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Full-Text Articles in Social and Behavioral Sciences

Black Writing Ink Analysis By Direct Infusion Electrospray Mass Spectroscopy, Christopher M. Moody Jan 2010

Black Writing Ink Analysis By Direct Infusion Electrospray Mass Spectroscopy, Christopher M. Moody

Electronic Theses and Dissertations

An optimized method of extraction, an instrumental analysis method and data analysis was proposed for black writing inks based on direct infusion electrospray-mass spectrometry (ESI-MS). The sampling and analysis method is both minimally destructive and able to assess differences in inks from a reference collection of thirty ballpoint, gel, and rollerball inks. The methanol extracts of ink on paper samples were analyzed with three direct infusion (ESI-MS) methods. Each method varied scan voltage negative and positive, ESI fragmentor applied voltage (+120V, +0V, and -120V), and mobile phase additive. Direct infusion ESI-MS analysis, followed by pair-wise comparisons of the observed ion …


Determining The Presence Of An Ignitable Liquid Residue In Fire Debris Samples Utilizing Target Factor Analysis, Kelly Mchugh Jan 2010

Determining The Presence Of An Ignitable Liquid Residue In Fire Debris Samples Utilizing Target Factor Analysis, Kelly Mchugh

Electronic Theses and Dissertations

Current fire debris analysis procedure involves using the chromatographic patterns of total ion chromatograms, extracted ion chromatograms, and target compound analysis to identify an ignitable liquid according to the American Society for Testing and Materials (ASTM) E 1618 standard method. Classifying the ignitable liquid is accomplished by a visual comparison of chromatographic data obtained from any extracted ignitable liquid residue in the debris to the chromatograms of ignitable liquids in a database, i.e. by visual pattern recognition. Pattern recognition proves time consuming and introduces potential for human error. One particularly difficult aspect of fire debris analysis is recognizing an ignitable …


United States Land Cover Land Use Change, Albedo And Radiative Forcing: Past And Potential Climate Implications, Christopher A. Barnes Jan 2010

United States Land Cover Land Use Change, Albedo And Radiative Forcing: Past And Potential Climate Implications, Christopher A. Barnes

Electronic Theses and Dissertations

Land Cover Land Use (LCLU) change affects Earth surface properties including albedo that impose a radiative forcing on the climate. Recent spatially explicit satellite derived contemporary LCLU, albedo, and projected LCLU data are used to study the impact of LCLU change from 1973 to 2000, and from 2000 to 2050, on albedo and surface radiative forcing for the conterminous United States. Four research hypotheses concerned with past and potential future climate implications of LCLU change are addressed. The research described in this dissertation makes an important contribution to advancing understanding of the role of LCLU change on the climate system, …


Emergent Geographies In Green Energy, Sean Tierney Jan 2010

Emergent Geographies In Green Energy, Sean Tierney

Electronic Theses and Dissertations

A consensus on climate change is spurring an energy transition, but the geography of this transition is uneven and this paper evaluates the energy landscape globally, in the United States and in Colorado. Developed countries have taken the lead in installations and of next generation energy technology ownership. Green electricity has still not achieved parity with fossil fuels, which puts their adoption in the hands of policy makers who are trying to spur innovation with minimal financial disruption. Yet the future of green electricity is in question due to weak and fragmented policy regimes, but also because of inadequate R&D …


Item Order Effects On Attitude Measures, Pei-Hua Chen Jan 2010

Item Order Effects On Attitude Measures, Pei-Hua Chen

Electronic Theses and Dissertations

The purpose of this dissertation was to examine the effects of altered item order on attitude measures for both computerized adaptive and conventional survey formats. Based on items modified from a dissertation/thesis completion survey (Green & Kluever, 1997) with three scales, three survey versions were generated with items ordered by difficulty as hard-to-easy (H-E), easy-to-hard (E-H), and five medium trait level items presented first followed by randomly ordered items (M-R) for conventional survey format. Significant differences in item difficulty and item discrimination were found for two of the three scales. Differences in scale reliability were detected for the procrastination and …