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Articles 1 - 30 of 191
Full-Text Articles in Social and Behavioral Sciences
Late Quaternary Morphodynamics In The Quebrada De Purmamarca, Nw Argentina, Jan-Hendrik May, Ramiro Daniel Soler
Late Quaternary Morphodynamics In The Quebrada De Purmamarca, Nw Argentina, Jan-Hendrik May, Ramiro Daniel Soler
Faculty of Science - Papers (Archive)
This study aims to document the geomorphic, sedimentary and paleopedogenic archives in the Quebrada de Purmamarca. The paleoenvironmental interpretation of these archives and the reconstruction of landscape evolution are mainly based on field observations and geomorphological mapping (May 2008). A series of aggradational terraces mostly consisting of coarse debris-flow deposits are the main focus of this investigation. While the associated cut-and-fill processes are probably the result of an interplay between climatic and tectonic controls, the deposition of the youngest terrace level (> 150 m thickness) may likely be attributed to a drop of the periglacial belt of more than 1000 …
Assessing The Vulnerability Of Asian Megadeltas To Climate Change Using Gis, Colin D. Woodroffe
Assessing The Vulnerability Of Asian Megadeltas To Climate Change Using Gis, Colin D. Woodroffe
Faculty of Science - Papers (Archive)
Susceptibility of Asian megadeltas to climate change, including sea-level rise, is investigated using GIS. The Indus, Ganges-Brahmaputra-Meghna, Irrawaddy, Chao Phraya, Mekong, Red, Pearl, Changjiang, and Huanghe deltas began to form around 6000 years ago and have prograded since. The surface topography of active and abandoned delta plains is examined using digital terrain models derived from Shuttle Radar Topography Mission data and channel morphology is investigated using radar imagery. After delta plains are abandoned they become increasingly dominated by tidal processes. Population density is estimated using gridded world population data but highly variable local microtopography and uncertainty regarding future climate changes …
Application Of A Simple Hydrodynamic Model To Estuary Entrance Management, Errol J. Mclean, Jon B. Hinwood
Application Of A Simple Hydrodynamic Model To Estuary Entrance Management, Errol J. Mclean, Jon B. Hinwood
Faculty of Science - Papers (Archive)
Tidal inlets which link a tidal basin to the sea via a constricted entrance are common on the south-east Australian coast. Closure, or even significant constriction, raises water levels but restricts tidal range within the basin, while open entrances provide regular and significant tidal exchange with the ocean. A rapid assessment procedure with minimal data requirements has been shown to be informative for monitoring and a useful component of any Decision Support System set up as part of a management structure. Such a system is presented in this paper. It is based on one permanent water level gauge inside the …
Diffusion Of Vitamin B12 In Gellan Gum-Carbon Nanotube Hydrogels, Cameron Ferris, Marc In Het Panhuis
Diffusion Of Vitamin B12 In Gellan Gum-Carbon Nanotube Hydrogels, Cameron Ferris, Marc In Het Panhuis
Faculty of Science - Papers (Archive)
We report on the diffusion of vitamin B12 through gellan gum-carbon nanotube hydrogels. The addition of carbon nanotubes to gellan gum reduced the vitamin B12 diffusion coefficient from 1.70 x 10-6 cm2/s to 0.70 x 10-6 cm2/s.
What You Need To Know About Selenium, Terry Young, Keith Finley, William Adams, John Besser, William D. Hopkins, Dianne F. Jolley, Eugenia Mcnaughton, Theresa S. Presser, D. Patrick Shaw, Jason Unrine
What You Need To Know About Selenium, Terry Young, Keith Finley, William Adams, John Besser, William D. Hopkins, Dianne F. Jolley, Eugenia Mcnaughton, Theresa S. Presser, D. Patrick Shaw, Jason Unrine
Faculty of Science - Papers (Archive)
No abstract provided.
