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Full-Text Articles in Social and Behavioral Sciences
Blast Furnace Hearth Refractory And Coke Ash Mineral Interactions, P B. Drain, M W. Chapman, R J. Nightingale, B J. Monaghan
Blast Furnace Hearth Refractory And Coke Ash Mineral Interactions, P B. Drain, M W. Chapman, R J. Nightingale, B J. Monaghan
Brian Monaghan
In the blast furnace hearth the calcium aluminate by-products of coke dissolution can react with the hearth refractories. Reactions between these coke ash minerals and the aluminosilicate and alumina-carbon hearth refractories may result in increased refractory wear reducing the blast furnace campaign life. Hence improved understanding of these interactions may have implications for the campaign life of the blast furnace hearth refractory materials. The interactions between the coke ash minerals and aluminosilicate hearth refractory have been assessed by heating samples of calcium aluminates (CA, CA2 & CA6) coupled with aluminosilicate refractory to temperatures representative of the blast furnace hearth (1450 …
Thermodynamic Considerations Of The Corrosion Of Nickel Ferrite Refractory By Na3alf6-Alf3-Caf2-Al 2o3 Bath, Raymond Longbottom, Sharon Nightingale, Brian Monaghan
Thermodynamic Considerations Of The Corrosion Of Nickel Ferrite Refractory By Na3alf6-Alf3-Caf2-Al 2o3 Bath, Raymond Longbottom, Sharon Nightingale, Brian Monaghan
Brian Monaghan
Thermodynamic analysis was carried out to interpret the results of corrosion testing of nickel ferrite samples in cryolite-based baths. The equilibrium between cryolite-based baths and nickel ferrite was considered. Isopleths between cryolite-based baths and nickel ferrite confirmed that for the temperature range of interest (1223-1273 K) there was limited solubility of nickel ferrite in the bath. To better understand the formation of the metal from nickel ferrite, the effect of reducing potentials on nickel ferrite and nickel ferrite-cryolite-based bath systems were considered. The formation of a metal phase was predicted at relatively high pO2. The metal phase was nickel-rich at …