Provenance Analysis Of The Grover Gravel Using Detrital Zircon Geochronology, Petrology And Heavy Mineral Analysis, Grant Spoering

MSU Graduate Theses

The Grover Gravel in the St. Louis, Missouri area contains a mix of chert, quartzite, jasper, and ironstone in clast sizes ranging up to 60 cm. The gravel varies in thickness from a veneer to over 30 feet and rests on upland surfaces at elevations sometimes exceeding 300 feet above the floors of major valleys. A pre-Pleistocene age generally has been proposed or assumed for the gravel, which classically has been interpreted to be a meandering-stream deposit atop an extensive flat upland surface, which was subsequently eroded and dissected by rejuvenated streams. However, large quartzite boulders in the gravel also …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Resolving Chronological And Temperature Constraints On Antarctic Deglacial Evolution Through Improved Dating Methodology, Cristina Subt

USF Tampa Graduate Theses and Dissertations

In order to determine the timing of Antarctic ice sheet retreat and advance during the Late Quaternary, various tools are used to measure the age of marginal marine sediments. Carbonate 14C dating is a well-established approach, but requires foraminiferal microfossils, shells or other carbonate materials that are rare in most Antarctic regions, and may also suffer from vital effects, which can result in variability of up to 500 years in living organisms. Bulk acid insoluble organic (AIO) 14C dates are frequently as an alternative, but this approach works best where high productivity and sedimentation rates reign, and not too well …

Geochemistry Of The Dome Mine Ankerite Veins: Insights Into The Multi-Stage Enrichment Of A World-Class Orogenic Gold Deposit, Jessica M. Stromberg

Electronic Thesis and Dissertation Repository

The Dome Mine in the world-class Timmins camp has produced over 16 Moz of gold during its 108 year production history. This gold endowment is the result of multistage enrichment of which the first stage is a set of ankerite veins that extend over 5,400 m in strike and 1,500 m vertically. A deposit wide geochemical study of the Dome ankerite veins was undertaken to characterize their genesis, geochemistry, and role in the deposit mineralization history. Samples and mapping from new and historic mine workings, bulk rock geochemistry, and stable isotope geochemistry were used to constrain the depositional context of …

Paleoenvironmental Variation And Provenance Records From Neogene Deep Sea Sediment Of The South China Sea, Chang Liu

LSU Doctoral Dissertations

I employed several paleoenvironmental proxies by utilizing deep sea sediment from the largest marginal basin in east Asia, namely the South China Sea (SCS), to reconstruct the long term paleoenvironmental variation in SE Asia since the Neogene. Sediments deposited within the SCS were mainly delivered by several major fluvial systems whose catchment basins cover several geological blocks in SE Asia. By analyzing the sediment’s geochemical and mineralogical characteristics, several indices which are affected by the source of the sedimentary influx, as well as the weathering state could be built and applied to constrain my paleoenvironmental reconstructions

Two deep sea drilling …

When, How, And Why Did The West Antarctic Ice Sheet Retreat In The Ross Sea Since The Last Glacial Maximum Using Foraminiferal And Porewater Geochemistry, Matthew Decesare

LSU Doctoral Dissertations

The Antarctic Ice Sheets (AIS) began to retreat from their Last Glacial Maximum (LGM) position sometime after 19,000 years ago. However, the corrosive waters circulating around Antarctica has prevented the recovery of radiocarbon-dateable material, hindering the development of deglacial chronologies. During Expedition NBP1502B to the eastern Ross Sea, an unprecedented quantity of fossil foraminifera and bivalves were recovered. Radiocarbon-dated specimens have been used to constrain the timing of West-AIS retreat from Whales Deep basin and Ross Bank. Whales Deep samples show that the WAIS retreated from its LGM position on the continental shelf edge by 14,700 ± 400 calibrated radiocarbon …

A Geochemical And Petrological Analysis Of The San Rafael Volcanic Field, Utah, Danielle Koebli

USF Tampa Graduate Theses and Dissertations

The San Rafael Volcanic Field, Utah, is a 4.6 Ma extinct monogenetic field that is found in the Northern Transition Zone of the Colorado Plateau. The field has been eroded, leaving the dikes, conduits, and sills visible. Within the sills we see evidences of immiscibility in the form of an intermediate syenite (~50 wt% SiO₂) enclosed in a mafic shonkinite (~48 wt % SiO₂). Field relations indicate that sills were formed due to single events (Richardson et al., 2015), which makes in-situ differentiation the process at the origin of both rock types. Geochemical data supports differentiation …

