Physical Sciences and Mathematics Commons^™

Impact Of Interlayer Cation Composition And Strongly Bound Water On Smectite ẟ²H, As Determined By A Modified Tcea Method, Nadine J. Kanik

Electronic Thesis and Dissertation Repository

Interlayer cation composition and cation hydration enthalpy can potentially affect the excess hydrogen-yield and δ²H of smectitic clays. Complexities arise from condensed atmospheric water adsorbed on the clay, as it constitutes a potential additional source of hydrogen when attempting to measure the δ²H of structural OH groups. To approach this problem, the δ²H of different cation-saturated, dried forms of six Clay Minerals Society Source Clay smectites were measured. A modified sample drying and on-line High-Temperature-Conversion-Elemental-Analysis (TCEA) Continuous-Flow-Isotope-Ratio-Mass-Spectrometry protocol, facilitated isotopic measurements. A stronger interlayer cation hydration enthalpy (Ca²⁺>Na⁺>K⁺), …

Mxenes As Flow Electrodes For Capacitive Deionization Of Wastewater, Naqsh E. Mansoor

Boise State University Theses and Dissertations

The energy-water nexus poses an integrated research challenge, while opening up an opportunity space for the development of energy efficient technologies for water remediation. Capacitive Deionization (CDI) is an upcoming reclamation technology that uses a small applied voltage applied across electrodes to electrophoretically remove dissolved ionic impurities from wastewater streams. Similar to a supercapacitor, the ions are stored in the electric double layer of the electrodes. Reversing the polarity of applied voltage enables recovery of the removed ionic impurities, allowing for recycling and reuse. Simultaneous materials recovery and water reclamation makes CDI energy efficient and resource conservative, with potential to …

An Ethnography Of Wash Infrastructures And Governance In Sulphur Springs, Florida, Mathews Jackon Wakhungu

USF Tampa Graduate Theses and Dissertations

This dissertation describes the forces that shape the perceptions and practices in Water, Sanitation, and Hygiene (WaSH) services in the community of Sulphur Springs, Tampa, Florida. It also explores how these forces, perceptions, and practices produce adverse experiences and inequalities in water, sewer, drainage, and laundry services. This ethnographic study combines participant observation, ethnographic interviewing, freelisting, oral history, and GIS to uncover the context, experiences, and perceptions about WaSH in Sulphur Springs. The study finds that the present conditions and perceptions about WaSH are embedded into the historical contexts—especially racial segregation, the construction of the interstate, and multiple economic downturns …

Relationship Between University Student Characteristics And Water Conservation Behaviors, Matthew A. Wise

Graduate Theses and Dissertations

Water over-consumption is a critical issue due to it being a mismanaged, and virtually finite, natural resource. In order to convey this information to the public and promote change, it is important to understand the public’s current attitude towards the topic in order to develop more targeted teaching approaches. The purpose of this study was to determine college-age students’ perceptions about water resource usage, their personal levels of active engagement in water conservation, and if any differences existed between agriculture students and non-agriculture students. This study utilized an online quantitative survey, guided by the Theory of Planned Behavior, which was …

Protean Caves And Cyrenean Grottos: The Subterranean World Of Vergil's Fourth Georgic, Kirby Schoephoerster

Arts & Sciences Electronic Theses and Dissertations

Using the studies and methodologies spearheaded by the burgeoning field of geomythology, this project aims to reevaluate one of the most famous works of ancient literature, the Georgics of Vergil, within the context of karst geology. In other words, I plan to critically investigate the famous myth of Aristaeus using a geomythological lens that focuses on how Vergil treats caves and cave systems as related to (his) myth. The didactic poem as a whole, and much less so the myth of Aristaeus, has been assessed relatively little by archaeologists, and by geomythologists not at all. Yet, book four contains an …

Irrigation Design In Montana: Accommodating Varying Water Accessibility Across The Continental Divide., John Garrett Lampson

Biological and Agricultural Engineering Undergraduate Honors Theses

The design work performed in this project was conducted over two summers (2018, 2019) of internship experience with the Natural Resources Conservation Service (NRCS) across the state of Montana. The first summer’s design work was based out of Glendive, MT, in Dawson County, approximately 50 kilometers from the North Dakota border. The second summer was in Missoula, MT, in Missoula County, near the Idaho border. The two areas differ significantly in topography, weather, and water availability with the main separating geographic influence being the Rocky Mountains.