Synthesis Of Polyhydroxylated Pyrrolizidine And Indolizidine Compounds And Their Glycosidase Inhibitory Activities, Thunwadee Ritthiwigrom, Robert J. Nash, Stephen G. Pyne
Synthesis Of Polyhydroxylated Pyrrolizidine And Indolizidine Compounds And Their Glycosidase Inhibitory Activities, Thunwadee Ritthiwigrom, Robert J. Nash, Stephen G. Pyne
Faculty of Science - Papers (Archive)
The synthesis of the natural product 3-epi-casuarine and two tricyclic ether bridged analogues, plus 7-deoxy-3,6-diepi-casuarine, 7-epi-australine, 1-epi-castanospermine and 1,6-diepi-castanospermine is described. The glycosidase inhibitory activities of these compounds, along with that of uniflorine A and other polyhydroxylated pyrrolizidines and indolizidines that we have published before, are reported.
Synthesis Of 2′-Aminoalkyl-1-Benzylisoquinoline Derivatives And Medium Sized Ring Analogues With Mu Opiod Receptor Binding Activities, Uta Mbere-Nguyen, Alison T. Ung, Stephen G. Pyne
Synthesis Of 2′-Aminoalkyl-1-Benzylisoquinoline Derivatives And Medium Sized Ring Analogues With Mu Opiod Receptor Binding Activities, Uta Mbere-Nguyen, Alison T. Ung, Stephen G. Pyne
Faculty of Science - Papers (Archive)
Novel 2′-aminoalkyl-1-benzylisoquinoline compounds and medium size ring analogues have been prepared using reductive alkylation methods. Four of these analogues were tested for biological activity across 48 different CNS receptors and were showed to have binding activities at the mu opiod receptor.
The Acute Nociceptive Signals Induced By Bradykinin In Rat Sensory Neurons Are Mediated By Inhibition Of M-Type K+ Channels And Activation Of Ca2+-Activated Cl- Channels, Boyi Liu, John E. Linley, Xiaona Du, Xuan Zhang, Lezanne Ooi, Hailin Zhang, Nikita Gamper
The Acute Nociceptive Signals Induced By Bradykinin In Rat Sensory Neurons Are Mediated By Inhibition Of M-Type K+ Channels And Activation Of Ca2+-Activated Cl- Channels, Boyi Liu, John E. Linley, Xiaona Du, Xuan Zhang, Lezanne Ooi, Hailin Zhang, Nikita Gamper
Faculty of Science - Papers (Archive)
Bradykinin (BK) is an inflammatory mediator and one of the most potent endogenous pain-inducing substances. When released at sites of tissue damage or inflammation, or applied exogenously, BK produces acute spontaneous pain and causes hyperalgesia (increased sensitivity to potentially painful stimuli). The mechanisms underlying spontaneous pain induced by BK are poorly understood. Here we report that in small nociceptive neurons from rat dorsal root ganglia, BK, acting through its B2 receptors, PLC, and release of calcium from intracellular stores, robustly inhibits M-type K+ channels and opens Ca2+-activated Cl- channels (CaCCs) encoded by Tmem16a (also known as Ano1). Summation of these …
Transcriptional Control Of Kcnq Channel Genes And The Regulation Of Neuronal Excitability, Mariusz Mucha, Lezanne Ooi, John Linley, Pawel Mordaka, Carine Dalle, Brian Robertson, Nikita Gamper, Ian C. Wood
Transcriptional Control Of Kcnq Channel Genes And The Regulation Of Neuronal Excitability, Mariusz Mucha, Lezanne Ooi, John Linley, Pawel Mordaka, Carine Dalle, Brian Robertson, Nikita Gamper, Ian C. Wood
Faculty of Science - Papers (Archive)
Regulation of the resting membrane potential and the repolarization of neurons are important in regulating neuronal excitability. The potassium channel subunits Kv7.2 and Kv7.3 play a key role in stabilizing neuronal activity. Mutations in KCNQ2 and KCNQ3, the genes encoding Kv7.2 and Kv7.3, cause a neonatal form of epilepsy, and activators of these channels have been identified as novel antiepileptics and analgesics. Despite the observations that regulation of these subunits has profound effects on neuronal function, almost nothing is known about the mechanisms responsible for controlling appropriate expression levels. Here we identify two mechanisms responsible for regulating KCNQ2 and …
Chemistry Of Hydrogen Oxide Radicals (Hox) In The Arctic Troposphere In Spring, J Mao, D J. Jacob, M J. Evans, J R. Olson, X Ren, W H. Brune, T M. St. Clair, J D. Crounse, K M. Spencer, M R. Beaver, P O. Wennberg, M J. Cubison, J L. Jimenez, A Fried, P Weibring, J G. Walega, S R. Hall, A J. Weinheimer, R C. Cohen, G Chen, J H. Crawford, C Mcnaughton, A D. Clarke, L Jaegle, Jenny A. Fisher, R M. Yantosca, P Le Sager, C C. Carouge
