Water Resource Management Commons^™

Inconsistencies Emerge Between Regional And Local-Scale Water Security Metrics At Military Installations, Abigail Birnbaum, Michael L. Berg, Caitlin Grady, Daniel J. Weeks, Christopher M. Chini

Faculty Publications

Recent United States federal policy for military installations has emphasized the importance of developing a standardized approach for water security assessment to monitor changes in water resources and the ability for an installation to meet both its civilian and mission needs. For military installations in the United States, these assessments must consider demands both inside and outside the installation’s fence line, as regional resources are required to meet mission readiness. Focusing on physical water scarcity, this study compares four water security metrics with unique formulations and spatial resolutions, including an installation-scale metric and multiple regional metrics defined for either baseline …

Assessing The Feasibility Of Managed Aquifer Recharge For The United States Air Force, Daniel Hendrix

Theses and Dissertations

Water stress is becoming an increasing global issue, with 4 billion people (50% of the world’s population) experiencing water stress at least one month per year. By 2050, 60% of the world’s population and $70 trillion USD in global gross domestic product will be affected. This research analyzes 78 CONUS USAF installations to determine location-specific water stress and feasible Managed Aquifer Recharge (MAR) solutions. Although thousands of MAR projects have been implemented globally, active-duty USAF installations have yet to contribute to solving this growing issue. Important factors such as required subsurface conditions, physical limitations, design, cost, and regulatory constraints are …

Atmospheric Water Generation: Experimental Observations And Assembly Of An Artificial Neural Network, Houston Hoss Anderson

Theses and Dissertations

This research investigated the performance of a Tsunami T50 Vapor Compression Cycle styled Atmospheric Water Generation (AWG) machine operated under ambient conditions in Dayton, Ohio. Water yield from the device was measured volumetrically and these values are paired with respective weather data, collected from a local monitoring station, to build an Artificial Neural Network in MATLAB and JMP software. Water yield varied over the course of this study but averaged 1.2L and maxed at 5L for 4-hour operating periods. This work is part of a 3-year project; future data is needed to enhance both training and validation of the model …

Evaluating Atmospheric Water Generation For The Indo-Pacific: Predictive Modeling, Energy Considerations, And Regional Viability, Jose I. De La Serna

Theses and Dissertations

Atmospheric Water Generator (AWG) technology presents a promising solution for extracting and harvesting water from ambient air through condensation methods. This innovative approach offers a viable alternative for water production in regions with limited or unreliable water sources. AWGs operate most effectively in hot and humid environments, typically at temperatures of 80°F and relative humidity levels of 80%. As of 2020, the Department of Defense (DoD) has identified the Indo-Pacific region as a strategic focus for addressing future greatpower competition. Within the framework of Agile Combat Employment, this study evaluates the feasibility and performance of AWG technology at pre-determined locations …

Atmospheric Water Generation: Bacterial And Inorganic Chemical Quality, Garrett E. Stanley

Theses and Dissertations

This study investigated the quality of untreated water collected from a vapor compression-based atmospheric water generator (AWG) operated outdoors in Dayton, Ohio. The concentrations of bacterial and chemical constituents were determined. The concentration of culturable bacteria was between 200 and 2300 CFU/mL, significantly higher than the reference levels described in recreational and drinking water quality guidance. Three discrete bacteria phenotypes were visually identified; two were yellow in color, rod-shaped and gram-negative while the third was milky white, circular, and gram-positive. Chemical analysis on 15 randomly selected samples revealed the presence of Barium (average = 0.16 mg/L), Magnesium (0.08 = mg/L), …

Seasonal Variability And Predictability Of Monsoon Precipitation In Southern Africa, Matthew F. Horan, Fred Kucharski, Moetasim Ashfaq

Faculty Publications

Rainfed agriculture is the mainstay of economies across Southern Africa (SA), where most precipitation is received during the austral summer monsoon. This study aims to further our understanding of monsoon precipitation predictability over SA. We use three natural climate forcings, El Niño–Southern Oscillation, Indian Ocean Dipole (IOD), and the Indian Ocean Precipitation Dipole (IOPD)—the dominant precipitation variability mode—to construct an empirical model that exhibits significant skill over SA during monsoon in explaining precipitation variability and in forecasting it with a five-month lead. While most explained precipitation variance (50%–75%) comes from contemporaneous IOD and IOPD, preconditioning all three forcings is key …

