Social and Behavioral Sciences Commons^™

Product Branching Fractions Of The Ch + Propene Reaction From Synchrotron Photoionization Mass Spectrometry, Adam J. Trevitt, Matthew B. Prendergast, Fabien Goulay, John D. Savee, David L. Osborn, Craig A. Taatjes, Stephen R. Leone

Adam Trevitt

The CH(X2Π) + propene reaction is studied in the gas phase at 298 K and 4 Torr (533.3 Pa) using VUV synchrotron photoionization mass spectrometry. The dominant product channel is the formation of C4H6 (m/z 54) + H. By fitting experimental photoionization spectra to measured spectra of known C4H6 isomers, the following relative branching fractions are obtained: 1,3-butadiene (0.63 ± 0.13), 1,2-butadiene (0.25 ± 0.05), and 1-butyne (0.12 ± 0.03) with no detectable contribution from 2-butyne. The CD + propene reaction is also studied and two product channels are observed that correspond to C4H6 (m/z 54) + D and C4H5D …

Factors Affecting The Acquisition And Transfer Of Novel Attribute Relationships To New Product Categories, Stewart Shapiro, Mark Spence, Jennifer Gregan-Paxton

Mark Spence

This article investigates two factors posited to affect consumers' ability to learn a novel attribute relationship (e.g., "no pesticides → USDA organic symbol") and apply this recently acquired knowledge when making judgments in a new product category. The first factor concerns the nature of the attribute encoding process and, in particular, whether it allows for comparison of examples. The second factor focuses on the relationship between the learning and transfer domains, and examines the influence of perceptual similarity (manipulated two ways: similarity in the elements comprising the attribute relationships, and similarity between the base and target domains) on the transfer …

Factors Influencing The Non-Use Of Respite Services By Caregivers Of People Living With Dementia Differ According To Respite Product And By Caregiver And Care Recipient Need, L Phillipson, S C. Jones

Sandra Jones

Abstract presented at the 8th National Conference of Emerging Researchers in Ageing, 23 Oct 2009, Melbourne, Australia

Isomer-Specific Product Detection Of Cn Radical Reactions With Ethene And Propene By Tunable Vuv Photoionization Mass Spectrometry, Adam Trevitt, Fabien Goulay, Giovanni Meloni, David Osborn, Craig Taatjes, Stephen Leone

Adam Trevitt

No abstract provided.

Pyrolysis Of Fulvenallene (C7h6) And Fulvenallenyl (C7h5): Theoretical Kinetics And Experimental Product Detection, Adam Trevitt, G Da Silva, M Steinbauer, P Hemberger

Adam Trevitt

Fulvenallene and fulvenallenyl are the respective C7H6 and C7H5 global minima, yet their importance to combustion has only recently emerged. We have studied the pyrolysis of these species theoretically to obtain rate constants and compare our results to pyrolysis mass spectrometry experiments for product identification. Master equation modeling reveals that fulvenallene rapidly dissociates to fulvenallenyl + H, and that fulvenallenyl dissociates to form propargyl plus diacetylene, with lesser amounts of i-C5H3 (CH2CCCCH)/n-C5H3 (CHCCHCCH) plus acetylene. Photoionization mass spectrometry experiments using a pyrolysis source on the fulvenallene precursor phthalide identify products consistent with those proposed theoretically for both fulvenallene and fulvenallenyl …

Reactions Of Small Carbon-Bearing Radicals With Unsaturated Hydrocarbons: Product Detection And Low Temperature Kinetics, Adam Trevitt, Fabien Goulay, Stephen Leone

Adam Trevitt

We report on results from two experimental techniques concerned with the reactions of small carbon based radicals (CN and CH) with unsaturated hydrocarbons. First, low temperature (100-300K) kinetic studies using a pulse Laval nozzle technique probe the reactions of the CN radical with benzene and toluene. The CN + benzene is found to be a fast, barrierless reaction. But in the case of toluene, two reaction pathways are in competition, one of which back dissociates to the reactants. The implications for the atmosphere of Titan are discussed. Product detection studies undertaken at the Advanced Light Source (ALS) using synchrotron coupled …

Product Detection Of The Ch Radical Reaction With Acetaldehyde, Fabien Goulay, Adam Trevitt, John Savee, Jordy Bouwman, David Osborn, Craig Taatjes, Kevin Wilson, Stephen Leone

Adam Trevitt

The reaction of the methylidyne radical (CH) with acetaldehyde (CH3CHO) is studied at room temperature and at a pressure of 4 Torr (533.3 Pa) using a multiplexed photoionization mass spectrometer coupled to the tunable vacuum ultraviolet synchrotron radiation of the Advanced Light Source at Lawrence Berkeley National Laboratory. The CH radicals are generated by 248 nm multiphoton photolysis of CHBr3 and react with acetaldehyde in an excess of helium and nitrogen gas flow. Five reaction exit channels are observed corresponding to elimination of methylene (CH2), elimination of a formyl radical (HCO), elimination of carbon monoxide (CO), elimination of a methyl …

