methods in Na2SO4 - Pb and K2SO4 - Pb phosphors. The combined radiative electronic state is formed from intrinsic SO3− 4 - SO− 4 and impurity Pb+ - SO− 4 electron-hole trapping centers in UV-irradiated phosphors with a photon en- ergy of 6.2 eV at 80 K. Emissions of 3.2 eV and 3.6 eV resulting from irradiation with photons with an energy of 6.2 eV are associated with intracenter transitions of 3p1 - 1s0 in Pb2+ …


On The Use Of Machine Learning And Data-Transformation Methods To Predict Hydration Kinetics And Strength Of Alkali-Activated Mine Tailings-Based Binders, Sahil Surehali, Taihao Han, Jie Huang, Aditya Kumar, Narayanan Neithalath Mar 2024

On The Use Of Machine Learning And Data-Transformation Methods To Predict Hydration Kinetics And Strength Of Alkali-Activated Mine Tailings-Based Binders, Sahil Surehali, Taihao Han, Jie Huang, Aditya Kumar, Narayanan Neithalath

Electrical and Computer Engineering Faculty Research & Creative Works

The escalating production of mine tailings (MT), a byproduct of the mining industry, constitutes significant environmental and health hazards, thereby requiring a cost-effective and sustainable solution for its disposal or reuse. This study proposes the use of MT as the primary ingredient (≥70%mass) in binders for construction applications, thereby ensuring their efficient upcycling as well as drastic reduction of environmental impacts associated with the use of ordinary Portland cement (OPC). The early-age hydration kinetics and compressive strength of MT-based binders are evaluated with an emphasis on elucidating the influence of alkali activation parameters and the amount of slag or cement …


Effect Of The Filler Morphology On The Crystallization Behavior And Dielectric Properties Of The Polyvinylidene Fluoride-Based Composite, Suzana Filipović, Nina Obradović, Cole Corlett, William G. Fahrenholtz, Martin Rosenschon, Ekkehard Füglein, Radovan Dojčilović, Dragana Tošić, Jovana Petrović, Antonije Đorđević, Branislav Vlahović, Vladimir B. Pavlović Mar 2024

Effect Of The Filler Morphology On The Crystallization Behavior And Dielectric Properties Of The Polyvinylidene Fluoride-Based Composite, Suzana Filipović, Nina Obradović, Cole Corlett, William G. Fahrenholtz, Martin Rosenschon, Ekkehard Füglein, Radovan Dojčilović, Dragana Tošić, Jovana Petrović, Antonije Đorđević, Branislav Vlahović, Vladimir B. Pavlović

Materials Science and Engineering Faculty Research & Creative Works

Ceramic/polymer composites can be chemically stable, mechanically strong, and flexible, which make them candidates for electric devices, such as pressure or temperature sensors, energy storage or harvesting devices, actuators, and so forth. Depending on the application, various electrical properties are of importance. Polymers usually have low dielectric permittivity, but increased dielectric permittivity can be achieved by the addition of the ceramic fillers with high dielectric constant. With the aim to enhance dielectric properties of the composite without loss of flexibility, 5 wt.% of BaTiO3-Fe2O3 powder was added into a polyvinylidene fluoride matrix. The powder was …


A Phenomenological Thermodynamic Energy Density Function For Ferroelectric Wurtzite Al1−Xscxn Single Crystals, Yijia Gu, Andrew C. Meng, Aiden Ross, Long Qing Chen Mar 2024

A Phenomenological Thermodynamic Energy Density Function For Ferroelectric Wurtzite Al1−Xscxn Single Crystals, Yijia Gu, Andrew C. Meng, Aiden Ross, Long Qing Chen

Materials Science and Engineering Faculty Research & Creative Works

A Landau-Devonshire thermodynamic energy density function for ferroelectric wurtzite aluminum scandium nitride (Al1−xScxN) solid solution is developed. It is parametrized using available experimental and theoretical data, enabling the accurate reproduction of composition-dependent ferroelectric properties, such as spontaneous polarization, dielectric permittivity, and piezoelectric constants, for both bulk and thin films. The maximum concentration of Sc for the wurtzite structure to remain ferroelectric is found to be 61 at. %. A detailed analysis of Al1−xScxN thin films reveals that the ferroelectric phase transition and properties are insensitive to substrate strain. This study lays the foundation for quantitative modeling of novel ferroelectric wurtzite …