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Full-Text Articles in Physical Sciences and Mathematics
In Situ Study Of Geological Fluid Inclusions Using 23na Nuclear Magnetic Resonance Spectroscopy, Stephen Pilar
In Situ Study Of Geological Fluid Inclusions Using 23na Nuclear Magnetic Resonance Spectroscopy, Stephen Pilar
Electronic Thesis and Dissertation Repository
23Na Magic Angle Spinning Solid State Nuclear Magnetic Resonance (MAS SS NMR) spectroscopy has been used to study natural geological samples of halite, fluorite, and quartz to evaluate the efficacy of NMR spectroscopy for in situ fluid inclusion analysis. NaCl calibration standards yielded a strong linear correlation (R2=0.9919) for salinity, albeit only over a ~1 ppm breadth of chemical shift. Fluid inclusions were successfully identified in all three types of minerals studied using MAS NMR. Chemical analysis with Inductively Coupled Plasma -- Mass Spectrometry (ICP-MS) was employed to quantify elemental contaminants in halite samples. Powder X-Ray Diffraction …
A Regional Chemical Characterization And Analysis Of Groundwater In Eastern Ontario, Laura M. Colgrove
A Regional Chemical Characterization And Analysis Of Groundwater In Eastern Ontario, Laura M. Colgrove
Electronic Thesis and Dissertation Repository
This study utilizes 234 samples to provide a regional characterization and analysis of groundwater chemistry in eastern Ontario, Canada, where elevated TDS, Na and halogens occur in shallow groundwater. Water-types, PCA and mapping are used to investigate the processes and features controlling the chemistry. The chemical patterns are associated with glaciomarine deposits (extent, thickness) and bedrock topography, which modulate residence time and flow-path of groundwater. These determine the relative effects of recharge, ion exchange, salinization and organic breakdown on groundwater chemistry. Anomalous chemistry east of Ottawa (brackish-to-saline TDS; elevated water δ18O; elevated Na, Cl, I, CH4, …
Diatoms In Castor Lake (North-Central Washington, Usa) – Proxies Of Climate And Hydrologic Variation, Kelly D. Hollingshead
Diatoms In Castor Lake (North-Central Washington, Usa) – Proxies Of Climate And Hydrologic Variation, Kelly D. Hollingshead
Electronic Thesis and Dissertation Repository
This research provides a high temporal resolution (1 sample / 2-3 years) record of hydrologic variation for the last 2,000 years using a lake sediment record from Castor Lake, a closed-basin system in Washington, USA. The core was dated using 137Cs, 14C, and tephrochronology. Approximately 600 diatoms were identified and enumerated in 198 samples from a Castor Lake freeze core and Livingstone-piston core. A diatom-inference model for salinity was applied to reconstruct fossil diatom salinity. Diatom-inferred salinity for the last century tracked Palmer Drought Severity Index, indicating diatom community composition tracks effective moisture and can be used to …