Arctic And North Atlantic Paleo-Environmental Reconstructions From Lake Sediments, Gregory A. De Wet

Doctoral Dissertations

ABSTRACT

Diurnal And Seasonal Variation In Groundwater Nitrate -N Concentration In A Saturated Buffer Zone, Joseph Miller

Theses and Dissertations

Surface water pollution by nitrate (NO3-) is identified as a critical problem in agricultural land-use areas. Excess NO3- loading causes eutrophication and hypoxia in near-shore marine waters such as the Gulf of Mexico. Diversion of agricultural runoff into saturated buffer zones reduces NO3- loading. Although the mechanisms responsible for NO3- reduction in saturated buffer zones are well characterized, little is known about how NO3- concentrations vary temporally and what factors control those changes. The objective of this study is to understand NO3- concentration and environmental factor variability in a saturated buffer zone on a diurnal scale within and among the …

Conduction Plus Convection Heat Flow Modeling For The Linga Complex, Peruvian Coastal Batholith, Luciano Uriel González Olivares

Loma Linda University Electronic Theses, Dissertations & Projects

Factors affecting the thermal evolution of the Linga magmatic intrusion in the Ica-Pisco area of the Peruvian Coastal Batholith were studied using field work, petrography, geochemistry data, and computer modeling. Field work and petrography involved collecting samples for geochemical analysis and documenting widespread propylitic and potassic hydrothermal alteration. Major element geochemistry was used to estimate rock density, viscosity, liquidus temperature, and water content. The δ18O values of seven fresh samples showed a slightly increasing west-east and old-young trend of approximately 7-8‰, indicating an increasing crustal component. The δ18O and δD values for eleven altered samples indicated that alteration came mostly …

Investigating Core Shale Depositional Environments Of Late Pennsylvanian Cyclothems Utilizing Geochemical Proxies To Test The Superestuarine Model, Bryce A. Mathis

LSU Master's Theses

The Late Paleozoic Midcontinent Sea (LPMS) inundated vast areas of the North American interior during glacio-eustatic transgressions, depositing widespread black shales facies within the core shale intervals of major cyclothems. These black shale deposits are unique because no modern analogs can adequately explain the depositional environments and model for organic matter preservation across such vast ancient epicontinental settings. One possible explanation is that a superestuarine circulation system developed across the LPMS during humid interglacial phases, which promoted strong water column stratification and benthic anoxia.

The goal of this research was to test the validity of the superestuarine estuarine model and …

The Dynamic Relationship Between The Bear River, Quaternary Basaltic Center, Normal Faults, And The Resulting Rearrangement Of Rivers In The Northeast Edge Of The Great Basin, Southeast Idaho, Brady Utley

All Graduate Plan B and other Reports, Spring 1920 to Spring 2023

The objective of this research project in Gem Valley graben, southeast Idaho is to identify the location, age and history of the Quaternary diversion of the Bear River into paleo-Lake Thatcher, and then into the Lake Bonneville basin from the Columbia River basin. Mapping, geochemical analysis, cross-cutting relationships, and five new age determinations, together with prior published research, shed new light on the complex history of interaction between the volcanic rocks, rivers, lakes, and faults in Gem Valley. Research goals were to test the hypothesis that local faulting and volcanism drove the diversion of the Bear River and controlled the …

Sedimentary Characteristics And Nutrient Sequestration Of Embanked Floodplains Along The Lower Mississippi River, Mississippi And Louisiana, R M Malitha Rathnayake

Master's Theses

The Mississippi River Basin is the largest river basin in North America and the third largest river basin in the world. Most of the corn, soybeans, wheat, cattle, and hogs harvested in the United States come from the Mississippi River Basin and about 58% of the entire drainage basin is croplands. Runoff from these lands carries sediments and nutrients, and the Mississippi River transports these downstream and ultimately deposits them in the Gulf of Mexico. The northern Gulf of Mexico is one of largest human-caused hypoxic zones in the world. Hypoxia is the phenomena where the dissolved oxygen level decreases …

Geochemistry Of Volatiles Released By Incipient Continental Rifting And Subduction Processes, Hyunwoo Lee

