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Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project examines inert fuels containing ZrO₂ and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO₂. Reactor physics calculations are used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10% of ²³⁹Pu. Ceramics are synthesized and characterized based on the reactor physics results. The solubility of the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, are investigated in a manner to provide thermodynamic data necessary for …

Design And Evaluation Of Processes For Fuel Fabrication, Georg F. Mauer

Fuels Campaign (TRP)

The goal of this research project was to provide technical support to process designers working on the development of the fuel cycles for transmutation applications. Detailed process models were developed to better define the impact of fuel choice on the transmuter fuel cycle, including relative process losses, waste generation, and plant capital cost. These process models provide insight regarding required plant size and number of plants needed to mesh with the fuel recycling line. They also determine requirements for automation.

Manufacturing models for large-scale production in a hot cell environment were also developed. Combined, these two models allow the assessment …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 2nd Quarter Report, 2005, Clemens Heske

Fuels Campaign (TRP)

The goal of our project is to investigate interface corrosion processes in TRISO nuclear fuel particles. For this purpose, we are undertaking a detailed study of the interface formation between potential candidates for metallic fission products (Pd, Ag, and Cs), likely to diffuse from the kernel of the TRISO particles, with the TRISO coating layers. As a starting point, we are investigating the Pd/SiC interface and will extend our studies to Ag/SiC during our current summer research campaign. The experimental approach comprises the preparation of metal/SiC interfaces in-situ in our ultra-high vacuum system by electron-beam deposition. In order to understand …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 1st Quarter Report, 2005, Clemens Heske

Fuels Campaign (TRP)

In this project we utilize a combination of state-of-the-art soft X-ray spectroscopies to understand the chemical bonding between metal fission products (Pd and Ag) with coating layers in TRISO fuel particles (SiC and pyrocarbon). We are primarily focusing on an analysis of intermediate chemical phases at the interface, the intermixing/diffusion behavior, and the electronic interface structure as a function of material choice (metal and coating materials), temperature, and external stress. In the current first project year, we are beginning these investigations with the Pd/SiC interface, as discussed in the previous two quarterly reports. Our first experiments (both using our lab …

Interaction Between Metal Fission Products And Triso Coating Materials, Clemens Heske

Fuels Campaign (TRP)

The goal of this project is to elucidate the chemical bonding and interface formation of metal fission products with the coating materials used in state-of-the-art TRISO fuel particles. Particular emphasis is placed on an analysis of intermediate chemical phases at the interface, the intermixing/diffusion behavior, and the electronic interface structure as a function of material choice (metal and coating materials), temperature, and external stress. Furthermore, the chemical state of some of the metal fission products will be assessed.

This project studies the interface formation of Pd, Ag, and Cs with SiC and pyrolytic carbon. Using the TRISO coating materials (and …

Design Concepts And Process Analysis For Transmuter Fuel Manufacturing, Georg F. Mauer

Fuels Campaign (TRP)

The safe and effective manufacturing of actinide-bearing fuels for any transmutation strategy requires that the entire manufacturing process be contained within a shielded hot cell environment. To ensure that the fabrication process is feasible, the entire process must be designed for remote operation. The equipment must be reliable enough to perform over several decades, and also easy to maintain or repair remotely. The facility must also be designed to facilitate its own decontamination and decommissioning. In addition to these design factors, the potential viability of any fuel fabrication process will also be impacted by a number of variables, such as …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Quarterly Report, October 2004 To December 2004, Earl Wolfram, Thomas Hartmann, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert matrix fuels containing ZrO₂ and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO₂. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10% of ²³⁹Pu. Ceramics will be synthesized and characterized based on the reactor physics results. The solubility the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, will be investigated in a manner to provide …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Neutronic Evaluation Of Zro2-Mgo Inert Fuels, E. Fridman, A. Galperin, E. Shwageraus

Fuels Campaign (TRP)

