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Chemistry

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2006

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Characterization Of Violet Emission From Rb Optical Pumping Cells Used In Laser-Polarized Xenon Nmr Experiments, Indrajit Saha, Panayiotis Nikolaou, Nicholas Whiting, Boyd M. Goodson Dec 2005

Characterization Of Violet Emission From Rb Optical Pumping Cells Used In Laser-Polarized Xenon Nmr Experiments, Indrajit Saha, Panayiotis Nikolaou, Nicholas Whiting, Boyd M. Goodson

Nicholas Whiting

Visible emission from Rb optical pumping cells was characterized under a range of conditions relevant to the production of laserpolarized xenon (including temperature, partial pressures, and D1-resonant 795 nm laser power). Bright 421 nm (6P --> 5S) emission was consistent with energy-pooling processes of the type: Rb*(5P1/2) + Rb*(5P1/2,3/2) --> Rb*(6P1/2,3/2) + Rb(5S1/2), with processes transiting through 5D states likely contributing at higher temperatures/lower N2 partial pressures. Under such conditions a number of Rb lines may be observed, indicating population of Rb states to P9D (~31822 cm^-1). Such energies exceed those required for efficient production of laser-induced plasma.

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Synthesis And Spectral Studies Of A Novel 20-Membered Unsymmetrical Dinucleating [N8] Macrocycle And Its Bimetallic Complexes, M2lcln(Clo4)2 (N = 2, M = Co, Ni Or Cu; N = 4, M = Cr Or Fe), Mohammad Mansoob Khan Dr, Z. A. Siddiqi Dr Dec 2005

Synthesis And Spectral Studies Of A Novel 20-Membered Unsymmetrical Dinucleating [N8] Macrocycle And Its Bimetallic Complexes, M2lcln(Clo4)2 (N = 2, M = Co, Ni Or Cu; N = 4, M = Cr Or Fe), Mohammad Mansoob Khan Dr, Z. A. Siddiqi Dr

Dr. Mohammad Mansoob Khan

A 20-membered octaaza unsymmetrical Schiff base macrocycle, 6,10,16,20-tetramethyl-7,9,17,19-tetraphenyl [1,5,7,9,11,15,17,19]octaazacycloeicosa-5,10,15,20-tetraene dihydroperchlorate, has been obtained as an...

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Exchange Coupling And Contribution Of Induced Orbital Angular Momentum Of Low-Spin Fe^3+ Ions To Magnetic Anisotropy In Cyanide-Bridged Fe2m2 Molecular Magnets: Spin-Polarized Density-Functional Calculations, Stephen Holmes, Kyungwha Park Dec 2005

Exchange Coupling And Contribution Of Induced Orbital Angular Momentum Of Low-Spin Fe^3+ Ions To Magnetic Anisotropy In Cyanide-Bridged Fe2m2 Molecular Magnets: Spin-Polarized Density-Functional Calculations, Stephen Holmes, Kyungwha Park

Stephen Holmes

Electronic structure and intramolecular exchange constants are calculated for three cyanide-bridged molecular magnets, Tp#1;FeIII#1;CN3MII#1;DMF4#4;2#1;OTf2 ·2DMF #1;MII=Mn,Co,Ni #1;abbreviated as Fe2Mn2, Fe2Co2, and Fe2Ni2 that have been recently synthesized, within a generalized-gradient approximation in spin-polarized density-functional theory #1;DFT. Here Tp#1;=C3#1;CH32HN2#4;3BH, OTf =O3SCF3, and DMF=HCON#1;CH32. Due to strong ligand fields present in the Tp#1;FeIII#1;CN3#4; − units, the Fe3+ ions exhibit a low ground-state spin of S=1/2. Our calculations show that the metal ions in the Fe2Mn2 molecule interact antiferromagnetically via cyanide ligands, while those in the Fe2Co2 and Fe2Ni2 molecule interact ferromagnetically. The calculations also suggest that the smallest gaps between the highest …

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1,4,10,13-Tetra­Oxa-7,16-Diazo­Niacyclo­Octa­Decane Bis­(Hexa­Fluoro­Phosphate): Pf6− Acting As A Pseudohalide, Daron E. Janzen, Maikel E. Botros, Gregory P. Helton, Donald G. Vanderveer, Gregory J. Grant Dec 2005

1,4,10,13-Tetra­Oxa-7,16-Diazo­Niacyclo­Octa­Decane Bis­(Hexa­Fluoro­Phosphate): Pf6− Acting As A Pseudohalide, Daron E. Janzen, Maikel E. Botros, Gregory P. Helton, Donald G. Vanderveer, Gregory J. Grant

Daron E Janzen, Ph.D.

No abstract provided.

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Progress Towards The Stereoselective Synthesis Of Korupensamine A, Andrew A. Lover Dec 2005

Progress Towards The Stereoselective Synthesis Of Korupensamine A, Andrew A. Lover

Andrew Lover

Progress towards the atroposelective synthesis of bioactive biaryl alkaoids in the michellamine and korupensamine family. (MS Thesis, University of California, Santa Barbara; 2006)

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