Earth and Planetary Sciences ETDs

Volatiles (N2, CO2, and He) are released by volcanism and hydrothermal activity during continental rifting and subduction processes. Analyses of volatile components have been conducted to obtain gas contents (CO2, SO2, H2S, N2, Ar, He, and so on), stable isotope compositions (δ13C, δ15N, and so on), and noble gas isotopes (3He/4He, 40Ar/36Ar, and so on). This dissertation includes four chapters to report new nitrogen isotope fractionation factors of bubbling gases during gas-water transfer at various water temperatures (Chapter 1), first measurements of massive amounts of CO2 released by incipient continental rifting in the Magadi and Natron Basin, East African Rift …

Enstatite Achondrites As Indicators Of Processes And Environments In The Early Solar System, Diego David Uribe

Electronic Thesis and Dissertation Repository

This thesis investigates the processes and environments of formation of the anomalous enstatite achondrites NWA 4301, Zakłodzie, and NWA 8173 to determine how they relate to other enstatite meteorites (chondrites, impact melt rocks, aubrites, and so-called “primitive enstatite achondrites”). Observations of Zakłodzie and NWA 4301 showed both meteorites may share a common parent body, but experienced different metamorphic conditions. Different zonation patterns in plagioclase, silica polymorphs and associations, and sulfide assemblages indicate Zakłodzie experienced higher metamorphic temperatures and cooled faster than NWA 4301, therefore NWA 4301 was buried deeper in the parent body relative to Zakłodzie. In NWA 8173, mineral …

Petrogenesis And Concentric Zonation Of The Belchertown Intrusive Complex, West-Central Massachusetts, Karen June Van Wagner

Masters Theses

The Belchertown Intrusive Complex is a ~164 km2 Devonian pluton that intruded Paleozoic metasedimentary and metavolcanic rocks in west-central Massachusetts. Intrusion of the pluton was synchronous with Acadian deformation (Ashwal, 1974). The complex is concentrically zoned, with a core of orthopyroxene-biotite monzodiorite, a middle zone of clinopyroxene-hornblende-biotite granodiorite, and an outermost zone of hornblende-biotite granodiorite. Zoning from a more to less hydrous mineral suite from the outside to the inside of the pluton led Ashwal (1974) to suggest that metamorphic hydration most strongly affected the outermost zones of the complex. Basaltic inclusions occur most commonly near the edges of …

Using Fluid-Mobile Elements To Decipher An Aqueous History Preserved In The Sedimentary Rocks Of Gale Crater, Mars, Jeff A. Berger

Electronic Thesis and Dissertation Repository

Fluid-mobile elements preserve a record of the aqueous history of Mars in the sedimentary rocks of Gale Crater, and they are traceable with the rover Curiosity’s Alpha Particle X-ray Spectrometer (APXS). This is the fundamental principle behind the scientific questions addressed in the four main chapters of this dissertation. First, we conducted a field study at Hawai’i, an established Mars analogue, to investigate sedimentary processes and alteration in rocks comparable to those in Gale Crater. We conclude that open system, circumneutral weathering is very limited in Gale rocks; acid sulfate alteration and sedimentary mixing of diverse rocks is likely. Second, …

Mineral Evidence For Generating Compositionally Zoned Rhyolites Of The Devine Canyon Tuff, High Lava Plains, Oregon, Erik Paul Shafer

Dissertations and Theses

Large-volume silicic eruptions are often evacuated from magma reservoirs which display gradients in composition, temperature, crystallinity, and volatile content. The 9.7 Ma Devine Canyon Tuff (DCT) of eastern Oregon represents such an eruption, with >300 km³ of compositionally zoned pyroclastic material deposited as a variably-welded ignimbrite. The ignimbrite displays homogenous bulk tuff major element compositions with a wide range of trace element compositions, allowing for the investigation of how these magmas were generated, stored, and modified in the magma reservoir by studying pumices which represent the primary magmas composing the DCT. Five pumices ranging from dacite to rhyolite bulk compositions …

Hydrocarbon And Co2 Emissions From Oil And Gas Production Well Pad Soils Comparative To Background Soil Emissions In Eastern Utah, Cody S. Watkins

All Graduate Theses and Dissertations, Spring 1920 to Summer 2023

What effect does the development of oil and gas have on the observed air quality (i.e., increased ozone, carbon dioxide (CO₂), volatile organic compounds (VOCs), and/or methane emissions) in northeastern Utah? What percentage of these gases is natural background emissions, and what percentage is due to the recent oil and gas development in the region? Emissions in this text refer to gases released from the earth’s surface to the atmosphere. Methane is the primary compound in natural gas. Natural gas is a naturally occurring hydrocarbon gas mixture. Emissions of methane, non-methane hydrocarbons (NMHC), and CO₂ at 27 …