Second task of the BGU part of “Dissolution, Reactor, and Environmental Behavior of ZrO₂-MgO Inert Fuel Matrix” project aims at evaluation of the fertile free fuel matrix composition effect on the fuel reactivity and corresponding reactivity limited burnup. Fertile free fuel with different MgO to ZrO₂ ratio in the matrix will require different PuO₂ loading in order to assure certain fuel cycle length. This is due to the fact that absorption cross section of Zr is slightly higher than that of Mg, although absorption in both of these elements is small compared to Pu. Therefore, the …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Quarterly Report, July 2004 To September 2004, Kenneth Czerwinski, Earl Wolfram

Fuels Campaign (TRP)

This project will examine inert fuels containing ZrO₂ and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO₂. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10 % of ²³⁹Pu. Ceramics will be synthesized and characterized based on the reactor physics results. The solubility the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, will be investigated in a manner to provide …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix: Neutronic Evaluation Of Zro2-Mgo Inert Fuels, E. Fridman, A. Galperin, E. Shwageraus

Fuels Campaign (TRP)

This progress report presents results of analysis performed within the framework of “Dissolution, Reactor, and Environmental Behavior of ZrO₂-MgO Inert Fuel Matrix” project managed by University of Nevada at Las Vegas, Harry Reid Center for Environmental Studies.

The BGU working program includes the following four tasks:

1. Benchmark of computational tools

2. Determination of fissile Pu loading

3. Evaluation of burnable poison designs

4. Evaluation of reactivity feedback coefficients

This progress report presents the results of Task 1. The main objective of this task is to confirm the validity of the ELCOS ¹ code system for inert matrix …

Design Concepts And Process Analysis For Transmuter Fuel Manufacturing, Georg F. Mauer

Fuels Campaign (TRP)

This proposal addresses the subject heading ‘Transmutation Fuel Development’ in the 2004 research topic list of the UNLV Transmutation Research Program (TRP) and DOE Advanced Fuel Cycle Initiative (AFCI). The large-scale deployment of remote fabrication and refabrication processes (with a capacity of approx. 100 metric tons of Minor Actinides (MA) annually) will be required for all transmutation scenarios. The objective of this project is the design, analysis, and evaluation of manufacturing processes for transmuter fuel fabrication. Fabrication processes for different fuel types differ in terms of equipment types, throughput, and cost. The evaluation of the fabrication processes will create a …

Design And Evaluation Of Processes For Fuel Fabrication, Georg F. Mauer

Fuels Campaign (TRP)

The goal of this research project is to provide technical support to process designers working on the development of the fuel cycles for transmutation applications. Detailed process models are developed to better define the impact of fuel choice on the transmuter fuel cycle, including relative process losses, waste generation, and plant capital cost. These process models provide insight regarding required plant size and number of plants needed to mesh with the fuel recycling line. They also determine requirements for automation.

Manufacturing models for large-scale production in a hot cell environment are also developed. Combined, these two models allow the assessment …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion, Clemens Heske

Fuels Campaign (TRP)

The goal of this project is to elucidate the chemical bonding and interface formation of metal fission products with the coating materials used in state-of-the-art TRISO fuel particles. Particular emphasis is placed on an analysis of intermediate chemical phases at the interface, the intermixing/diffusion behavior, and the electronic interface structure as a function of material choice (metal and coating materials), temperature, and external stress. Furthermore, we intend to assess the chemical state of some of the metal fission products. The findings are expected to give valuable information about failure mechanisms of TRISO particles and fission product transport. Secondly, through simulating …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 3rd Quarter Report, 2004, Clemens Heske

Fuels Campaign (TRP)

The goal of this project, which started in May 2004, is to elucidate the chemical bonding and interface formation of metal fission products with the coating materials used in state-of-the-art TRISO fuel particles. Particular emphasis is placed on an analysis of intermediate chemical phases at the interface, the intermixing/diffusion behavior, and the electronic interface structure as a function of material choice (metal and coating materials), temperature, and external stress.

