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Full-Text Articles in Social and Behavioral Sciences
Isomer-Specific Product Detection Of Cn Radical Reactions With Ethene And Propene By Tunable Vuv Photoionization Mass Spectrometry, Adam Trevitt, Fabien Goulay, Giovanni Meloni, David Osborn, Craig Taatjes, Stephen Leone
Isomer-Specific Product Detection Of Cn Radical Reactions With Ethene And Propene By Tunable Vuv Photoionization Mass Spectrometry, Adam Trevitt, Fabien Goulay, Giovanni Meloni, David Osborn, Craig Taatjes, Stephen Leone
Adam Trevitt
No abstract provided.
Pyrolysis Of Fulvenallene (C7h6) And Fulvenallenyl (C7h5): Theoretical Kinetics And Experimental Product Detection, Adam Trevitt, G Da Silva, M Steinbauer, P Hemberger
Pyrolysis Of Fulvenallene (C7h6) And Fulvenallenyl (C7h5): Theoretical Kinetics And Experimental Product Detection, Adam Trevitt, G Da Silva, M Steinbauer, P Hemberger
Adam Trevitt
Fulvenallene and fulvenallenyl are the respective C7H6 and C7H5 global minima, yet their importance to combustion has only recently emerged. We have studied the pyrolysis of these species theoretically to obtain rate constants and compare our results to pyrolysis mass spectrometry experiments for product identification. Master equation modeling reveals that fulvenallene rapidly dissociates to fulvenallenyl + H, and that fulvenallenyl dissociates to form propargyl plus diacetylene, with lesser amounts of i-C5H3 (CH2CCCCH)/n-C5H3 (CHCCHCCH) plus acetylene. Photoionization mass spectrometry experiments using a pyrolysis source on the fulvenallene precursor phthalide identify products consistent with those proposed theoretically for both fulvenallene and fulvenallenyl …
Reactions Of Small Carbon-Bearing Radicals With Unsaturated Hydrocarbons: Product Detection And Low Temperature Kinetics, Adam Trevitt, Fabien Goulay, Stephen Leone
Reactions Of Small Carbon-Bearing Radicals With Unsaturated Hydrocarbons: Product Detection And Low Temperature Kinetics, Adam Trevitt, Fabien Goulay, Stephen Leone
Adam Trevitt
We report on results from two experimental techniques concerned with the reactions of small carbon based radicals (CN and CH) with unsaturated hydrocarbons. First, low temperature (100-300K) kinetic studies using a pulse Laval nozzle technique probe the reactions of the CN radical with benzene and toluene. The CN + benzene is found to be a fast, barrierless reaction. But in the case of toluene, two reaction pathways are in competition, one of which back dissociates to the reactants. The implications for the atmosphere of Titan are discussed. Product detection studies undertaken at the Advanced Light Source (ALS) using synchrotron coupled …
Ultrasensitive Detection Of Antibodies Using A New Tus-Ter-Lock Immunopcr System, Isabelle Morin, Nicholas E. Dixon, Patrick M. Schaeffer
Ultrasensitive Detection Of Antibodies Using A New Tus-Ter-Lock Immunopcr System, Isabelle Morin, Nicholas E. Dixon, Patrick M. Schaeffer
Professor Nick E Dixon
A system consisting of a protein LG coated surface for the capture of mammalian antibodies (target), and an antigen fused to Tus and stoichiometrically linked to a DNA template via the Tus-Ter-lock sequence allowed the ultrasensitive detection of 5.5 attomol of target by real-time immunoPCR in complex media. © The Royal Society of Chemistry 2010.