Terroir Studies In Washington And Wisconsin American Viticultural Areas, Snejana Karakis

Theses and Dissertations

The concept of terroir has been evaluated since the 12th century, when Cistercian monks from Burgundy realized that the physical environment in which grapes are grown has a major influence on the character and quality of the resulting wine. These environmental conditions affecting grape and wine quality are known as terroir in viticulture and have become increasingly important in the grape growing and wine industry. In this dissertation, three studies investigating the terroir of vineyards located in Washington and Wisconsin American Viticultural Areas (AVAs), which are defined by the Alcohol and Tobacco Tax and Trade Bureau (TTB) as delimited grape-growing …

Magmatic Hydrothermal Alteration And Secondary Post-Shock Features In Martian Olivine-Phyric Basalt Northwest Africa 10416; Petrology And Geochemistry Of Primitive Achondrite Northwest Africa 11042, Zoltan Vaci

Earth and Planetary Sciences ETDs

The Martian olivine-phyric basalt Northwest Africa (NWA) 10416 contains large olivine xenocrysts whose cores have been stained brown by hydrothermal alteration and whose rims are composed of pristine olivine overgrowths. Microanalysis of these olivine cores reveals various degrees of amorphization, some of which have been overprinted by terrestrial weathering, evident as part of a weathering rind along the exposed surface of the meteorite. Studies of a completely unweathered terrestrial analogue basalt from southern Colorado reveal similar features and indicate that both basalts were altered in a supersolidus magma chamber setting. The alteration features in NWA 10416 thus imply the presence …

Determining Sources Of Nitrate In The Semi-Arid Rio Grande Using Nitrogen And Oxygen Isotopes, Diego Alberto Sanchez Hernandez

Masters Theses

The Rio Grande, a semi-arid river in the American Southwest, is a major source of surface water for agriculture and drinking supplies in New Mexico and Texas. In addition to increasing salinity, considerable increases of NO₃^- [nitrate] have been observed in the semi-arid portion of the Rio Grande. It is possible that elevated water salinity inhibits denitrification on irrigated fields and, thus, fails to mediate excess nutrient load from anthropogenic activities. Therefore, two major goals of this project were to 1) characterize and quantify major NO₃^- sources, and 2) assess whether elevated water salinity affects microbial …

An Elemental Highway: Investigation Of A High Nickel Anomaly In Olivine From The Island Of Niihau, Hawaii, Alexander James Valentine

UNLV Theses, Dissertations, Professional Papers, and Capstones

The study of volcanic geochemistry is one of the main gateways for investigating the Earth’s mantle. One important topic in the field is that of nickel (Ni) in the mineral olivine. While Ni is a compatible element in olivine, its high concentration at a given MgO content is not well understood. A variety of hypotheses have been proposed, including attributing presence of Ni to pyroxenite source melting, contribution from the core, or variation in peridotite source melting. In addition to the other hypotheses, chemical diffusion may also be a mechanism for enriching olivine Ni concentration. Magnesium-iron (Mg-Fe) isotopic measurements have …

Depositional Dynamics Of The Upper Eagle Ford (Upper Cretaceous): Karnes And Gonzales Counties, South Texas, Josie Brunick

Graduate Theses and Dissertations

The mixed siliciclastic/carbonate late Cretaceous Eagle Ford Formation is commonly divided into the lower Eagle Ford and the upper Eagle Ford. The lower Eagle Ford is arguably the most obvious organic rich interval highlighted with wireline log data; however, the upper Eagle Ford may have just as much potential for hydrocarbon production success as the lower Eagle Ford has had. A better understanding of the upper Eagle Ford will allow a more thorough and educated assessment into its full potential as an unconventional reservoir, and allow its sweet spots for oil or gas to be found and exploited.

