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Non-aqueous phase liquid Gas phase expansion Dissolution mass flux Tetrachloroethene Dichloroethene Groundwater
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Full-Text Articles in Environmental Health and Protection
Expansion Of The Discontinuous Gas Phase And Its Effect On Mass Flux From A Non-Aqueous Phase Liquid (Napl) Pool, Kevin G. Mumford, James E. Smith, Sarah E. Dickson
Expansion Of The Discontinuous Gas Phase And Its Effect On Mass Flux From A Non-Aqueous Phase Liquid (Napl) Pool, Kevin G. Mumford, James E. Smith, Sarah E. Dickson
Sarah E Dickson
The partitioning of non-aqueous phase liquid (NAPL) compounds to a discontinuous gas phase results in the repeated spontaneous expansion, snap-off, and vertical mobilization of the gas phase. This mechanism has the potential to significantly affect the mass transfer processes that control the dissolution of NAPL pools by increasing the vertical transport of NAPL mass and increasing the total mass transfer rate from the surface of the pool. The extent to which this mechanism affects mass transfer from a NAPL pool depends on the rate of expansion and the mass of NAPL compound in the gas phase. This study used well-controlled …