Fabrication Of Polyaniline-Based Gas Sensors Using Piezoelectric Inkjet And Screen Printing For The Detection Of Hydrogen Sulfide, Karl H. Crowley, Aoife Morrin, Roderick L. Shepherd, Marc In Het Panhuis, Gordon G. Wallace, Malcolm R. Smyth, Anthony J. Killard
Fabrication Of Polyaniline-Based Gas Sensors Using Piezoelectric Inkjet And Screen Printing For The Detection Of Hydrogen Sulfide, Karl H. Crowley, Aoife Morrin, Roderick L. Shepherd, Marc In Het Panhuis, Gordon G. Wallace, Malcolm R. Smyth, Anthony J. Killard
Gordon Wallace
This work describes a fully printable polyaniline-copper (II) chloride sensor for the detection of hydrogen sulfide gas. The sensing device is composed of screen printed silver interdigitated electrode (IDE) on a flexible PET substrate with inkjet printed layers of polyaniline and copper (II) chloride. The sensor is employed as a chemiresistor with changes in measured current being correlated with concentration. On exposure to hydrogen sulfide, 2.5 ppmv (parts per million by volume) is clearly detectable with a linear relationship between measured current and concentration over the 10-100 ppmv region. The detection mechanism is discussed with respect to the hydrogen sulfide …
Fabrication Of Chemical Sensors Using Inkjet Printing And Application To Gas Detection, Karl H. Crowley, Aoife Morrin, Malcolm R. Smyth, Anthony J. Killard, Roderick Shepherd, Marc In Het Panhuis, Gordon G. Wallace
Fabrication Of Chemical Sensors Using Inkjet Printing And Application To Gas Detection, Karl H. Crowley, Aoife Morrin, Malcolm R. Smyth, Anthony J. Killard, Roderick Shepherd, Marc In Het Panhuis, Gordon G. Wallace
Gordon Wallace
This work describes the fabrication of gas sensors using inkjet printing. Sensors were constructed by building up a film of sensing material, such as polyaniline, from aqueous nanoparticulate dispersions. These films were printed over patterned silver interdigitated array designs for the purposes of conductimetric analysis. Unlike screen printing or lithography, inkjet printing does not require stencils or masks, therefore allowing rapid design and prototyping. For this study, polyaniline and modified polyaniline sensors were inkjet printed and assessed for the purposes of gas sensing applications, specifically hydrogen sulfide monitoring.
Direct Ascorbic Acid Detection With Ferritin Immobilized On Single-Walled Carbon Nanotubes, Chonlada Dechakiatkrai, Jun Chen, Carol M. Lynam, Kwang Min Shin, Seon Jeong Kim, Sukon Phanichphant, Gordon G. Wallace
Direct Ascorbic Acid Detection With Ferritin Immobilized On Single-Walled Carbon Nanotubes, Chonlada Dechakiatkrai, Jun Chen, Carol M. Lynam, Kwang Min Shin, Seon Jeong Kim, Sukon Phanichphant, Gordon G. Wallace
Gordon Wallace
Ferritin protein was noncovalently immobilized onto single-walled carbon nanotubes (SWNTs). This SWNT/ferritin composite was characterized using cyclic voltammetry, UV-visible spectroscopy, Raman spectroscopy, and high-resolution transmission electron microscopy. The use of the SWNT/ferritin film as an amperometric biosensor was demonstrated by sensing ascorbic acid in phosphate-buffered saline solution with a sensitivity of 767 uAmg. It demonstrated that ferritin protein bound to SWNTs enhances the oxidation reaction of ascorbic acid over 11-fold.
The Detection Of Malingered Psychopathology And Cognitive Deficits: Employing The Fake Bad Scale And The Raven's Standard Progressive Matricies, Mitchell Byrne, Peter Golus, Steven Sellers
The Detection Of Malingered Psychopathology And Cognitive Deficits: Employing The Fake Bad Scale And The Raven's Standard Progressive Matricies, Mitchell Byrne, Peter Golus, Steven Sellers
Mitchell K Byrne
No abstract provided.
