Physical Sciences and Mathematics Commons^™

Experimental Investigation Of High-Temperature Brine-Shale Interactions, Anna Atasha Hoffmann

Doctoral Dissertations

"Hydrofracturing (fracking), a common practice in the Petroleum Industry to induce or improve fluid flow in tight formations, creates chemical disequilibrium that further alters the porosity and permeability of host rocks and results in the production of saline and contaminated produced waters (PW). The PW of the Tuscaloosa Marine Shale (TMS) are Na-Ca-Mg-K-Cl brines with mean concentrations of approximately 16% Total Dissolved Solids (TDS) and circumneutral pH. Analysis of composition suggests the PW result from a 20 to 80% dilution of formation waters (relict brines of the Louann Salt) by fracking fluid. Trace element concentrations generally show moderate to strong …

Precipitation Variability And Predictability Over The Arabian Peninsula, Central Southwest Asia, And Southern Africa, Matthew Francis Horan

Doctoral Dissertations

The Northern Hemisphere winter is the main rainy season for the Arabian Peninsula (AP), Central Southwest Asia (CSWA), and Southern Africa (SF), where precipitation predictability is limited or understudied. This dissertation research focuses on improving our understanding of these regions' wet-season precipitation characteristics and predictability.

First, I have identified the AP's key moisture sources through a Lagrangian back-trajectory algorithm. Mid-latitude land and water bodies, such as the Mediterranean and Caspian Seas, are the primary moisture sources in the northern region. Areas further south rely on moisture transport from the Western Indian Ocean and the African continent. A significant drying trend …

Hydroclimate Variability In Central America During The Holocene Inferred From Lacustrine Sediments In Lake Izabal, Eastern Guatemala, Edward Fernando Duarte

Doctoral Dissertations

"Holocene hydroclimate reconstructions have contributed to our understanding of the mechanisms controlling precipitation in Central America. Recent hydroclimate proxy records from the region, however, have revealed considerable spatiotemporal complexity in precipitation variability. This complexity is hypothesized to result from the interaction between multiple oceanic-atmospheric processes that converge in the region. This project analyzed three sediment cores from Lake Izabal, eastern lowland Guatemala, with the goal of understanding changes in precipitation, lake productivity, and lake water chemistry during the Holocene. Our proxy results indicate that precipitation in the region increased from the early to the middle Holocene, when Lake Izabal became …

Precipitation And Coacervation In Polyelectrolyte-Colloid Systems, Fatih Comert

Doctoral Dissertations

Complex coacervation between oppositely charged polyelectrolytes (PEs) and colloids (i.e. micelles and proteins) has increasingly become popular due to the use of these materials in a range of applications including but not limited to personal care, biomaterials, protein purification, and food science. In taking advantage of complex coacervation, which is a liquid-liquid phase separation, precipitation has always represented a problem by introducing inhomogeneities, irreversibility and irreproducible kinetics. Therefore, understanding the dominant factors driving the formation of precipitates is important to control outcomes. In this work, we have performed comparative studies of coacervation and precipitation in model PE-colloid systems to investigate …