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Full-Text Articles in Social and Behavioral Sciences

Synthesis Of Reaction-Ready 6,6 '-Biindole And 6,6 '-Biisatin Via Palladium(Ii)-Catalysed Intramolecular C-H Functionalisation, Allan B. Gamble, Paul A. Keller Sep 2013

Synthesis Of Reaction-Ready 6,6 '-Biindole And 6,6 '-Biisatin Via Palladium(Ii)-Catalysed Intramolecular C-H Functionalisation, Allan B. Gamble, Paul A. Keller

Paul Keller

The first synthesis of a 6,6'-biindole and 6,6'-biisatin scaffold is reported with the penultimate step being the formation of the di-heterocyclic ring by Pd(II)-catalysed intramolecular C-H functionalisation and Sandmeyer cyclisation, respectively.


Enhancement Of The Refrigerant Capacity In Low Level Boron Doped La0.8gd0.2fe11.4si1.6, P Shamba, R Zeng, Jianli Wang, S J. Campbell, S X. Dou Jul 2013

Enhancement Of The Refrigerant Capacity In Low Level Boron Doped La0.8gd0.2fe11.4si1.6, P Shamba, R Zeng, Jianli Wang, S J. Campbell, S X. Dou

Jianli Wang

The effects of boron doping on the itinerant-electron metamagnetic (IEM) transition and the magnetocaloric effects (MCEs) in the cubic NaZn13-type La0.8Gd0.2Fe11.4Si1.6 compound have been investigated. The Curie temperature, TC, of La0.8Gd0.2Fe11.4Si1.6Bx compounds with x=0, 0.03, 0.06, 0.2 and 0.3 was found to increase from 200 K to 222 K with increase in boron doping, x. The maximum values of the isothermal magnetic entropy change, ΔSM, (derived using the Maxwell relation for a field change ΔB=0-5 T) in La0.8Gd0.2Fe11.4Si1.6Bx with x=0, 0.03, 0.06, 0.2 and 0.3 are 14.8, 16, 15, 7.5 and 6.6 J kg−1 K−1 respectively, with corresponding values of …


Enhancement Of The Refrigerant Capacity In Low Level Boron Doped La0.8gd0.2fe11.4si1.6, P Shamba, R Zeng, Jianli Wang, S J. Campbell, S X. Dou Jun 2013

Enhancement Of The Refrigerant Capacity In Low Level Boron Doped La0.8gd0.2fe11.4si1.6, P Shamba, R Zeng, Jianli Wang, S J. Campbell, S X. Dou

Shi Xue Dou

The effects of boron doping on the itinerant-electron metamagnetic (IEM) transition and the magnetocaloric effects (MCEs) in the cubic NaZn13-type La0.8Gd0.2Fe11.4Si1.6 compound have been investigated. The Curie temperature, TC, of La0.8Gd0.2Fe11.4Si1.6Bx compounds with x=0, 0.03, 0.06, 0.2 and 0.3 was found to increase from 200 K to 222 K with increase in boron doping, x. The maximum values of the isothermal magnetic entropy change, ΔSM, (derived using the Maxwell relation for a field change ΔB=0-5 T) in La0.8Gd0.2Fe11.4Si1.6Bx with x=0, 0.03, 0.06, 0.2 and 0.3 are 14.8, 16, 15, 7.5 and 6.6 J kg−1 K−1 respectively, with corresponding values of …


Effect Of 6 Weeks' Consumption Of Β-Glucan-Rich Oat Products On Cholesterol Levels In Mildly Hypercholesterolaemic Overweight Adults, Karen E. Charlton, Linda C. Tapsell, Marijka J. Batterham, Jane O'Shea, Rebecca Thorne, Eleanor Beck, Susan M. Tosh Apr 2013

Effect Of 6 Weeks' Consumption Of Β-Glucan-Rich Oat Products On Cholesterol Levels In Mildly Hypercholesterolaemic Overweight Adults, Karen E. Charlton, Linda C. Tapsell, Marijka J. Batterham, Jane O'Shea, Rebecca Thorne, Eleanor Beck, Susan M. Tosh