Direct Detection Of Additives And Degradation Products From Polymers By Liquid Extraction Surface Analysis Employing Chip-Based Nanospray Mass Spectrometry, Martin Paine, Phillip Barker, Shane A. Maclaughlin, Todd W. Mitchell, Stephen J. Blanksby
Direct Detection Of Additives And Degradation Products From Polymers By Liquid Extraction Surface Analysis Employing Chip-Based Nanospray Mass Spectrometry, Martin Paine, Phillip Barker, Shane A. Maclaughlin, Todd W. Mitchell, Stephen J. Blanksby
Stephen Blanksby
Rationale: Polymer-based surface coatings in outdoor applications experience accelerated degradation due to exposure to solar radiation, oxygen and atmospheric pollutants. These deleterious agents cause undesirable changes to the polymers aesthetic and mechanical properties reducing its lifetime. The use of antioxidants such as hindered amine light stabilisers (HALS) retard these degradative processes, however, mechanisms for HALS action and polymer degradation are poorly understood. Methods: Detection of the hindered amine light stabiliser (HALS) TINUVIN®123 (bis (1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate) and the polymer degradation products directly from a polyester-based coil coating was achieved by liquid extraction surface analysis (LESA) coupled to a triple quadrupole QTRAP® …
Preliminary Investigations Of Pigment Responses To Phylloxera Infestation, A L. Blanchfield, K S. Powell, Sharon A. Robinson
Preliminary Investigations Of Pigment Responses To Phylloxera Infestation, A L. Blanchfield, K S. Powell, Sharon A. Robinson
Sharon Robinson
Early detection of grape phylloxera (Daktulosphaira vitifoliae) infestation is vital for the implementation of post-outbreak quarantine in Australia. Remote sensing systems exploit changes in leaf pigment content associated with plant stress and offer a real possibility of a phylloxera-specific detection system. Pre-visual, symptomatic changes in the pigment content of phylloxera-infested grapevine leaves were investigated using high performance liquid chromatography (HPLC) as a potential aid to improve current phylloxera detection methods. A glasshouse trial was established to characterize the response of two grapevine varieties, Vitis vinifera ‘Cabernet Sauvignon’ and ‘Shiraz’, to phylloxera infestation, in a controlled environment. Field trials were conducted …
Reaction Of The C2h Radical With 1-Butyne (C4h6): Low Temperature Kinetics And Isomer-Specific Product Detection, Satchin Soorkia, Adam J. Trevitt, Talitha M. Selby, David L. Osborn, Craig A. Taatjes, Kevin R. Wilson, Stephen R. Leone
Reaction Of The C2h Radical With 1-Butyne (C4h6): Low Temperature Kinetics And Isomer-Specific Product Detection, Satchin Soorkia, Adam J. Trevitt, Talitha M. Selby, David L. Osborn, Craig A. Taatjes, Kevin R. Wilson, Stephen R. Leone
Adam Trevitt
No abstract provided.
Reactions Of The Cn Radical With Benzene And Toluene: Product Detection And Low-Temperature Kinetics, Adam J. Trevitt, Fabien Goulay, Craig A. Taatjes, David L. Osborn, Stephen R. Leone
Reactions Of The Cn Radical With Benzene And Toluene: Product Detection And Low-Temperature Kinetics, Adam J. Trevitt, Fabien Goulay, Craig A. Taatjes, David L. Osborn, Stephen R. Leone
Adam Trevitt
Low-temperature rate coefficients are measured for the CN + benzene and CN + toluene reactions using the pulsed Laval nozzle expansion technique coupled with laser-induced fluorescence detection. The CN + benzene reaction rate coefficient at 105, 165, and 295 K is found to be relatively constant over this temperature range, (3.9−4.9) × 10−10 cm3 molecule−1 s−1. These rapid kinetics, along with the observed negligible temperature dependence, are consistent with a barrierless reaction entrance channel and reaction efficiencies approaching unity. The CN + toluene reaction is measured to have a rate coefficient of 1.3 × 10−10 cm3 molecule−1 s−1 at 105 …
Direct Detection Of Additives And Degradation Products From Polymers By Liquid Extraction Surface Analysis Employing Chip-Based Nanospray Mass Spectrometry, Martin Paine, Phillip Barker, Shane A. Maclaughlin, Todd W. Mitchell, Stephen J. Blanksby
Direct Detection Of Additives And Degradation Products From Polymers By Liquid Extraction Surface Analysis Employing Chip-Based Nanospray Mass Spectrometry, Martin Paine, Phillip Barker, Shane A. Maclaughlin, Todd W. Mitchell, Stephen J. Blanksby
Faculty of Science - Papers (Archive)