In detail, this project is devoted to studying the interface formation of Pd, Ag, and Cs with SiC and pyrolytic carbon. Using the TRISO coating materials and single crystal references as …

Interaction Between Metal Fission Products And Triso Coating Materials: A Study Of Chemical Bonding And Interdiffusion: 4th Quarter Report, 2004, Clemens Heske

Fuels Campaign (TRP)

The goal of this project, which started in May 2004, is to elucidate the chemical bonding and interface formation of metal fission products with the coating materials used in state-of-the-art TRISO fuel particles. Particular emphasis is placed on an analysis of intermediate chemical phases at the interface, the intermixing/diffusion behavior, and the electronic interface structure as a function of material choice (metal and coating materials), temperature, and external stress. In detail, this project is devoted to studying the interface formation of Pd, Ag, and Cs with SiC and pyrolytic carbon. In order to study the properties of the relevant interfaces, …

Dissolution, Reactor, And Environmental Behavior Of Zro2-Mgo Inert Fuel Matrix, Kenneth Czerwinski

Fuels Campaign (TRP)

This project will examine inert fuels containing ZrO₂ and MgO as the inert matrix, with the relative amount of MgO varied from 30% to 70% in ZrO₂. Reactor physics calculations will be used to examine suitable quantities of burnable poisons from the candidate elements Gd, Er, or Hf with reactor grade Pu providing the fissile component, with up to 10 % of ²³⁹Pu. Ceramics will be synthesized and characterized based on the reactor physics results. The solubility the fuel ceramics, in reactor conditions, reprocessing conditions, and repository conditions, will be investigated in a manner to provide …

Design And Evaluation Of Processes For Fuel Fabrication, Georg F. Mauer

Fuels Campaign (TRP)

The goal of this research project is to provide technical support to process designers working on the development of the fuel cycles for transmutation applications. Detailed process models are developed to better define the impact of fuel choice on the transmuter fuel cycle, including relative process losses, waste generation, and plant capital cost. These process models provide insight regarding required plant size and number of plants needed to mesh with the fuel recycling line. They also determine requirements for automation.

Manufacturing models for large-scale production in a hot cell environment are also developed. Combined, these two models allow the assessment …

Design And Evaluation Of Processes For Transmuter Fuel Fabrication, Georg F. Mauer

Fuels Campaign (TRP)

• Project Objective: examine autonomous robotic fuel fabrication processes with regard to hot cell and equipment design, operations, and costs.

• Fabrication processes for different fuel types differ in terms of equipment types, throughput, and cost.

• Design options are restricted by the requirement to employ only radiation-hardened machinery and components

• Benefit to Department of Energy: decision support for the selection of the most suitable manufacturing process.

Design And Evaluation Of Processes For Fuel Fabrication: Year 1 Final Report, Georg F. Mauer

Fuels Campaign (TRP)

The project objective is the design and evaluation of manufacturing processes for transmuter fuel fabrication. The large-scale deployment of remote fabrication and refabrication processes will be required for all transmutation scenarios. Current program emphasis is on a five-year effort to determine the feasibility of transmutation as a technology to limit the need for repository storage of spent commercial fuel. The evaluation of the fabrication processes will create a decision support data base to document design, operations, and costs. Fabrication processes required for different fuel types differ in terms of equipment types, throughput, and cost. The year 1 project was focused …

Development Of A Model For Induction Heating, Randy Clarksean, Yitung Chen

Fuels Campaign (TRP)

There are two coupled equations that must be solved in order to determine the power deposition. The numerical solution of these equations is needed in order to apply a source term within the energy equations. These equations have previously solved in FIDAP. That implementation used modified versions of the momentum and energy equations to provide a mechanism for the solution of two coupled equations. Currently, we want to solve for the induction heating field in addition to the flow field and the energy equation. In order to do this, a mechanism has to be defined within FIDAP to solve these …