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Faculty of Engineering and Information Sciences - Papers: Part A

2014

Organic

Articles 1 - 12 of 12

Full-Text Articles in Social and Behavioral Sciences

A Novel Type Of One-Dimensional Organic Selenium-Containing Fiber With Superior Performance For Lithium-Selenium And Sodium-Selenium Batteries, Hongqiang Wang, Sha Li, Zhixin Chen, Hua-Kun Liu, Zaiping Guo Jan 2014

A Novel Type Of One-Dimensional Organic Selenium-Containing Fiber With Superior Performance For Lithium-Selenium And Sodium-Selenium Batteries, Hongqiang Wang, Sha Li, Zhixin Chen, Hua-Kun Liu, Zaiping Guo

Faculty of Engineering and Information Sciences - Papers: Part A

A novel type of organic selenide fiber composed of carbonized polyacrylonitrile/selenium (CPAN/Se) has been synthesized by heating polyacrylonitrile-selenium (PAN-Se) fibers via the electrospinning technique at 600°C. The Se molecules are confined by N-containing carbon ring structures in the form of energy-storing selenium side chains in the carbonized PAN matrix. This unique stable chemical structure with a conductive carbon skeleton connected to the selenium side chains and excellent mechanical stability can allow CPAN/Se composite cathodes to be charged and discharged in a low-cost carbonate-based electrolyte with excellent long cycle stability and quite good rate performance. The superior electrochemical performance of CPAN/Se …


Neutron-Gamma Pulse Shape Discrimination Using Organic Scintillators With Silicon Photomultiplier Readout, Rhys M. Preston, John Eberhardt, James Tickner Jan 2014

Neutron-Gamma Pulse Shape Discrimination Using Organic Scintillators With Silicon Photomultiplier Readout, Rhys M. Preston, John Eberhardt, James Tickner

Faculty of Engineering and Information Sciences - Papers: Part A

Neutron/Gamma pulse shape discrimination (PSD) was measured using stilbene and EJ-299-34 plastic scintillators with readout by silicon photomultipliers (SiPMs). The SiPM pulses were digitized and processed for energy and pulse shape information using a digital technique performing numerical weighted integrations on each pulse. A genetic algorithm (GA) was developed to optimize the weighting vectors used for the pulse shape discrimination. Efficient PSD was obtained down to an electron-equivalent energy of 127 keV with stilbene and 391 keV with the EJ-299-34 PSD plastic. Separation at lower energies was possible at reduced detection efficiency, down to 78 keV and 186 keV at …


Removal Of Trace Organic Chemicals And Performance Of A Novel Hybrid Ultrafiltration-Osmotic Membrane Bioreactor, Ryan W. Holloway, Julia Regnery, Long D. Nghiem, Tzahi Cath Jan 2014

Removal Of Trace Organic Chemicals And Performance Of A Novel Hybrid Ultrafiltration-Osmotic Membrane Bioreactor, Ryan W. Holloway, Julia Regnery, Long D. Nghiem, Tzahi Cath

Faculty of Engineering and Information Sciences - Papers: Part A

A hybrid ultrafiltration-osmotic membrane bioreactor (UFO-MBR) was investigated for over 35 days for nutrient and trace organic chemical (TOrC) removal from municipal wastewater. The UFO-MBR system uses both ultrafiltration (UF) and forward osmosis (FO) membranes in parallel to simultaneously extract clean water from an activated sludge reactor for nonpotable (or environmental discharge) and potable reuse, respectively. In the FO stream, water is drawn by osmosis from activated sludge through an FO membrane into a draw solution (DS), which becomes diluted during the process. A reverse osmosis (RO) system is then used to reconcentrate the diluted DS and produce clean water …


Rejection And Fate Of Trace Organic Compounds (Trocs) During Membrane Distillation, Kaushalya Wijekoon, Faisal Ibney Hai, Jinguo Kang, William E. Price, Tzahi Cath, Long D. Nghiem Jan 2014

Rejection And Fate Of Trace Organic Compounds (Trocs) During Membrane Distillation, Kaushalya Wijekoon, Faisal Ibney Hai, Jinguo Kang, William E. Price, Tzahi Cath, Long D. Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

In this study, we examined the feasibility of membrane distillation (MD) for removing trace organic compounds (TrOCs) during water and wastewater treatment. A set of 29 compounds was selected to represent major TrOC groups, including pharmaceuticals, steroid hormones, phytoestrogens, UV-filters, industrial chemicals, and pesticides that occur ubiquitously in municipal wastewater. Results reported here suggest that rejection and fate and transport of TrOC during MD are governed by their volatility and, to a lesser extent, hydrophobicity. All TrOCs with pKH > 9 (which can be classified as non-volatile) were well removed by MD. Among the 29 TrOCs investigated in this study, three …