Rationale: Polymer-based surface coatings in outdoor applications experience accelerated degradation due to exposure to solar radiation, oxygen and atmospheric pollutants. These deleterious agents cause undesirable changes to the polymers aesthetic and mechanical properties reducing its lifetime. The use of antioxidants such as hindered amine light stabilisers (HALS) retard these degradative processes, however, mechanisms for HALS action and polymer degradation are poorly understood. Methods: Detection of the hindered amine light stabiliser (HALS) TINUVIN®123 (bis (1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate) and the polymer degradation products directly from a polyester-based coil coating was achieved by liquid extraction surface analysis (LESA) coupled to a triple quadrupole QTRAP® …
The Thioflavin T Fluorescence Assay For Amyloid Fibril Detection Can Be Biased By The Presence Of Exogenous Compounds, Sean A. Hudson, Heath Ecroyd, Tak W. Kee, John A. Carver
The Thioflavin T Fluorescence Assay For Amyloid Fibril Detection Can Be Biased By The Presence Of Exogenous Compounds, Sean A. Hudson, Heath Ecroyd, Tak W. Kee, John A. Carver
Heath Ecroyd
Thioflavin T (ThT) dye fluorescence is used regularly to quantify the formation and inhibition of amyloid fibrils in the presence of anti-amyloidogenic compounds such as polyphenols. However, in this study, it was shown, using three polyphenolics (curcumin, quercetin and resveratrol), that ThT fluorescence should be used with caution in the presence of such exogenous compounds. The strong absorptive and fluorescent properties of quercetin and curcumin were found to significantly bias the ThT fluorescence readings in both in situ real-time ThT assays and single time-point dilution ThT-type assays. The presence of curcumin at concentrations as low as 0.01 and 1 uM …
Detection And Quantification Of Tear Phospholipids And Cholesterol In Contact Lens Deposits: The Effect Of Contact Lens Material And Lens Care Solution, Jennifer Saville, Zhenjun Zhao, Mark D.P. Willcox, Stephen J. Blanksby, Todd W. Mitchell
Detection And Quantification Of Tear Phospholipids And Cholesterol In Contact Lens Deposits: The Effect Of Contact Lens Material And Lens Care Solution, Jennifer Saville, Zhenjun Zhao, Mark D.P. Willcox, Stephen J. Blanksby, Todd W. Mitchell
Stephen Blanksby
PURPOSE. To examine the deposition of tear phospholipids and cholesterol onto worn contact lenses and the effect of lens material and lens care solution. METHODS. Lipids were extracted from tears and worn contact lenses using 2: 1 chloroform: methanol and the extract washed with aqueous ammonium acetate, before analysis by electrospray ionization tandem mass spectrometry (ESI-MS/MS). RESULTS. Twenty-three molecular lipids from the sphingomyelin (SM) and phosphatidylcholine (PC) classes were detected in tears, with total concentrations of each class determined to be 5 +/- 1 pmol/mu L (similar to 3.8 mu g/mL) and 6 +/- 1 pmol/mu L (similar to 4.6 …
Reaction Of The C2h Radical With 1-Butyne (C4h6): Low Temperature Kinetics And Isomer-Specific Product Detection, Satchin Soorkia, Adam J. Trevitt, Talitha M. Selby, David L. Osborn, Craig A. Taatjes, Kevin R. Wilson, Stephen R. Leone
Reaction Of The C2h Radical With 1-Butyne (C4h6): Low Temperature Kinetics And Isomer-Specific Product Detection, Satchin Soorkia, Adam J. Trevitt, Talitha M. Selby, David L. Osborn, Craig A. Taatjes, Kevin R. Wilson, Stephen R. Leone
Faculty of Science - Papers (Archive)
No abstract provided.
Detection And Quantification Of Tear Phospholipids And Cholesterol In Contact Lens Deposits: The Effect Of Contact Lens Material And Lens Care Solution, Jennifer Saville, Zhenjun Zhao, Mark D.P. Willcox, Stephen J. Blanksby, Todd W. Mitchell
Detection And Quantification Of Tear Phospholipids And Cholesterol In Contact Lens Deposits: The Effect Of Contact Lens Material And Lens Care Solution, Jennifer Saville, Zhenjun Zhao, Mark D.P. Willcox, Stephen J. Blanksby, Todd W. Mitchell
Faculty of Science - Papers (Archive)
PURPOSE. To examine the deposition of tear phospholipids and cholesterol onto worn contact lenses and the effect of lens material and lens care solution. METHODS. Lipids were extracted from tears and worn contact lenses using 2: 1 chloroform: methanol and the extract washed with aqueous ammonium acetate, before analysis by electrospray ionization tandem mass spectrometry (ESI-MS/MS). RESULTS. Twenty-three molecular lipids from the sphingomyelin (SM) and phosphatidylcholine (PC) classes were detected in tears, with total concentrations of each class determined to be 5 +/- 1 pmol/mu L (similar to 3.8 mu g/mL) and 6 +/- 1 pmol/mu L (similar to 4.6 …
