Geology Commons^™

Tryptophan-Like Fluorescence And Non-Point Source Pollution In Karst Basins, Inner Bluegrass Region, Kentucky, Ryan Dapkus

Theses and Dissertations--Earth and Environmental Sciences

Typically, the degree of fecal contamination of water is assessed by the concentration of thermotolerant coliforms, like E. coli. This method is time-consuming, taking > 18 hours between the start of incubation and subsequent enumeration. The current study examines the utility of monitoring tryptophan-like fluorescence (TLF) using in-situ fluorometers as a proxy for fecal contamination, particularly E. coli. Relative timing of discharge peaks and TLF peaks is considered, as well as differences in E. coli concentrations and major anion concentrations between two different basins that were monitored weekly. Results indicate that TLF is somewhat useful in the prediction of …

Isotopic And Geochemical Tracers Of Groundwater Flow In The Shivwits Plateau, Grand Canyon National Park, Jonathan W. Wilson

Theses and Dissertations--Earth and Environmental Sciences

As the impacts of global climate change on water resources continue to become more apparent, proper understanding and management of groundwater resources will be needed as supplies become more strained. Traditional methods of characterizing groundwater systems are time-intensive, costly, and can be difficult to complete in remote areas. Using ambient geochemical tracers from discrete sampling could aid in characterizing spring systems through determining flow paths, recharge areas, and carbon cycling. However, using discrete seasonal samples to understand the hydrogeology of complex, mixed-lithology aquifers has not been extensively examined. Here we explore using δ¹³C of dissolved organic carbon (DOC), …

Variability In Groundwater Flow And Chemistry In The Houzhai Karst Basin, Guizhou Province, China, Joshua M. Barna

Theses and Dissertations--Earth and Environmental Sciences

Understanding how karst aquifers store and transmit water and contaminants is an ongoing problem in hydrogeology. Flowpath and recharge heterogeneity contribute to the complexity of these systems. This thesis explores karst-conduit connectivity and water chemistry variability in the Houzhai catchment in Guizhou province, China. Artificial tracer tests were conducted during both the monsoon and dry seasons to understand temporal variability in connectivity and water velocity between karst features. Multiple flowpaths through the catchment are activated during the monsoon season and partially abandoned during the dry season. Additionally, gradient reversals during monsoonal high-flow events and as a result of pumping can …

Rethinking Karst Hazard Assessment In Kentucky, William P. Pierskalla Jr.

Theses and Dissertations--Earth and Environmental Sciences

Current karst hazard maps in Kentucky reflect the general lithology of the state and ignore or significantly reduce the impact of the actual sinkholes present within these areas. These maps rely on equal weighting, by area, of the Karst Potential Index (KPI) map and the sinkhole inventory map. The KPI is based on a 1:500,000 geologic map and less than 500 data points of carbonate rocks. The sinkhole inventory is derived from topographic maps updated in the 1970s with approximately 10-foot resolution. This method gives a preferential weighting of the KPI over the sinkhole data. Consequently, the current method is …

Hydrologic Monitoring And 2-D Electrical Resistivity Imaging For Joint Geophysical And Geotechnical Characterization Of Shallow Colluvial Landslides, Matthew M. Crawford

Theses and Dissertations--Earth and Environmental Sciences

Landslide characterization and hazard assessments require multidisciplinary approaches that connect geologic processes with geotechnical parameters. Field monitoring of hydrologic variables such as water content and water potential, coupled with geoelectrical measurements that can establish relationships used for geotechnical and landslide hazard investigations is deficient.