Advanced Oxidation Of Methyl Tert Butyl Ether With Ultraviolet Light Emitting Diodes, Aaron R. Neal

Theses and Dissertations

Methyl Tert-Butyl Ether (MTBE) is a volatile, soluble, organic compound introduced to gasoline within the United States as a fuel oxygenator in 1979. MTBE is a common groundwater pollutant due to its high water solubility and resistance to bio-degradation; it commonly infiltrates groundwater sources via leaking underground storage tanks or fuel spills. This research employed ultraviolet light emitting diodes (UV-LEDs) and hydrogen peroxide (H₂O₂) induced advanced oxidation process (AOP) to treat MTBE contaminated water at the bench scale. Using four H₂O₂:MTBE molar peroxide ratios (100:1, 200:1, 400:1, 500:1), MTBE degradation was induced …

Temporal And Spatial Variability Of Specific Energy Consumption For Atmospheric Water Generators, Anthony T. Brenes

Theses and Dissertations

Atmospheric Water Generators (AWG) produce potable water from the moisture in the air, providing a potentially viable water source in austere locations or emergency response scenarios. In this study, the operating constraints of three existing commercially available AWG devices are investigated, compared to historical weather data from across the continental United States. Utilizing linear regression modeling and weather station data for the years of 1985-2019, the monthly and spatial trends of energy demand to produce water from these devices are evaluated. Energy and water production efficiencies for the devices are highly dependent on environmental conditions with relative humidity and temperature …

Net Zero Water Air Force Installations, Kenneth R. Mcknight

Theses and Dissertations

The United States continues to face problems of a reduction in quality and quantity of groundwater sources because water extraction exceeds natural source recharge. The Air Force has recognized the importance of these groundwater sources but has put minimal effort into determining their contribution to the depletion of these sources. The purpose of this study is to determine this contribution by determining whether Air Force installations are net zero water. This is done using a geospatial information system to determine the volume of water recharging groundwater sources associated with an Air Force installation. This volume is then compared to the …

The Impacts Of Climate Uncertainty On Streamflow In Andes, Antioquia, Colombia, Kristen R. Roberts

Theses and Dissertations

Natural hazards, such as hurricanes, wildfires, floods, and droughts impact human systems that rely on predictable patterns in the natural elements with which they interact. Skillful prediction of the impacts of climate change on linked, human-natural systems, like surface water resources, can help ensure physical risks within vulnerable communities are mitigated, resource sustainability is maximized, and intersectoral markets continue to contribute to socioeconomic stability. Due to water resources being a primary conduit through which climate uncertainty impacts people, economies, and ecosystems, its study is worthy of investigation; particularly, where those resources are uncertain and demanded by a variety of competitive …

Efficiency Mapping And Determination Of Reliability, Resiliency And Vulnerability Of Atmospheric Water Generators In The United States, Erica F. Sadowski

Theses and Dissertations

Atmospheric Water Generators (AWG) extract water from the air using one of three available technologies: refrigeration, sorption, and fog harvesting. A refrigeration device works like a dehumidifier and works best in conditions above 60% relative humidity. A sorption device utilizes a desiccant to extract the water vapor from the air and works in very low humidity levels. A fog harvesting device utilizes a mesh to capture the water vapor from the air and requires 100% relative humidity. In this research, I analyze two refrigeration-based devices and one sorption-based device and their efficacy in providing supplemental water supply. Due to climatological …

Water Security At United States Air Force Installations, John D. Pollock

Theses and Dissertations

Global water security is a growing concern that poses unique challenges that stem from geopolitical arrangement, regional location, and local climate conditions. United States national defense relies on an uninterrupted water supply to sustain operations to carry out its readiness mission. Accurate water security assessments are necessary for adapting to climate factors and to provide essential information to meet the changing needs of human water demand. This research presents how different water metrics are applied at various United States Air Force locations to measure water scarcity. Geographical Information Systems (GIS) software is used to conduct spatial correlation across the United …

Evaluation Of Efficient Water Reuse Technologies For Sustainable Forward Operating Bases, Kelsie L. Crouch