Karen E. Charlton

Several regulatory bodies have approved a health claim on the cholesterol-lowering effects of oat β-glucan at levels of 3·0 g/d. The present study aimed to test whether 1·5 g/d β-glucan provided as ready-to-eat oat flakes was as effective in lowering cholesterol as 3·0 g/d from oats porridge. A 6-week randomised controlled trial was conducted in eighty-seven mildly hypercholesterolaemic ( ≥ 5 mmol/l and < 7·5 mmol/l) men and women assigned to one of three diet arms (25 % energy (E%) protein; 45 E% carbohydrate; 30 E% fat, at energy requirements for weight maintenance): (1) minimal β-glucan (control); (2) low-dose oat β-glucan …


6-Hydroxy-5,6-Seco-Stemocurtisine: A Novel Seco-Stemocurtisine-Type Alkaloid, Pitchaya Mungkornasawakul, Stephen G. Pyne, Anthony C. Willis, Araya Jatisatienr, Duang Phuthsuk, Wilford Lie Jan 2013

6-Hydroxy-5,6-Seco-Stemocurtisine: A Novel Seco-Stemocurtisine-Type Alkaloid, Pitchaya Mungkornasawakul, Stephen G. Pyne, Anthony C. Willis, Araya Jatisatienr, Duang Phuthsuk, Wilford Lie

Faculty of Science, Medicine and Health - Papers: part A

A novel seco-stemocurtisine-type alkaloid, 6-hydroxy-5,6-seco-stemocurtisine was isolated from the aerial parts of Stemona curtisii (Stemonaceae) collected from Trang Province in Thailand. The unprecedented 5,6-seco-pyrido[1,2-a] azepine structure was elucidated by 2D NMR analysis and a single crystal X-ray crystallographic analysis. (C) 2013 Phytochemical Society of Europe.


Deposition Of Stellite 6 On Nickel Superalloy And Mild Steel Substrates With Laser Cladding, Alain Kusmoko, Druce P. Dunne, Huijun Li, David J. Nolan Jan 2013

Deposition Of Stellite 6 On Nickel Superalloy And Mild Steel Substrates With Laser Cladding, Alain Kusmoko, Druce P. Dunne, Huijun Li, David J. Nolan

Faculty of Engineering and Information Sciences - Papers: Part A

Stellite 6 was deposited by laser cladding of two different steel substrates (nickel superalloy and mild steel). The chemical compositions and microstructures of these coatings were characterized by atomic absorption spectroscopy, optical microscopy and scanning electron microscopy. The microhardness of the coatings was measured and the wear mechanism of the coatings was examined using a pin-on-plate (reciprocating) wear testing machine. The results showed less cracking and pore development for Stellite 6 coatings applied to the mild steel (MS) substrate. Further, the Stellite coating on mild steel was significantly harder than that deposited on the superalloy. The wear test results showed …


Enhancement Of The Refrigerant Capacity In Low Level Boron Doped La0.8gd0.2fe11.4si1.6, P Shamba, R Zeng, Jianli Wang, S J. Campbell, S X. Dou Jan 2013

Enhancement Of The Refrigerant Capacity In Low Level Boron Doped La0.8gd0.2fe11.4si1.6, P Shamba, R Zeng, Jianli Wang, S J. Campbell, S X. Dou

Faculty of Engineering and Information Sciences - Papers: Part A

The effects of boron doping on the itinerant-electron metamagnetic (IEM) transition and the magnetocaloric effects (MCEs) in the cubic NaZn13-type La0.8Gd0.2Fe11.4Si1.6 compound have been investigated. The Curie temperature, TC, of La0.8Gd0.2Fe11.4Si1.6Bx compounds with x=0, 0.03, 0.06, 0.2 and 0.3 was found to increase from 200 K to 222 K with increase in boron doping, x. The maximum values of the isothermal magnetic entropy change, ΔSM, (derived using the Maxwell relation for a field change ΔB=0-5 T) in La0.8Gd0.2Fe11.4Si1.6Bx with x=0, 0.03, 0.06, 0.2 and 0.3 are 14.8, 16, 15, 7.5 and 6.6 J kg−1 K−1 respectively, with corresponding values of …