This paper focuses on the design process and requirements for two farms located outside …

Drinking Water Governance For Whom? An Institutional Analysis Of Rural Drinking Water Systems In New Mexico, Tucker Colvin

Geography ETDs

Rural community drinking water systems in New Mexico are facing many challenges, including a lack of personnel, deteriorating infrastructure, lack of funds, overly burdensome and confusing regulation, environmental concerns, and concerns over water rights. Governing agencies are creating vulnerability by making managers prioritize some issues and neglect others. Water systems designated a Mutual Domestic Water Consumers Associations are especially problematic because they are small and managed by volunteers but have as much regulatory burden as larger municipalities. I use the theory of institutional work to explain how an institution that was originally designed to help low-income and rural communities is …

Living Rivers, Cosmopolitan Activism, And Environmental Justice In The Bengal Delta, Daniel Adel

Cal Poly Humboldt theses and projects

This thesis explores the social movements and civil society activism to protect the rivers that flow through Bangladesh—the cradle and terminal delta floodplain of the transboundary Ganges, Brahmaputra, and Meghna river systems—, as well as ways to build regional cooperation and watershed democracy in South Asia. The research drew on four overarching fields of study: environmental justice, southern environmentalism, ecological nationalism, and environmental governance. These four bodies of scholarship helped address the overarching question: how are civil society organizations analyzing and responding to the water diversions and degradation of Bangladesh’s transboundary rivers? Semi-structured interviews were conducted with civil society organizations …

Elucidating The Properties And Mechanism For Cellulose Dissolution In Tetrabutylphosphonium-Based Ionic Liquids Using High Concentrations Of Water, Brad Crawford

Graduate Theses, Dissertations, and Problem Reports

The structural, transport, and thermodynamic properties related to cellulose dissolution by tetrabutylphosphonium chloride (TBPCl) and tetrabutylphosphonium hydroxide (TBPH)-water mixtures have been calculated via molecular dynamics simulations. For both ionic liquid (IL)-water solutions, water veins begin to form between the TBPs interlocking arms at 80 mol % water, opening a pathway for the diffusion of the anions, cations, and water. The water veins allow for a diffusion regime shift in the concentration region from 80 to 92.5 mol % water, providing a higher probability of solvent interaction with the dissolving cellulose strand. The hydrogen bonding was compared between small and large …

Filtration Apparatus Design For Oil-Water Separation Using Membranes And Sponges, Alec Jerger

Williams Honors College, Honors Research Projects

It can be difficult to separate water and oil emulsions through traditional filtration. Therefore, investigations of filtering using thermo-responsive (TR) polymers, in this case poly(vinyl methyl ether) (PVME), was conducted. It’s hypothesized that below its lower critical solution temperature (LCST), PVME has an affinity for water while oil substances do not. Above the LCST the opposite will be true. To verify this hypothesis, iterations of filtration designs were created to provide optimum control over the parameters to measure flow. The final optimized experimental apparatus was a Chromaflex glass column which was air tight and controlled all parameters besides fluid flow. …

Investigation Of Underpotential Deposition Of Copper At Heated Gold Loop Screen-Printed Electrodes In A Variety Of Water Samples, Eun-Ju Lee

Legacy Theses & Dissertations (2009 - 2024)

To study the underpotential deposition (UPD) of copper, three different types of water samples (TraceSelect® Ultra-pure water, Indian pond water at University at Albany and tap water) are used at a heated gold loop screen-printed electrode (GLE), which is a new type of heated working electrode for voltammetry measurements that is able to directly detect the copper content in the water samples. The anodic stripping analysis of copper is performed with these gold loop electrodes at room temperature of 25 °C and electrode temperature of 80 °C at two different deposition potentials, -0.20 V and +0.10 V. Furthermore, the concentration …

Mixed-Valent Heterometallic Molecular Precursors : Expansion Into 4d Transition Metals, Jesse Caleb Carozza

Legacy Theses & Dissertations (2009 - 2024)

Hydrogen fuel can provide an ideal carbon-free energy carrier wherever water is available, be that on Earth or throughout the solar system. The use of water electrolysis to split water molecules into contaminant-free hydrogen gas, suitable for use in fuel cells, and oxygen gas allows also for storage of excess electrical energy during periods of high production and low demand, and an easy path to release that stored energy when demand is high and active supply is low. However, liberating hydrogen from water is an energy-intensive process, and effective electrocatalysts that reduce the amount of energy wasted by the reaction …