Chemistry Of Hydrogen Oxide Radicals (Hox) In The Arctic Troposphere In Spring, J Mao, D J. Jacob, M J. Evans, J R. Olson, X Ren, W H. Brune, T M. St. Clair, J D. Crounse, K M. Spencer, M R. Beaver, P O. Wennberg, M J. Cubison, J L. Jimenez, A Fried, P Weibring, J G. Walega, S R. Hall, A J. Weinheimer, R C. Cohen, G Chen, J H. Crawford, C Mcnaughton, A D. Clarke, L Jaegle, Jenny A. Fisher, R M. Yantosca, P Le Sager, C C. Carouge
Faculty of Science - Papers (Archive)
We use observations from the April 2008 NASA ARCTAS aircraft campaign to the North American Arctic, interpreted with a global 3-D chemical transport model (GEOS-Chem), to better understand the sources and cycling of hydrogen oxide radicals (HOx≡H+OH+peroxy radicals) and their reservoirs (HOy≡HOx+peroxides) in the springtime Arctic atmosphere. We find that a standard gas-phase chemical mechanism overestimates the observed HO2 and H2O2 concentrations. Computation of HOx and HOy gas-phase chemical budgets on the basis of the aircraft observations also indicates a large missing sink for both. We hypothesize that …
The Arctic Research Of The Composition Of The Troposphere From Aircraft And Satellites (Arctas) Mission: Design, Execution, And First Results, D J. Jacob, J H. Crawford, H Maring, A D. Clarke, J E. Dibb, L K. Emmons, R A. Ferrare, C A. Hostetler, P B. Russell, H B. Singh, A M. Thompson, G E. Shaw, E Mccauley, J R. Pederson, J A. Fisher
The Arctic Research Of The Composition Of The Troposphere From Aircraft And Satellites (Arctas) Mission: Design, Execution, And First Results, D J. Jacob, J H. Crawford, H Maring, A D. Clarke, J E. Dibb, L K. Emmons, R A. Ferrare, C A. Hostetler, P B. Russell, H B. Singh, A M. Thompson, G E. Shaw, E Mccauley, J R. Pederson, J A. Fisher
Faculty of Science - Papers (Archive)
The NASA Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) mission was conducted in two 3-week deployments based in Alaska (April 2008) and western Canada (June–July 2008). Its goal was to better understand the factors driving current changes in Arctic atmospheric composition and climate, including (1) influx of mid-latitude pollution, (2) boreal forest fires, (3) aerosol radiative forcing, and (4) chemical processes. The June–July deployment was preceded by one week of flights over California (ARCTAS-CARB) focused on (1) improving state emission inventories for greenhouse gases and aerosols, (2) providing observations to test and improve models …
Total Column Co2 Measurements At Darwin, Australia - Site Description And Calibration Against In Situ Aircraft Profiles, Nicholas Deutscher, David Griffith, Glenn Bryant,, Paul Wennberg, G. Toon, Rebecca Washenfelder, Gretchen Keppel-Aleks, Debra Wunch, Yael Yavin, Norton Allen, J. F. Blavier, Rodrigo Jimenez, Bruce Daube, Alfram Bright, Daniel Matross, Steven Wofsy, Sunyoung Park
Total Column Co2 Measurements At Darwin, Australia - Site Description And Calibration Against In Situ Aircraft Profiles, Nicholas Deutscher, David Griffith, Glenn Bryant,, Paul Wennberg, G. Toon, Rebecca Washenfelder, Gretchen Keppel-Aleks, Debra Wunch, Yael Yavin, Norton Allen, J. F. Blavier, Rodrigo Jimenez, Bruce Daube, Alfram Bright, Daniel Matross, Steven Wofsy, Sunyoung Park
Faculty of Science - Papers (Archive)
An automated Fourier Transform Spectroscopic (FTS) solar observatory was established in Darwin, Australia in August 2005. The laboratory is part of the Total Carbon Column Observing Network, and measures atmospheric column abundances of CO2 and O2 and other gases. Measured CO2 columns were calibrated against integrated aircraft profiles obtained during the TWP-ICE campaign in January– February 2006, and show good agreement with calibrations for a similar instrument in Park Falls, Wisconsin. A clearsky low airmass relative precision of 0.1% is demonstrated in the CO2 and O2 retrieved column-averaged volume mixing ratios. The 1% negative bias in the FTS XCO2 relative …
Coping With Chaos: Unpredictable Food Supplies Intensify Torpor Use In An Arid-Zone Marsupial, The Fat-Tailed Dunnart (Sminthopsis Crassicaudata), Adam J. Munn, Pippa Kern, Bronwyn M. Mcallan
Coping With Chaos: Unpredictable Food Supplies Intensify Torpor Use In An Arid-Zone Marsupial, The Fat-Tailed Dunnart (Sminthopsis Crassicaudata), Adam J. Munn, Pippa Kern, Bronwyn M. Mcallan
Faculty of Science - Papers (Archive)
