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Desorption Hysteresis In Five Ion Exchanged Montmorillonites, Jerry Paul Fairley

UNLV Theses, Dissertations, Professional Papers, and Capstones

It is generally believed that the formation of recalcitrant (slowly desorbing) fractions of volatile organic compounds (VOCs) in soils is due to diffusion of compounds to sorption sites inaccessible to bulk fluid. The exact nature of these sites, however, is not well understood. In clay minerals, researchers favor two probable areas for the storage of persistent contamination; sites between the clay lamella, or sites with clay particle aggregates.

To test the hypothesis that recalcitrant fractions are formed in interlamellar spaces, a Na/Ca Montmorillonite (Smectite) was ion exchanged with five different cations (K⁺, Na⁺, Ca⁺, …