Reactions Of The Cn Radical With Benzene And Toluene: Product Detection And Low-Temperature Kinetics, Adam J. Trevitt, Fabien Goulay, Craig A. Taatjes, David L. Osborn, Stephen R. Leone
Reactions Of The Cn Radical With Benzene And Toluene: Product Detection And Low-Temperature Kinetics, Adam J. Trevitt, Fabien Goulay, Craig A. Taatjes, David L. Osborn, Stephen R. Leone
Faculty of Science - Papers (Archive)
Low-temperature rate coefficients are measured for the CN + benzene and CN + toluene reactions using the pulsed Laval nozzle expansion technique coupled with laser-induced fluorescence detection. The CN + benzene reaction rate coefficient at 105, 165, and 295 K is found to be relatively constant over this temperature range, (3.9−4.9) × 10−10 cm3 molecule−1 s−1. These rapid kinetics, along with the observed negligible temperature dependence, are consistent with a barrierless reaction entrance channel and reaction efficiencies approaching unity. The CN + toluene reaction is measured to have a rate coefficient of 1.3 × 10−10 cm3 molecule−1 s−1 at 105 …
Ultrasensitive Detection Of Antibodies Using A New Tus-Ter-Lock Immunopcr System, Isabelle Morin, Nicholas E. Dixon, Patrick M. Schaeffer
Ultrasensitive Detection Of Antibodies Using A New Tus-Ter-Lock Immunopcr System, Isabelle Morin, Nicholas E. Dixon, Patrick M. Schaeffer
Faculty of Science - Papers (Archive)
A system consisting of a protein LG coated surface for the capture of mammalian antibodies (target), and an antigen fused to Tus and stoichiometrically linked to a DNA template via the Tus-Ter-lock sequence allowed the ultrasensitive detection of 5.5 attomol of target by real-time immunoPCR in complex media. © The Royal Society of Chemistry 2010.
Fabrication Of Polyaniline-Based Gas Sensors Using Piezoelectric Inkjet And Screen Printing For The Detection Of Hydrogen Sulfide, Karl H. Crowley, Aoife Morrin, Roderick L. Shepherd, Marc In Het Panhuis, Gordon G. Wallace, Malcolm R. Smyth, Anthony J. Killard
Fabrication Of Polyaniline-Based Gas Sensors Using Piezoelectric Inkjet And Screen Printing For The Detection Of Hydrogen Sulfide, Karl H. Crowley, Aoife Morrin, Roderick L. Shepherd, Marc In Het Panhuis, Gordon G. Wallace, Malcolm R. Smyth, Anthony J. Killard
Faculty of Science - Papers (Archive)
This work describes a fully printable polyaniline-copper (II) chloride sensor for the detection of hydrogen sulfide gas. The sensing device is composed of screen printed silver interdigitated electrode (IDE) on a flexible PET substrate with inkjet printed layers of polyaniline and copper (II) chloride. The sensor is employed as a chemiresistor with changes in measured current being correlated with concentration. On exposure to hydrogen sulfide, 2.5 ppmv (parts per million by volume) is clearly detectable with a linear relationship between measured current and concentration over the 10-100 ppmv region. The detection mechanism is discussed with respect to the hydrogen sulfide …
The Utility Of Different Object Properties In Change Detection, Simone K. Favelle, Stephen A. Palmisano
The Utility Of Different Object Properties In Change Detection, Simone K. Favelle, Stephen A. Palmisano
Faculty of Health and Behavioural Sciences - Papers (Archive)
Previous research has shown that changes to the configuration of an object's parts are better detected than changes to the shape/arrangement of those parts. This finding suggests that configural, rather than shape, information plays a critical role in object change detection. The current study investigated configural and shape changes in greater detail to determine what aspects of these two types of object properties, if any, were more or less important for change detection. Specifically we investigated configural changes in terms of the orientation of the part change and shape changes in terms of the non-accidental properties of the part change. …
The Thioflavin T Fluorescence Assay For Amyloid Fibril Detection Can Be Biased By The Presence Of Exogenous Compounds, Sean A. Hudson, Heath Ecroyd, Tak W. Kee, John A. Carver
The Thioflavin T Fluorescence Assay For Amyloid Fibril Detection Can Be Biased By The Presence Of Exogenous Compounds, Sean A. Hudson, Heath Ecroyd, Tak W. Kee, John A. Carver
Faculty of Science - Papers (Archive)