The severity, duration and amplitude of extreme weather events are forecast to intensify with current climate trends, over both long (e.g. seasonal) and short (e.g. daily) time-scales. As such, the predictability of food supplies for many small endotherms is likely to become increasingly important. Numerous small mammals and birds combat food shortages using torpor, a controlled reduction in metabolic rate and body temperature that helps lower their daily energy requirements. As such, torpor often has been cited as a key feature allowing some small endotherms to survive highly unpredictable climates, such as tropics or dry deserts, but mensurative demonstrations of …
Effects Of A Shark Repulsion Device On Rocky Reef Fishes: No Shocking Outcomes, Alison Broad, N. A. Knott, X. Turon, Andrew R. Davis
Effects Of A Shark Repulsion Device On Rocky Reef Fishes: No Shocking Outcomes, Alison Broad, N. A. Knott, X. Turon, Andrew R. Davis
Faculty of Science - Papers (Archive)
Shark repulsion devices (SRDs; e.g. Shark Shield™) use an electric field to deter large and potentially dangerous sharks. The use of these devices is becoming increasingly widespread for a range of recreational activities as well as scientific and commercial diving. We sought to determine if SRDs might modify the behaviour of chondrichthyan and osteichthyan fishes and thereby impact on fish assemblages, as well as potentially bias diver census techniques. To assess the potential impacts of this technology, we attached SRDs to baited remote underwater video (BRUV) units and deployed them on shallow rocky reefs in Jervis Bay Marine Park (New …
One In Four Citations In Marine Biology Papers Is Inappropriate, Peter Todd, James Guest, Jinzhen Lu, Loke Ming Chou
One In Four Citations In Marine Biology Papers Is Inappropriate, Peter Todd, James Guest, Jinzhen Lu, Loke Ming Chou
Faculty of Science - Papers (Archive)
Citing sources that do not support the assertion being made can misinform readers, perpetuate mistakes and deny credit to the researchers who should have been acknowledged. To quantify citation fidelity in marine biology, we retrieved 198 papers from 2 recent issues of 33 marine biology journals. From each paper we randomly selected 1 citation, recovered the source material, and evaluated its appropriateness. We discovered that the assertion was ‘clearly supported’ by the citation in only 75.8% of cases, the support was ‘ambiguous’ in 10.6% of cases and the citation offered ‘no support’ to the original statement in 6.0% of cases. …
Supply-Side Biogeography: Geographic Patterns Of Settlement And Early Mortality For A Barnacle Approaching Its Range Limit, Justin A. Lathlean, David J. Ayre, Todd E. Minchinton
Supply-Side Biogeography: Geographic Patterns Of Settlement And Early Mortality For A Barnacle Approaching Its Range Limit, Justin A. Lathlean, David J. Ayre, Todd E. Minchinton
Faculty of Science - Papers (Archive)
Species range limits are often associated with reduced adult densities, and this may reflect the failure of a particular life-history stage. For benthic marine invertebrates, settlement is a time of great mortality that strongly influences adult population structure, at least at local spatial scales. In south-eastern Australia we determined that adult abundance of the intertidal barnacle Tesseropora rosea declines over a 450 km region of rocky shore from the middle to the southern limit of its range, and we tested the hypothesis that this biogeographic pattern reflects variations in the production, settlement, or early post-settlement mortality of larvae or adult …
Panmictic Population Structure In The Migratory Marine Sparid Acanthopagrus Australis Despite Its Close Association With Estuaries, David Roberts, David Ayre
Panmictic Population Structure In The Migratory Marine Sparid Acanthopagrus Australis Despite Its Close Association With Estuaries, David Roberts, David Ayre
Faculty of Science - Papers (Archive)
Recent studies have revealed surprising levels of genetic structuring within populations of marine species that were previously thought to be widely dispersed. Such subdivision may reflect unexpected physical or biological barriers to dispersal, including philopatric behaviour. Here we investigate the genetic structure of the eastern Australian yellowfin bream Acanthopagrus australis—a widely distributed species that is thought to be highly dispersive but is also known to spawn in close association with estuaries. Our data from surveys of allele frequencies at 6 microsatellite DNA loci for 350 fish revealed high levels of genetic diversity within all sites but no genetic differentiation of …
Quantifying Wave Exposure In Shallow Temperate Reef Systems: Applicability Of Fetch Models For Predicting Algal Biodiversity, Nicole A. Hill, Austen R. Pepper, Marjetta Puotinen, Michael G. Hughes, Graham J. Edgar, Neville S. Barrett, Rick D. Stuart-Smith, Rebecca Leaper