Theses and Dissertations

A secure water source is essential to the resiliency and readiness of military installations and contingency operation locations, especially those located in the dry climates the US military operates in today. There are multiple issues of concern when identifying water sources, such as security, cleanliness, accessibility, and sustainability. Water resources pose a potential vulnerability to mission readiness in a remote, agile environment, such as a forward operating base (FOB). Having a secure water resource helps facilitate mission readiness in the contingency environment, offering the opportunity to be more resilient and cost-effective. Current water treatment technologies present the possibility to perform …

The Traded Water Footprint Of Global Energy From 2010 To 2018, Christopher M. Chini, Rebecca A. M. Peer

Faculty Publications

The energy-water nexus describes the requirement of water-for-energy and energy-for-water. The consumption of water in the production and generation of energy resources is also deemed virtual water. Pairing the virtual water estimates for energy with international trade data creates a virtual water trade network, facilitating analysis of global water resources management. In this database, we identify the virtual water footprints for the trade of eleven different energy commodities including fossil fuels, biomass, and electricity. Additionally, we provide the necessary scripts for downloading and pairing trade data with the virtual water footprints to create a virtual water trade network. The resulting …

Virus Adsorption To Colloids In Water: Interactions Between Bacteriophage Ms2, Kaolinite, And Fiberglass, Ashlee N. Ellis

Theses and Dissertations

Virus adsorption to colloidal particles is an important issue in the water quality community, and it is a particularly important issue for conventional wastewater treatment plants that accept biohazardous waste. Colloids impact the transport of viruses in engineered treatment systems, and they also provide protection against oxidants and other destructive mechanisms. This study evaluated the adsorption of bacteriophage MS2 to colloidal suspensions of kaolinite (KAO) and fiberglass (FG). A series of laboratory batch tests were carried out over a range of experimental conditions to determine kinetic rate constants and characterize bond strength, and computational experiments were done to assess both …

Removal Of Perfluorinated Compounds From Post-Emergency Wastewater By Advanced Oxidation Process And Granular Activated Carbon Adsorption, Sean M. Dyson

Theses and Dissertations

This research presents a novel approach to remove per- and polyfluoroalkyl substances (PFAS) from aqueous film-forming foam (AFFF) impacted wastewater with high (~100 mg/L) total organic carbon (TOC) concentrations. A treatment-train process was investigated involving an ultraviolet (UV)/hydrogen peroxide (H2O2) advanced oxidation process (AOP) followed by filtration using Calgon Filtrasorb® 600 (F600) granular activated carbon (GAC). UV/H₂O₂ AOP experiments were conducted to determine whether TOC concentrations could be reduced as a pre-treatment step before filtering the water with F600-GAC. Results showed using UV/H₂O₂ AOP reduced TOC in solution by > 98% (< 2 mg/L down from 99.1 mg/L). Reducing TOC concentrations was achieved by using a 250 mg/L H₂O_{2 …}

Application Of Ultraviolet Light Emitting Diodes For The Advanced Oxidation Of Guar Gum, Andrew W. Davenport

Theses and Dissertations

Guar Gum (GG) is one of the problematic water pollutants connected to hydraulic fracturing. There is a pressing need to investigate appropriate unit operations that can be employed to protect the aquatic environment. This study investigated the use of light-emitting diodes (LEDs) in the advanced oxidation process (AOP) of GG. Chemical oxygen demand (COD) removal provided mixed results, depending on the concentration of hydrogen peroxide (H₂O₂) in solution, and was between (0-95%) for H₂O₂-to-GG ratios between 7.0 and 176.3 g H₂O₂/g GG. COD removal was greatest at the …

Adsorption Of Perfluorinated Compounds From Post-Emergency Response Wastewater, Christopher T. Schmidt

Theses and Dissertations

This research investigated the efficacy of granular activated carbon (GAC) as a method to treat water impacted with aqueous film forming foam (AFFF) after a firefighting response. Bench-top experiments were conducted and compared to field scale adsorber performance removing mg/L concentrations of PFAS in water contaminated with Military Specification AFFF. Batch tests compared four adsorbents, and determined Calgon F600 GAC and Rembind Plus mixed carbon media had the greatest perfluorooctane sulfonate (PFOS) capacities. Additional batch isotherm experiments using AFFF and higher PFOS concentrations (mg/L) indicated larger amounts of GAC are required (>30mg/L) for effective removal. Full-scale testing simulated an …

Removal Of Perfluorooctanoic Acid From Water Using Primitive, Conventional And Novel Carbonaceous Sorbent Materials, Christopher K. Brown

Theses and Dissertations

Polyfluoroalkyl Substances (PFAS), like perfluorooctanoic acid, have been used for the last 50 years in a wide variety of industrial processes and consumer-based products, including polymer additives, lubricants, fire retardants and suppressants, pesticides, and surfactants (Buck et al. 2015). The Department of Defense (DoD) has used PFAS-based Aqueous Film Forming Foam (AFFF) at fire training facilities and aircraft hangars. AFFF has contaminated approximately 600 sites classified as fire training facilities with PFAS (Huang, 2013).