Thioflavin T (ThT) dye fluorescence is used regularly to quantify the formation and inhibition of amyloid fibrils in the presence of anti-amyloidogenic compounds such as polyphenols. However, in this study, it was shown, using three polyphenolics (curcumin, quercetin and resveratrol), that ThT fluorescence should be used with caution in the presence of such exogenous compounds. The strong absorptive and fluorescent properties of quercetin and curcumin were found to significantly bias the ThT fluorescence readings in both in situ real-time ThT assays and single time-point dilution ThT-type assays. The presence of curcumin at concentrations as low as 0.01 and 1 uM …
Direct Ascorbic Acid Detection With Ferritin Immobilized On Single-Walled Carbon Nanotubes, Chonlada Dechakiatkrai, Jun Chen, Carol M. Lynam, Kwang Min Shin, Seon Jeong Kim, Sukon Phanichphant, Gordon G. Wallace
Direct Ascorbic Acid Detection With Ferritin Immobilized On Single-Walled Carbon Nanotubes, Chonlada Dechakiatkrai, Jun Chen, Carol M. Lynam, Kwang Min Shin, Seon Jeong Kim, Sukon Phanichphant, Gordon G. Wallace
Faculty of Science - Papers (Archive)
Ferritin protein was noncovalently immobilized onto single-walled carbon nanotubes (SWNTs). This SWNT/ferritin composite was characterized using cyclic voltammetry, UV-visible spectroscopy, Raman spectroscopy, and high-resolution transmission electron microscopy. The use of the SWNT/ferritin film as an amperometric biosensor was demonstrated by sensing ascorbic acid in phosphate-buffered saline solution with a sensitivity of 767 uAmg. It demonstrated that ferritin protein bound to SWNTs enhances the oxidation reaction of ascorbic acid over 11-fold.
Fabrication Of Chemical Sensors Using Inkjet Printing And Application To Gas Detection, Karl H. Crowley, Aoife Morrin, Malcolm R. Smyth, Anthony J. Killard, Roderick Shepherd, Marc In Het Panhuis, Gordon G. Wallace
Fabrication Of Chemical Sensors Using Inkjet Printing And Application To Gas Detection, Karl H. Crowley, Aoife Morrin, Malcolm R. Smyth, Anthony J. Killard, Roderick Shepherd, Marc In Het Panhuis, Gordon G. Wallace
Faculty of Science - Papers (Archive)
This work describes the fabrication of gas sensors using inkjet printing. Sensors were constructed by building up a film of sensing material, such as polyaniline, from aqueous nanoparticulate dispersions. These films were printed over patterned silver interdigitated array designs for the purposes of conductimetric analysis. Unlike screen printing or lithography, inkjet printing does not require stencils or masks, therefore allowing rapid design and prototyping. For this study, polyaniline and modified polyaniline sensors were inkjet printed and assessed for the purposes of gas sensing applications, specifically hydrogen sulfide monitoring.
Attention To Configural Information In Change Detection For Faces, Simone K. Favelle, Darren Burke
Attention To Configural Information In Change Detection For Faces, Simone K. Favelle, Darren Burke
Faculty of Health and Behavioural Sciences - Papers (Archive)
In recent research the change-detection paradigm has been used along with cueing manipulations to show that more attention is allocated to the upper than lower facial region, and that this attentional allocation is disrupted by inversion. We report two experiments the object of which was to investigate how the type of information changed might be a factor in these findings by explicitly comparing the role of attention in detecting change to information thought to be special to faces (second-order relations) with information that is more useful for basic-level object discrimination (first-order relations). Results suggest that attention is automatically directed to …
Detection Of Al(Iii) And Ga(Iii) Complexes With Morin By Electrospray Ionization Mass Spectrometry, John B. Bremner, Larry A. Hick, Jody Morgan, Saowanee Rattanaphani, Vichitr Rattanaphani, C Septhum
Detection Of Al(Iii) And Ga(Iii) Complexes With Morin By Electrospray Ionization Mass Spectrometry, John B. Bremner, Larry A. Hick, Jody Morgan, Saowanee Rattanaphani, Vichitr Rattanaphani, C Septhum
Faculty of Science - Papers (Archive)