Quantifying Wave Exposure In Shallow Temperate Reef Systems: Applicability Of Fetch Models For Predicting Algal Biodiversity, Nicole A. Hill, Austen R. Pepper, Marjetta Puotinen, Michael G. Hughes, Graham J. Edgar, Neville S. Barrett, Rick D. Stuart-Smith, Rebecca Leaper
Faculty of Science - Papers (Archive)
Management and conservation of ecosystems relies on biodiversity data; however, broad-scale biological data are often limited. Predictive modelling using environmental variables has recently proven a valuable tool in addressing this gap. Wave exposure is a particularly important environmental variable that structures shallow reef systems, but it is rarely quantified across the large areas often used for predictive studies. Therefore, we investigated approaches that quantify exposure and can be readily applied across a large area. We generated 6 quantitative indices that emphasise different aspects of exposure using a numerical wave model and cartographic fetch models. The utility of these indices for …
Recalcitrant Industrial Wastewater Treatment By Membrane Bioreactor (Mbr), Faisal I. Hai, Kazuo Yamamoto, Fumiyuki Nakajima, Kensuke Fukushi
Recalcitrant Industrial Wastewater Treatment By Membrane Bioreactor (Mbr), Faisal I. Hai, Kazuo Yamamoto, Fumiyuki Nakajima, Kensuke Fukushi
Faculty of Science - Papers (Archive)
Membrane Bioreactor (MBR) process consists of a biological reactor integrated with membranes that combine clarification and filtration of an activated sludge process into a simplified, single step process. The membrane is an absolute barrier to suspended matter and microorganisms and it offers the possibility of operating the system at high mixed liquor suspended solids (MLSS) concentration. The implication of maintenance of high MLSS are— requirement of a smaller footprint and operation at high solids retention time (SRT) under low F/M ratio, hence, yielding reduced excess sludge. Operating as an MBR allows conventional activated sludge plants to become single step processes, …
Evidence For Specific Subunit Distribution And Interactions In The Quaternary Structure Of Α-Crystallin, Amie M. Morris, J. Andrew Aquilina
Evidence For Specific Subunit Distribution And Interactions In The Quaternary Structure Of Α-Crystallin, Amie M. Morris, J. Andrew Aquilina
Faculty of Science - Papers (Archive)
The quaternary structure of α-crystallin is dynamic, a property which has thwarted crystallographic efforts towards structural characterization. In this study, we have used collision-induced dissociation mass spectrometry to examine the architecture of the polydisperse assemblies of α-crystallin. For total α-crystallin isolated directly from fetal calf lens using size-based chromatography, the αB-crystallin subunit was found to be preferentially dissociated from the oligomers, despite being significantly less abundant overall than the αA-crystallin subunits. Furthermore, upon mixing molar equivalents of purified αA- and αB-crystallin, the levels of their dissociation were found to decrease and increase, respectively, with time. Interestingly though, dissociation of subunits …
Localization Of Low Molecular Weight Crystallin Peptides In The Aging Human Lens Using A Maldi Mass Spectrometry Imaging Approach, S. P. Su, Jason D. Mcarthur, J. A. Aquilina
Localization Of Low Molecular Weight Crystallin Peptides In The Aging Human Lens Using A Maldi Mass Spectrometry Imaging Approach, S. P. Su, Jason D. Mcarthur, J. A. Aquilina
Faculty of Science - Papers (Archive)
Low molecular weight (LMW) peptides, derived from the breakdown of the major eye lens proteins, the crystallins, accumulate in the human lens with age. These LMW peptides are associated with age-related lens opacity and cataract, with some shown to inhibit the chaperone activity of α-crystallin. However, the mechanism(s) giving rise to the production of these peptides, as well as their distribution within the lens, are not well understood. In this study, we have mapped the distribution of these crystallin-derived peptides present in human lenses of different ages using matrix-assisted laser desorption/ionization-imaging mass spectrometry (MALDI-IMS). Our data showed that most of …
And Then There Were None?, Richard G. Roberts, Barry W. Brook
And Then There Were None?, Richard G. Roberts, Barry W. Brook
Faculty of Science - Papers (Archive)
No abstract provided.