Branching Fractions Of The Cn + C3h6 Reaction Using Synchrotron Photoionization Mass Spectrometry: Evidence For The 3-Cyanopropene Product, Adam Trevitt, Talitha Selby, Craig Taatjes, Satchin Soorkia, J Savee, D L Osborn, S R Leone

Adam Trevitt

The gas-phase CN + propene reaction is investigated using synchrotron photoionization mass spectrometry (SPIMS) over the 9.8 - 11.5 eV photon energy range. Experiments are conducted at room temperature in 4 Torr of He buffer gas. The CN + propene addition reaction produces two distinct product mass channels, C3H3N and C4H5N, corresponding to CH3 and H elimination, respectively. The CH3 and H elimination channels are measured to have branching fractions of 0.59 + 0.15 and 0.41 + 0.10, respectively. The absolute photoionization cross sections between 9.8 and 11.5 eV are measured for the three considered H-elimination coproducts: 1-, 2-, and …

Metodología Para Generar Información Regional. Aplicación A La Industria Mexicana, Vicente German-Soto

Vicente German-Soto

The Effects Of Structure, Communication And Trust Between Marketing And R&D During New Product Development, Elias Kyriazis, Graham Massey

Elias Kyriazis

The ability to effectively manage cross-functional working relationships (CFRs) during innovation is a key success factor in developing successful new products. However, empirical evidence suggests that CFRs during new product development are often problematic, resulting in extremely poor relations between managers, and the development of unsuccessful new products. This paper adds to our existing knowledge on the Marketing/R&D CFR by examining the effects of structural factors, communication behaviours, and interpersonal trust on the dependent variable perceived relationship effectiveness. Our findings reveal that trust has potent positive, direct effects on this CFR. Further, bidirectional communication and quality of communication also have …

Relative Values And Complementarity Of Online And Offline Interactions In Consumer Buying Behaviour: A Proposed Research Plan To Study Purchasing Of A Consumer Service Product Bundle, Robert G. Grant

Robert Grant

Current research into online consumer behaviour seems to be limited in two respects, firstly it treats online interaction as a stand-alone phenomenon and secondly it focuses on discrete steps in consumer processes, neglecting links between the steps. This paper proposes a research method to investigate relative values and complementarity between online and offline interactions in a consumer's buying process, examining differences within and between steps. A range of information source types and functional resource options will be researched for both effectiveness and efficiency benefits as well as emotional preferences for both online and offline interactions. The research will focus on …

Utilitarian And Hedonic Value Across Fulfillment-Product Categories Of Internet Shopping, Julie E. Francis, Lesley White

Julie Francis

Extant Internet shopping literature identifies potential sources, and inhibitors, of utilitarian and hedonic value for consumers. However, Internet shopping is oftentimes treated as a relatively homogenous activity or the insights are accompanied by inexact qualifications such as 'in some situations' or 'for some types of products'. The present study enhances these insights in two ways. Firstly, the authors developed a Fulfillment-Product classification scheme that segments Internet shopping situations on the basis of shared marketing-relevant characteristics. Secondly, the study provides a more detailed analysis than has to date been performed by examining the sources and inhibitors of utilitarian and hedonic value …

Reaction Of The C2h Radical With 1-Butyne (C4h6): Low Temperature Kinetics And Isomer-Specific Product Detection, Satchin Soorkia, Adam J. Trevitt, Talitha M. Selby, David L. Osborn, Craig A. Taatjes, Kevin R. Wilson, Stephen R. Leone

Adam Trevitt

No abstract provided.

Reactions Of The Cn Radical With Benzene And Toluene: Product Detection And Low-Temperature Kinetics, Adam J. Trevitt, Fabien Goulay, Craig A. Taatjes, David L. Osborn, Stephen R. Leone

Adam Trevitt

Low-temperature rate coefficients are measured for the CN + benzene and CN + toluene reactions using the pulsed Laval nozzle expansion technique coupled with laser-induced fluorescence detection. The CN + benzene reaction rate coefficient at 105, 165, and 295 K is found to be relatively constant over this temperature range, (3.9−4.9) × 10−10 cm3 molecule−1 s−1. These rapid kinetics, along with the observed negligible temperature dependence, are consistent with a barrierless reaction entrance channel and reaction efficiencies approaching unity. The CN + toluene reaction is measured to have a rate coefficient of 1.3 × 10−10 cm3 molecule−1 s−1 at 105 …

New Process And New Products In Europe And Italy, Mario Pianta, Francesco Crespi

Mario Pianta