Enhancement Of Trace Organic Contaminant Degradation By Crude Enzyme Extract From Trametes Versicolor Culture: Effect Of Mediator Type And Concentration, Ngoc Luong Nguyen, Faisal Ibney Hai, Jinguo Kang, Frederic Leusch, Felicity Roddick, S Faraj Magram, William Price, Long Nghiem Jan 2014

Enhancement Of Trace Organic Contaminant Degradation By Crude Enzyme Extract From Trametes Versicolor Culture: Effect Of Mediator Type And Concentration, Ngoc Luong Nguyen, Faisal Ibney Hai, Jinguo Kang, Frederic Leusch, Felicity Roddick, S Faraj Magram, William Price, Long Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

The performance of two redox mediating compounds, namely 1-hydroxybenzotriazole (HBT) and syringaldehyde (SA), was compared in terms of enhancement of enzymatic degradation of a diverse set of 14 phenolic and 16 non-phenolic trace organic contaminants (TrOCs) and the toxicity of the treated media. Extracellular enzyme extract (predominantly containing laccase) from Trametes versicolor culture achieved efficient degradation (70-95%) of nine phenolic and one non-phenolic TrOCs. Mediator dosing extended the spectrum of efficiently degraded TrOCs to 13 phenolic and three non-phenolic compounds, with moderate improvements in removal of a few other non-phenolic compounds. TrOC removal efficiency improved significantly as the HBT dose …


Impact Of Organic And Colloidal Fouling On Trace Organic Contaminant Rejection By Forward Osmosis: Role Of Initial Permeate Flux, Ming Xie, Long D. Nghiem, William E. Price, Menachem Elimelech Jan 2014

Impact Of Organic And Colloidal Fouling On Trace Organic Contaminant Rejection By Forward Osmosis: Role Of Initial Permeate Flux, Ming Xie, Long D. Nghiem, William E. Price, Menachem Elimelech

Faculty of Engineering and Information Sciences - Papers: Part A

Fouling behaviour and its impact on the rejection of trace organic contaminants (TrOCs) by forward osmosis (FO) were investigated.Membrane fouling was simulated using humic acid and colloidal particles asmodel foulants at different initial permeatewater fluxes.Water flux declinewas insignificant at an initial permeate flux of 9 L/m2h and the fouling layerwas loose and fluid-like. By contrast, thewater flux declinewas substantial at an initial permeate flux of 20 L/m2h, resulting in the formation of a compact fouling layer. Water flux recovery after physical cleaning for both humic acid and colloidal particle fouledmembraneswas consistently higher at an initial permeate flux of 9 L/m2h …


Effects Of Organic And Colloidal Fouling On The Rejection Of Two Pharmaceutically Active Compounds (Phacs) By Nanofiltration Processes: Role Of Membrane Foulants, Long D. Nghiem, Christiane Espendiller Jan 2014

Effects Of Organic And Colloidal Fouling On The Rejection Of Two Pharmaceutically Active Compounds (Phacs) By Nanofiltration Processes: Role Of Membrane Foulants, Long D. Nghiem, Christiane Espendiller

Faculty of Engineering and Information Sciences - Papers: Part A

No abstract provided.


Enhancement Of Removal Of Trace Organic Contaminants By Powdered Activated Carbon Dosing Into Membrane Bioreactors, Ngoc Luong Nguyen, Faisal Ibney Hai, Long Nghiem, Jinguo Kang, William Price, Chul Park, Kazuo Yamamoto Jan 2014

Enhancement Of Removal Of Trace Organic Contaminants By Powdered Activated Carbon Dosing Into Membrane Bioreactors, Ngoc Luong Nguyen, Faisal Ibney Hai, Long Nghiem, Jinguo Kang, William Price, Chul Park, Kazuo Yamamoto

Faculty of Engineering and Information Sciences - Papers: Part A

This study compared the removal efficiency of 22 widespread trace organic contaminants by a laboratory-scale membrane bioreactor (MBR) with and without direct addition of powdered activated carbon (PAC) into the activated sludge reactor over a period of 312 days. The removal of hydrophilic and biologically persistent trace organic contaminants was immediately improved to above 95% after the addition of PAC into MBR. However, a compound-specific gradual decrease in removal underscored the requirement for the addition of fresh PAC. Adsorption onto PAC-added sludge appeared to play a significant role in the relatively more effective aqueous phase removal of a few resistant …