Effect Of Two Types Of Tree Guards (With And Without Weed Control) On Tree Seedling Establishment, Brenton Ladd, Stephen P. Bonser, Joshua R. Larsen
Effect Of Two Types Of Tree Guards (With And Without Weed Control) On Tree Seedling Establishment, Brenton Ladd, Stephen P. Bonser, Joshua R. Larsen
Faculty of Science - Papers (Archive)
No abstract provided.
Age And Origin Of Alluvial Sediments Within And Flanking The Mt Lofty Ranges, Southern South Australia: A Late Quaternary Archive Of Climate And Environmental Change, D Banerjee, N F. Alley, R P. Bourman, S Buckman, J R. Prescott
Age And Origin Of Alluvial Sediments Within And Flanking The Mt Lofty Ranges, Southern South Australia: A Late Quaternary Archive Of Climate And Environmental Change, D Banerjee, N F. Alley, R P. Bourman, S Buckman, J R. Prescott
Faculty of Science - Papers (Archive)
No abstract provided.
Synthesis Of Hyacinthacine B-3 And Purported Hyacinthacine B-7, Christopher W.G. Au, Robert J. Nash, Stephen G. Pyne
Synthesis Of Hyacinthacine B-3 And Purported Hyacinthacine B-7, Christopher W.G. Au, Robert J. Nash, Stephen G. Pyne
Faculty of Science - Papers (Archive)
The synthesis of hyacinthacines B-3 and B-7 has confirmed the structure of the former alkaloid and shown that the structure of the latter is incorrect.
Dipyridyl Beta-Diketonate Complexes: Versatile Polydentate Metalloligands For Metal-Organic Frameworks And Hydrogen-Bonded Networks, Andrew D. Burrows, Christopher G. Frost, Mary F. Mahon, Paul R. Raithby, Catherine L. Renouf, Christopher Richardson, Anna J. Stevenson
Dipyridyl Beta-Diketonate Complexes: Versatile Polydentate Metalloligands For Metal-Organic Frameworks And Hydrogen-Bonded Networks, Andrew D. Burrows, Christopher G. Frost, Mary F. Mahon, Paul R. Raithby, Catherine L. Renouf, Christopher Richardson, Anna J. Stevenson
Faculty of Science - Papers (Archive)
The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.