This study …

Mineralogy And Geochemistry Of The Heddleston Porphyry Cu-Mo Deposit, Montana, Ben Schubert

Graduate Theses & Non-Theses

The Heddleston porphyry Cu-Mo deposit is located in Lewis and Clark County, Montana, near the headwaters of the Blackfoot River. It is immediately west of the historic Mike Horse mine, an important producer of Pb-Zn from polymetallic veins and lodes. The Heddleston property was explored extensively by the Anaconda Company in the 1960s and 1970s, but was never mined. Specimens of polished drill core from the deposit are archived in the Anaconda Research Collection at Montana Tech campus. The purpose of this research project was to use the archived samples to examine the geochemistry and mineralogy of the Heddleston and …

Supergene Mineralization Of The Continental Pit, Butte, Silver Bow County, Montana, Kyle Eastman

Graduate Theses & Non-Theses

The Butte porphyry Cu-Mo-Ag deposit has been considerably altered by supergene processes that enriched Cu and Ag, and mobilized other metals. Supergene enrichment provided early miners with excellent ore grades, and contributes significantly to current mining operations in Butte. The Continental Pit exhibits the classic leached and enriched vertical zonation that is common in near-surface porphyry systems around the world. Although studied by the Anaconda Copper Mining Company during the mid-20th century, significant and economically relevant questions remain regarding this deposit’s supergene heavy metal geochemistry and its relationship to the local hydrology and tectonic history.

This thesis investigates the paragenesis …

Quantity Trumps Quality: Bayesian Statistical Accumulation Modeling Guides Radiocarbon Measurements To Construct A Chronology In Real-Time, Devon Robert Firesinger

USF Tampa Graduate Theses and Dissertations

The development of an accurate and precise geochronology is imperative to understanding archives containing information about Earth’s past. Unable to date all intervals of an archive, researchers use methods of interpolation to approximate age between dates. Sections of the radiocarbon calibration curve can induce larger chronological uncertainty independent of instrumental precision, meaning even a precise date may carry inflated error in its calibration to a calendar age. Methods of interpolation range from step-wise linear regression to, most recently, Bayesian statistical models. These employ prior knowledge of accumulation rate to provide a more informed interpolation between neighboring dates. This study uses …

Characterizing The Evolution Of Slab Inputs In The Earliest Stages Of Subduction: Preliminary Evidence From The Fluid-Mobile Element (B, Cs, As, Li) Systematics Of Izu-Bonin Boninitic Glasses Recovered During Iodp Expedition 352, Keir Aavon Sanatan

USF Tampa Graduate Theses and Dissertations

Fluid-mobile elements (FMEs) such as B, Cs, As, Li and Tl can mobilize readily under low P-T conditions (0.2-0.5 GPa). This makes them effective geochemical tracers that can be used as a way of tracking fluid-rock exchanges at the shallow depths encountered in the earliest stages of subduction.

The Izu-Bonin-Mariana (IBM) subduction system is unique in that it preserves a record of the sequences produced from the onset of subduction through the development of arc magmatism. International Ocean Discovery Program (IODP) Expedition 352 recovered >800m of boninite core material from the earliest IBM magmatic events.

Select boninitic glasses from these …

Cu-Pd Mineralization And Exploration Geochemistry Of The Eastern Gabbro, Coldwell Alkaline Complex, On, Canada, Yonghua Cao

Electronic Thesis and Dissertation Repository

The Eastern Gabbro forms the northern and eastern margin of the Coldwell Alkaline Complex. It contains three magma series: the barren meta-basalt, the Layered Series, and the Marathon Series which hosts all known PGE mineralization. The Marathon Series can be distinguished from other Series using the combination of portable X-ray fluorescence (pXRF) and benchtop scanning electron microscope (bSEM). Whole-rock Ba, Mg# (molar Mg/(Mg+Fe)*100), Zr and V/Ti values acquired from pXRF, and Mg#s of olivine and clinopyroxene, and anorthite content (molar Ca/(Ca+Na)*100) of plagioclase acquired from bSEM-EDS are key parameters. The Layered Series generally contains higher Ba and lower V/Ti than …

Zircon As A Proxy For "Taking The Temperature" Of Granites: An Example Using Zircon Thermometry Applied To Grenvillian Mid-Crustal Magmas In The Blue Ridge Province, Virginia, Samantha Rae Burk

Theses and Dissertations--Earth and Environmental Sciences

The Grenville orogeny was a protracted (~200 m.y.) series of “hot” magmatic- metamorphic events that contributed to the growth of the Laurentian margin in the late Mesoproterozoic. The granites contain remarkably high Zr content, lack xenocrysts, and become zircon saturated at high temperatures, which are all unusual for felsic magmas. The “hot Grenville granite” hypothesis is tested and use of high-Zr granitoids as potential zones of crustal magma generation through: U-Pb geochronology and cathodoluminescence imaging to assess inherited zircon components; quantitative modeling of zircon crystallization history using rhyolite-MELTS; and Ti-in-zircon thermometry. U-Pb zircon ages for two samples from the Virginia …