The Al(III) and Ga(III) complexes formed by morin (M) in aqueous solution were investigated by means of electrospray ionization mass spectrometry (ESI-MS). In the full scan mass spectra, Al:M showed 1:2 and 2:3 stoichiometric ratios. When (S)-N-acetylserine methyl ester (Ser), as a partial mimic of the serine residue in silk, was added to Al:M and Ga:M complexes in aqueous solution, the mass spectra of Ser:Al:M showed 1:1:1 and 1:1:2 stoichiometric ratios. The patterns of the mass spectra of Ga:M and Ser:Ga:M complexes were similar to those for the corresponding Al(III) complexes. Calculated heats of formation of potential structures of the …
Preliminary Investigations Of Pigment Responses To Phylloxera Infestation, A L. Blanchfield, K S. Powell, Sharon A. Robinson
Preliminary Investigations Of Pigment Responses To Phylloxera Infestation, A L. Blanchfield, K S. Powell, Sharon A. Robinson
Faculty of Science - Papers (Archive)
Early detection of grape phylloxera (Daktulosphaira vitifoliae) infestation is vital for the implementation of post-outbreak quarantine in Australia. Remote sensing systems exploit changes in leaf pigment content associated with plant stress and offer a real possibility of a phylloxera-specific detection system. Pre-visual, symptomatic changes in the pigment content of phylloxera-infested grapevine leaves were investigated using high performance liquid chromatography (HPLC) as a potential aid to improve current phylloxera detection methods. A glasshouse trial was established to characterize the response of two grapevine varieties, Vitis vinifera ‘Cabernet Sauvignon’ and ‘Shiraz’, to phylloxera infestation, in a controlled environment. Field trials …
The Configural Advantage In Object Change Detection Persists Across Depth Rotation, Simone K. Favelle, Stephen Palmisano, Darren Burke, William G. Hayward
The Configural Advantage In Object Change Detection Persists Across Depth Rotation, Simone K. Favelle, Stephen Palmisano, Darren Burke, William G. Hayward
Faculty of Health and Behavioural Sciences - Papers (Archive)
Although traditionally there has been a debate over whether object recognition involves 3-D structural descriptions or 2-D views, most current approaches to object recognition include the representation of object structure in some form. An advantage for the processing of structural or configural information in objects has been recently demonstrated using a change detection task (Keane, Hayward, & Burke, 2003). We report two experiments that extend this finding and show that configural information dominates change detection performance regardless of an object's orientation. Experiment 1 demonstrated the advantage that configural information has over shape and part arrangement information in change detection across …
Detection Of Moisture Stress In Eucalyptus Camaldulensis Using Leaf-Level Spectral Reflectance: Implications For Remote Sensing, Laurie A. Chisholm
Detection Of Moisture Stress In Eucalyptus Camaldulensis Using Leaf-Level Spectral Reflectance: Implications For Remote Sensing, Laurie A. Chisholm
Faculty of Science - Papers (Archive)
Foliage moisture stress may be detectable by remote sensing using high resolution spectral data, but meaningful diagnosis requires that plant water status be assessed on the ground under controlled conditions. Design parameters of an experimental plantation of E. camaldulensis (River red gum), were used to examine tree-level responses to moisture stress, as measured by xylem water potential, and relationships to physiological parameters including spectral reflectance, chlorophyll flurescence, and cholorphyll across a range of stress categories.
First Detection Of Meso-Thermospheric Nitric Oxide (No) By Ground-Based Ftir Solar Absorption Spectroscopy, Aldona Wiacek, Nicholas B. Jones, K Strong, J R. Taylor, Richard L. Mittermeier, Hans Fast
First Detection Of Meso-Thermospheric Nitric Oxide (No) By Ground-Based Ftir Solar Absorption Spectroscopy, Aldona Wiacek, Nicholas B. Jones, K Strong, J R. Taylor, Richard L. Mittermeier, Hans Fast
Faculty of Science - Papers (Archive)
We report the first detection of mesospheric-lower thermospheric (MLT, 50–130 km) NO from ground-based FTIR solar absorption spectra using Lorentz- and Doppler-broadened solar absorption lines in the stratosphere and in the MLT, respectively. We present the first characterization of vertical sensitivity in the FTIR NO retrieval and show that MLT NO partial columns can be retrieved with ~1 independent piece of information using a climatological NO profile extending up to 130 km. The information content analysis also improves the characterization of stratospheric partial column retrievals and is relevant to NO results obtained at other Network for the Detection of Stratospheric …