This study brings together different techniques to develop a methodology that connects geoelectrical measurements and shear strength. A field-based framework was established that includes (1) analysis of long-term soil moisture fluctuations within different landslides (2) establishment of constitutive and new equations that test the use of electrical conductivity to predict soil-water relationships and shear strength (3) …

Mobility Of Escherichia Coli Within Karst Terrains, Kentucky, Usa, Ashley M. Bandy

Theses and Dissertations--Earth and Environmental Sciences

Bacterial contamination of karst aquifers is a concern as water quality across the globe deteriorates in the face of decreasing water security. This study examined the transport and attenuation of two non-virulent isolates of Escherichia coli in relation to traditional groundwater tracers such as rhodamine WT dye and latex microspheres in two karst regions in Kentucky. Differential movement between the four tracers was observed in both epikarst and karst aquifer traces, with differences in behavior dependent on flow conditions. Attenuation was greater for the bacterial isolate containing the iha gene, compared to the isolate containing the kps gene. Microspheres of …

Spring Responses To Storms And Seasonal Variations In Recharge In The Middle Atlas Region Of Morocco, Brett Andrew Howell

Theses and Dissertations--Earth and Environmental Sciences

Springs in the Middle Atlas Mountains of Morocco are significant sources for public water supply. From March 2014 to May 2015, water temperatures were measured hourly at three springs (Ribaa, Sidi Rached, and Zerouka); water levels were measured hourly at Sidi Rached and Zerouka; and daily turbidity data were obtained from Ribaa. From March 2014 to March 2015, daily water samples were taken at Zerouka for analyses of the stable isotopes deuterium and oxygen-18. Hourly weather data (precipitation and air temperature) were available from March 2014 to May 2015 from Ifrane, near Zerouka. Temperature responses varied between the springs, showing …

Dynamic Surface Water-Groundwater Exchange In Tidal Freshwater Zones: Insights From The Christina River Basin (Delaware, Usa), Cole T. Musial

Theses and Dissertations--Earth and Environmental Sciences

In coastal rivers, tides can propagate for tens to hundreds of kilometers inland beyond the saltwater line. Yet the influence of tides on river-aquifer connectivity and solute transport in tidal freshwater zones (TFZs) is largely unknown. We estimate that along the TFZ of White Clay Creek (Delaware, USA), more than 17% of river water exchanges through hyporheic and riparian storage zones due to tidal pumping alone. Additional hyporheic processes such as flow through bedforms likely contribute even more exchange. The turnover length associated with the tidal pumping process is 39 km, similar to turnover lengths for all hyporheic exchange processes …

Spatio-Temporal Variability In Groundwater Discharge And Contaminant Fluxes Along A Channelized Stream In Western Kentucky, Ganesh N. Tripathi

Theses and Dissertations--Earth and Environmental Sciences

Spatio-temporal variability in groundwater discharge and contaminant fluxes along a channelized stream in western Kentucky

Surface and groundwater discharges and contaminant fluxes can vary with time and space depending upon the hydrogeological processes and geological setting of the area of interest. This study examined a ~300-m-long, channelized reach of a first-order perennial stream, Little Bayou Creek, in the Coastal Plain of far western Kentucky during the period October 2010–February 2012. Along the study reach, springs discharge groundwater contaminated by the chlorinated organic compound trichloroethene (TCE) and radionuclide technetium-99 (⁹⁹Tc) released as a result of past activities at the …

Chemical Evolution And Residence Time Of Groundwater In The Wilcox Aquifer Of The Northern Gulf Coastal Plain, Estifanos Haile

Theses and Dissertations--Earth and Environmental Sciences

This study aims to integrate groundwater geochemistry and mathematical modeling to determine the dominant geochemical processes and groundwater residence time within the Wilcox aquifer in the northern Gulf Coastal Plain. Groundwater samples were collected and analyzed for major ion chemistry, stable isotopes (¹⁸O, ²H, and ¹³C), and radioisotope ³⁶Cl content. Geochemical modeling enabled the identification of major sources and sinks of solutes in the aquifer. A two-dimensional, finite-difference, numerical model was used to determine the deep groundwater flow rate and transport of ³⁶Cl in the aquifer. Major ion chemistry shows a chromatographic pattern along …