This study focused on testing the most likely carbonaceous adsorbent compounds to remediate PFAS-contaminated sites on Air Force installations. Batch tests were performed to determine the …

Modeling Napl Dissolution From Pendular Rings In Idealized Porous Media, Junqi Huang, John A. Christ, Mark N. Goltz, Avery H. Demond

Faculty Publications

The dissolution rate of nonaqueous phase liquid (NAPL) often governs the remediation time frame at subsurface hazardous waste sites. Most formulations for estimating this rate are empirical and assume that the NAPL is the nonwetting fluid. However, field evidence suggests that some waste sites might be organic wet. Thus, formulations that assume the NAPL is nonwetting may be inappropriate for estimating the rates of NAPL dissolution. An exact solution to the Young‐Laplace equation, assuming NAPL resides as pendular rings around the contact points of porous media idealized as spherical particles in a hexagonal close packing arrangement, is presented in this …

Semianalytical Solutions For Transport In Aquifer And Fractured Clay Matrix System, Junqi Huang, Mark N. Goltz

Faculty Publications

A three‐dimensional mathematical model that describes transport of contaminant in a horizontal aquifer with simultaneous diffusion into a fractured clay formation is proposed. A group of semianalytical solutions is derived based on specific initial and boundary conditions as well as various source functions. The analytical model solutions are evaluated by numerical Laplace inverse transformation and analytical Fourier inverse transformation. The model solutions can be used to study the fate and transport in a three‐dimensional spatial domain in which a nonaqueous phase liquid exists as a pool atop a fractured low‐permeability clay layer. The nonaqueous phase liquid gradually dissolves into the …

Sediment Loss And Its Cause In Puerto Rico Watersheds, Y. Yuan, Y. Jiang, E. V. Taugas, Eric G. Mbonimpa

Faculty Publications

A major environmental concern in the Commonwealth of Puerto Rico is increased sediment load to water reservoirs, to estuaries, and finally to coral reef areas outside the estuaries. Sediment deposition has significantly reduced the storage capacity of reservoirs, and sediments, with their associated contaminants and nutrients that are adsorbed, can stress corals and negatively impact reef health. To prevent and manage sediment loss it is therefore important to understand local soil erosion and sediment transport processes. The main objective of this study was to determine the influence of landscape characteristics on sediment loss. We analyzed available precipitation and sediment data …

Upward Flow Constructed Wetland For Treatment Of Water Contaminated With Chlorinated Aliphatics, Michael Shelley, Abinash Agrawal, Ke Qin, Garrett Struckhoff, Carl Enfield, James Waldron, Christina Powell

AFIT Patents

An improved upward flow constructed wetland cell for treatment of water contaminated with chlorinated aliphatics is disclosed. The improvements include adding ammonia-oxidizing microorganisms to the methane-oxidizing microorganisms already present in an oxygenated root zone and adding improved pore-water sample chambers for measuring the performance of the constructed wetland cell.

Optimization Of Nanoscale Zero-Valent Iron For The Remediation Of Groundwater Contaminants, Andrew W. E. Mcpherson

Theses and Dissertations

Nanoscale zero-valent iron (nZVI) is an emerging tool for the remediation of groundwater contaminants. The nanoparticles are capable of reductively destroying or immobilizing a wide range of contaminants. Their small size results in a high surface area to mass ratio, making them much more reactive compared to their more-coarse predecessors. Small particle size also allows nZVI particles to be injected directly into contaminated areas via a well, limiting the above-ground footprint and allowing access to contaminated areas that are beyond the reach of some conventional methods. nZVI technology has the potential to facilitate remediation in difficult situations, improve remediation outcomes, …