Impact Of 1-Hydroxybenzotriazole Dosing On Trace Organic Contaminant Degradation By Laccase, Ngoc Luong Nguyen, Faisal Ibney Hai, Jinguo Kang, S Faraj Magram, William Price, Long Nghiem Jan 2014

Impact Of 1-Hydroxybenzotriazole Dosing On Trace Organic Contaminant Degradation By Laccase, Ngoc Luong Nguyen, Faisal Ibney Hai, Jinguo Kang, S Faraj Magram, William Price, Long Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

This study investigated the removal of five selected non-phenolic trace organic contaminants (TrOC) by extracellular enzyme extract from a white-rot fungus. Except diclofenac, no other investigated non-phenolic TrOC were degraded by the extracellular enzyme extract. Improvement of enzymatic degradation of all TrOC was achieved in the presence of a redox mediator, namely, 1-hydroxybenzotriazole (HBT). However, the enhancement of degradation was mediator concentration-specific. A significant improvement in degradation at higher dosage than 0.1 mM (HBT) was achieved.


A Novel Membrane Distillation-Thermophilic Bioreactor System: Biological Stability And Trace Organic Compound Removal, Kaushalya Wijekoon, Faisal Ibney Hai, Jinguo Kang, William Price, Wenshan Guo, Hao H. Ngo, Tzahi Cath, Long Nghiem Jan 2014

A Novel Membrane Distillation-Thermophilic Bioreactor System: Biological Stability And Trace Organic Compound Removal, Kaushalya Wijekoon, Faisal Ibney Hai, Jinguo Kang, William Price, Wenshan Guo, Hao H. Ngo, Tzahi Cath, Long Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

The removal of trace organic compounds (TrOCs) by a novel membrane distillation-thermophilic bioreactor (MDBR) system was examined. Salinity build-up and the thermophilic conditions to some extent adversely impacted the performance of the bioreactor, particularly the removal of total nitrogen and recalcitrant TrOCs. While most TrOCs were well removed by the thermophilic bioreactor, compounds containing electron withdrawing functional groups in their molecular structure were recalcitrant to biological treatment and their removal efficiency by the thermophilic bioreactor was low (0-53%). However, the overall performance of the novel MDBR system with respect to the removal of total organic carbon, total nitrogen, and TrOCs …


The Effects Of Feed Solution Temperature On Pore Size And Trace Organic Contaminant Rejection By The Nanofiltration Membrane Nf270, Hai Quang Dang, William E. Price, Long Duc Nghiem Jan 2014

The Effects Of Feed Solution Temperature On Pore Size And Trace Organic Contaminant Rejection By The Nanofiltration Membrane Nf270, Hai Quang Dang, William E. Price, Long Duc Nghiem

Faculty of Engineering and Information Sciences - Papers: Part A

This study investigated the effect of feed temperature on membrane pore size and the rejection of trace organic contaminants (TrOCs) by the nanofiltration (NF) membrane NF270. Filtration experiments were conducted using a cross flow membrane system at 20, 30 and 40 C. The membrane pore radius was estimated using the pore hindrance transport model at each temperature and the rejection data of three reference organic solutes (i.e. erythritol, xylose and glucose) experimentally obtained in this study. The results suggest that the pore size of an NF membrane is dependent on the feed solution temperature. An increase in the feed temperature …


Relating Rejection Of Trace Organic Contaminants To Membrane Properties In Forward Osmosis: Measurements, Modelling And Implications, Ming Xie, Long D. Nghiem, William E. Price, Menachem Elimelech Jan 2014

Relating Rejection Of Trace Organic Contaminants To Membrane Properties In Forward Osmosis: Measurements, Modelling And Implications, Ming Xie, Long D. Nghiem, William E. Price, Menachem Elimelech

Faculty of Engineering and Information Sciences - Papers: Part A

This study elucidates the relationship between membrane properties and the rejection of trace organic contaminants (TrOCs) in forward osmosis (FO). An asymmetric cellulose triacetate (CTA) and a thin-film composite (TFC) polyamide FO membrane were used for this investigation. The effective average pore radius (rp), selective barrier thickness over porosity parameter (l/ε), surface charge, support layer structural parameter (S), pure water permeability coefficient (A) and salt (NaCl) permeability coefficient (B) of the two membranes were systematically characterised. Results show that measured rejection of TrOCs as a function of permeate water flux can be well described by the pore hindrance transport model. …