Esi-Ms And Thermal Melting Studies Of Nanoscale Platinum(Ii) Metallomacrocycles With Dna, Margaret M. Harding, Louis M. Rendina, David Schilter, Thitima Urathamakul, Jennifer L. Beck
Esi-Ms And Thermal Melting Studies Of Nanoscale Platinum(Ii) Metallomacrocycles With Dna, Margaret M. Harding, Louis M. Rendina, David Schilter, Thitima Urathamakul, Jennifer L. Beck
Faculty of Science - Papers (Archive)
The hydrophilic, long-chain diamine PEGda (O,O′-bis(2-aminoethyl)octadeca(ethylene glycol)), when complexed with cis-protected Pt(II) ions afforded water-soluble complexes of the type [Pt(N,N)(PEGda)](NO3)2 (N,N = N,N,N′,N′-tetramethyl-1,2-diaminoethane (tmeda), 1,2-diaminoethane (en), and 2,2′-bipyridine (2,2′-bipy)) featuring unusual 62-membered chelate rings. Equimolar mixtures containing either the 16-mer duplex DNA D2 or the single-stranded D2a and [Pt(N,N)(PEGda)]2+ were analyzed by negative-ion ESI-MS. Analysis of D2-Pt(II) mixtures showed the formation of 1:1 adducts of [Pt(en)(PEGda)]2+, [Pt(tmeda)(PEGda)]2+ and the previously-described metallomacrocycle [Pt2(2,2′-bipy)2{4,4′-bipy(CH2)44,4′-bipy}2]8+ with D2; the dinuclear species bound to D2 most strongly, consistent with its greater charge and aromatic surface area. D2 formed 1:2 complexes with the acyclic species [Pt(2,2′-bipy)(Mebipy)2]4+ …
In Vivo Measurement Of Plant Respiration, M. Ribas-Carbo, J. Flexas, Sharon A. Robinson, G. G.B. Tcherkez
In Vivo Measurement Of Plant Respiration, M. Ribas-Carbo, J. Flexas, Sharon A. Robinson, G. G.B. Tcherkez
Faculty of Science - Papers (Archive)
Respiration is vital; it is the essence of life. Respiration is the mechanism by which energy obtained during the photosynthesis process is transformed into biochemical energy, in the form of ATP. This transformation of energy keeps all cells in all organisms alive. While energy conversion is the main function of respiration in animals, respiration has several other functions in plants. Among them, interactions with photosynthesis such as photorespiration and the production of carbon skeletons for the many compounds synthesized in plants (e.g., pigments, proteins and secondary metabolites). Therefore, it comes as no surprise that such a key role of respiration …
Flexible And Compressible Goretex-Pedot Membrane Electrodes For Solid-State Dye-Sensitized Solar Cells, Attila J. Mozer, Dillip K. Panda, Sanjeev Gambhir, Anthony C. Romeo, Bjorn Winther-Jensen, Gordon G. Wallace
Flexible And Compressible Goretex-Pedot Membrane Electrodes For Solid-State Dye-Sensitized Solar Cells, Attila J. Mozer, Dillip K. Panda, Sanjeev Gambhir, Anthony C. Romeo, Bjorn Winther-Jensen, Gordon G. Wallace
Faculty of Science - Papers (Archive)
A porous, flexible electrode based on a PTFE (Teflon) membrane (Goretex) coated with a metallic current collector and a conducting polymer (poly(3,4-ethylenedioxythiophene), PEDOT) has been developed for applications in solidstate dye-sensitized solar cells. Its low sheet resistance and compressibility make it an ideal electrode on uneven TiO2 surfaces with high efficiency and reproducibility. The porous nature of the electrode enables the feed-through of reactants and treatment agents, which opens up exciting opportunities to interface these photoelectrochemical devices with electrocatalytic, energy conversion, and storage systems. Postfabrication bonding of the photoanode and the Goretex-Au-PEDOT electrode is demonstrated.
Novel Technique Shows Different Hydrophobic Chemical Signatures Of Exotic And Indigenous Plant Soils With Similar Effects Of Extracts On Indigenous Species Seedling Growth, Emilie-Jane Ens, Kristine O. French, John B. Bremner, Jurgen Korth
Novel Technique Shows Different Hydrophobic Chemical Signatures Of Exotic And Indigenous Plant Soils With Similar Effects Of Extracts On Indigenous Species Seedling Growth, Emilie-Jane Ens, Kristine O. French, John B. Bremner, Jurgen Korth
Faculty of Science - Papers (Archive)
Changes to ecosystem abiotic parameters are regarded as possible mechanisms facilitating plant invasion and community composition shifts. This study compared the hydrophobic chemical signatures of soil from exotic bitou bush (Chrysanthemoides monilifera spp. rotundata) invaded, indigenous acacia (Acacia longifolia var. sophorae) dominated and bare sand (unvegetated) habitats using a novel, rapid, capturing technique which utilised AmberliteA (R) XAD4 resin filled bags that were placed in situ. The hydrophobic chemical signature of the bitou bush soil extract was significantly different to the acacia soil and bare sand extracts. High concentrations of 18 sesquiterpenes dominated the hydrophobic signature of the bitou bush …