Geology Commons^™

Scavenging, Cycling And Removal Fluxes Of 210Po And 210Pb At The Bermuda Time-Series Study Site, G. H. Hong, M. Baskaran, T. M. Church, M. Conte

Environmental Science and Geology Faculty Research Publications

Quantifying relative affinities of Po and Pb in different populations of marine particulate matter is of great importance in utilizing ²¹⁰Po as a tracer for carbon cycling. We collected and analyzed water samples for the concentrations of dissolved and total ²¹⁰Po and ²¹⁰Pb from the upper 600 m of the water column at Bermuda Time-series Study site (September 1999 to September 2000) to investigate their seasonality of concentrations and their ac-tivity ratio (²¹⁰Po/²¹⁰Pb activity ratio, AR). Sinking particles collected in sediment traps at depths of 500 m, 1500 m, and 3200 m from …

Effects Of Flow Rates And Composition Of The Filter, And Decay/Ingrowth Correction Factors Involved With The Determination Of In Situ Particulate 210Po And 210Pb In Seawater, Mark Baskaran, Thomas Church, Gi Hong, Anupam Kumar, Ma Qiang, Hui Choi, Sylvain Rigaud, Kanchan Maiti

Environmental Science and Geology Faculty Research Publications

Accurate measurements of particulate ²¹⁰Po (²¹⁰Po_p) and ²¹⁰Pb (²¹⁰Pb_p) are required in the investigation of (i) partitioning of Po and Pb between particulate and dissolved phases and (ii) export estimates of carbon and other key trace metals from the euphotic zone via sinking particulate matter. Based on the intercomparison of different composition of the filter material (QMA, Supor, Millipore, and Pall GN6) and flow rates (2 to 8 L min), we show how these factors affect the measured concentrations of ²¹⁰Po_p and ²¹⁰Pb_p and their activity …

Intercalibration Studies Of 210Po And 210Pb In Dissolved And Particulate Seawater Samples, Thomas Church, Sylvain Rigaud, Mark Baskaran, Anupam Kumar, Jana Friedrich, Pere Masque, Viena Puigcorbé, Guebuem Kim, Olivier Radakovitch, Gi Hong, Hui Choi, Gillian Stewart

Environmental Science and Geology Faculty Research Publications

Documented is an intercalibration (IC) exercise for both ²¹⁰Po and ²¹⁰Pb in seawater aliquots distributed between up to eight international laboratories that followed individual protocols. Dissolved and particulate samples were provided by GEOTRACES during two IC cruises at baseline stations in the North Atlantic and North Pacific oceans. Included were surface and/or deep dissolved and particulate samples at each site, plus complete profiles analyzed by the laboratory of the lead author. An unspecified solid phase standard was also distributed with ²¹⁰Po and ²¹⁰Pb in secular equilibrium to confirm spike calibrations. The ²¹⁰Po activities reported n …

Interaction Of Sea Ice Sediments And Surface Sea Water In The Arctic Ocean: Evidence From Excess 210Pb, M. Baskaran

Environmental Science and Geology Faculty Research Publications

We measured the activities of ²¹⁰Pb, ²²⁶Ra, ²³⁸U and ¹³⁷Cs in a suite of ice-rafted sediments (IRS) from the Arctic Ocean in an attempt to assess the interaction of sea ice sediments and surface water. The concentrations of these nuclides were compared to those of the benthic sediments in the coastal and shelf regions of the Arctic Ocean, which are believed to be the major source region for the IRS. The concentration factors (CF = activity of a nuclide in IRS/average activity in benthic sediments) are ∼1 and 4-92 for ¹³⁷Cs and ²¹⁰Pb, respectively. …

Speleothems As Proxy For The Carbon Isotope Composition Of Atmospheric Co2, M. Baskaran, R. V. Krishnamurthy

Environmental Science and Geology Faculty Research Publications

We have measured the stable isotope ratios of carbon in a suite of recent cave deposits (<200 >years) from the San Saba County, Texas, USA. The methodology for dating these deposits using excess ²¹⁰Pb was recently established [Baskaran and Iliffe, 1993]. The carbon isotope ratios of these samples, spanning the time period ∼1800–1990 AD, reflect the carbon isotope ratio of atmospheric CO₂ for the same period. The pathways by which the δ¹³C of atmospheric CO₂ is imprinted on these speleothems can be explained using a model developed by Cerling (1984). The results suggest that the …

Age Determination Of Recent Cave Deposits Using Excess 210Pb - A New Technique, M. Baskaran, Thomas M. Iliffe

Environmental Science and Geology Faculty Research Publications

Cave deposits have been widely used as proxy recorders in deciphering palaeoclimate during the last glacial/interglacial maxima (∼ 120 ka) [Harmon et al., 1975; Atkinson et al., 1978; Goede and Harmon, 1983; Ayliffe and Veeh, 1989]. Palaeoclimatic studies of cave deposits for the past 1–1000 yr time scale require a precise dating technique, that until now has been lacking. Due to the multiple sources of carbon in speleothems, ¹⁴C dates obtained for recently deposited calcite are highly variable and thus, ¹⁴C dating techniques are not suitable to obtain speleothem ages for the past 1–1000 years.

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Environmental Radiocesium In Subarctic And Arctic Alaska Following Chernobyl, M. Baskaran, J. J. Kelley, A. S. Naidu, D. F. Holleman

Environmental Science and Geology Faculty Research Publications

Radiocesium (¹³⁴ Cs and ¹³⁷ Cs) concentrations were measured in soil, plant and wildlife samples from subarctic to arctic Alaska. Concentrations of ¹³⁷ Cs ranged from below detectable or low levels in whale and fish samples to as high as 242 Bq/kg in lichen. For all potential human food items, the radiocesium concentrations measured in this study were below accepted permissible levels for human consumption. Chernobyl-derived radiocesium concentrations ranged from below detectable or low levels in all arctic samples (soil, sediment, lichen, whale, fish and caribou) to 32 Bq/kg in subarctic moss. Therefore the distribution and subsequent deposition of Chernobyl-derived …