Unintended Consequences: Potential Downsides Of The Air Force's Conversion To Biofuels, Mark N. Goltz, Charles A. Bleckmann, Charles M. Mackay, Khai Vuong, Jerrod P. Mccomb

Faculty Publications

The desire to reduce US dependence on foreign energy, ongoing environmental concerns, and the rising cost of petroleum have sparked significant development of greener alternative and renewable energy sources such as alcohol-based biofuels. To address these issues, the Department of Defense DOD has moved to diminish its reliance on petroleum for fueling aircraft and ground equipment. The US Air Force, in alignment with DOD objectives, has initiated several goals for reducing its use of energy: (1) decrease the use of petroleum-based fuel by 2 percent annually for the vehicle fleet, (2) increase the use of alternative fuel in motor vehicles …

Analytical Solutions For Efficient Interpretation Of Single-Well Push-Pull Tracer Tests, Junqi Huang, John A. Christ, Mark N. Goltz

Faculty Publications

Single-well push-pull tracer tests have been used to characterize the extent, fate, and transport of subsurface contamination. Analytical solutions provide one alternative for interpreting test results. In this work, an exact analytical solution to two-dimensional equations describing the governing processes acting on a dissolved compound during a modified push-pull test (advection, longitudinal and transverse dispersion, first-order decay, and rate-limited sorption/partitioning in steady, divergent, and convergent flow fields) is developed. The coupling of this solution with inverse modeling to estimate aquifer parameters provides an efficient methodology for subsurface characterization. Synthetic data for single-well push-pull tests are employed to demonstrate the utility …

Evaluation Of Alternative Technologies To Supply Drinking Water To Marines In Forward Deployed Locations, Derek R. George

Theses and Dissertations

With recent increases, there are approximately 20,000 Marines deployed in the Helmand Province of Afghanistan. The cost of delivering bottled water to the troops is rapidly becoming unsustainable and convoys delivering bottled water are vulnerable to Improvised Explosive Devices (IEDs). Currently, raw water from indigenous sources, which has chemical and microbiological contaminants, is treated with reverse osmosis (RO), but only used for hygiene, with bottled water used for drinking. Due to the economic costs and risks to life of providing bottled water, decision-makers need to evaluate technology alternatives to treat raw water to supply safe drinking water. In this study, …

Modeling The Fate Of Groundwater Contaminants Resulting From Leakage Of Butanol-Blended Fuel, Khai H. Vuong

Theses and Dissertations

Fuel spills and leaks from storage tanks can contaminate groundwater. Typically in groundwater, hazardous aromatic hydrocarbons like benzene are attenuated through natural processes. However, it is possible that adding butanol to gasoline will interfere with these natural attenuation processes, so that spills and leaks of alternative fuels containing biobutanol may result in more persistent hazardous aromatic hydrocarbon plumes. This effect has already been observed with ethanol, which is currently added to gasoline. A numerical model was developed to simulate the subsurface fate and transport of butanol-blended fuel to assess the potential impacts of butanol on the natural attenuation of benzene. …

Evaluation Of An Innovative Technology For Treatment Of Water Contaminated With Perchlorate And Organic Compunds, Maureen A. Downen

Theses and Dissertations

Drinking water sources contaminated with both perchlorate and organic compounds have frequently been found in the U.S. Tailored granular activated carbon (T-GAC) is an innovative technology that is being evaluated to determine if it can more cost effectively remove perchlorate than conventional technologies. A question that has been raised is whether T-GAC can economically treat perchlorate-contaminated water that also has organic co-contaminants present. During a field study, trichloroethylene, an organic compound, and perchlorate were successfully removed by adsorption using a T-GAC/GAC system. These results motivated development of a model that could be applied to predict the cost and performance of …

An Evaluation And Implementation Guide For Current Groundwater Mass Flux Measurement Practices, Jack G. Wheeldon Iii

Theses and Dissertations

Contaminant mass flux is an important parameter needed for decision making at sites with contaminated groundwater. New and potentially better methods for measuring mass flux are emerging. This study looks at the conventional transect method (TM), and the newer passive flux meter (PFM), modified integral pump test (MIPT), and tandem circulating well (TCW) methods. In order to facilitate transfer and application of these innovative technologies, it is essential that potential technology users have access to credible information that addresses technology capabilities, limitations, and costs. This study provides such information on each of the methods by reviewing implementation practices and comparing …