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Rinded Iron-Oxide Concretions: Hallmarks Of Altered Siderite Masses Of Both Early And Late Diagenetic Origin, David Loope, Richard Kettler, Karrie A. Weber, Nathan L. Hinrichs, Derek T. Burgess

Department of Earth and Atmospheric Sciences: Faculty Publications

Iron-bearing concretions are valuable records of oxidation states of subsurface waters, but the first concretions to form can be altered drastically during later diagenetic events. Distinctive concretions composed of heavy rinds of iron oxide that surround iron-poor, mud-rich cores are common along bases of fluvial cross-bed sets of the Cretaceous Dakota Formation, Nebraska, USA. Concretion rinds thicken inward and cores contain 46 to 89% void space. Millimeter-scale spherosiderites are abundant in palaeosols that developed in floodplain facies. Evolution of rinded concretions began when intraformational clasts were eroded from sideritic soils, transported, abraded and deposited in river channels. Alteration of siderite …