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Full-Text Articles in Physical Sciences and Mathematics
On The Origin Of Mode- And Bond-Selectivity In Vibrationally Mediated Reactions On Surfaces, Daniel Killelea, Arthur L. Utz
On The Origin Of Mode- And Bond-Selectivity In Vibrationally Mediated Reactions On Surfaces, Daniel Killelea, Arthur L. Utz
Chemistry: Faculty Publications and Other Works
The experimental observations of vibrational mode- and bond-selective chemistry at the gas–surface interface indicate that energy redistribution within the reaction complex is not statistical on the timescale of reaction. Such behavior is a key prerequisite for efforts to use selective vibrational excitation to control chemistry at the technologically important gas–surface interface. This paper outlines a framework for understanding the origin of non-statistical reactivity on surfaces. The model focuses on the kinetic competition between intramolecular vibrational energy redistribution (IVR) within the reaction complex, which in the long-time limit leads to statistical behavior, and quenching, scattering, or desorption processes that restrict the …
Computational Renormalization Scheme For Quantum Field Theories, Rainer Grobe, Qichang Su, R E. Wagner
Computational Renormalization Scheme For Quantum Field Theories, Rainer Grobe, Qichang Su, R E. Wagner
Faculty publications – Physics
We propose an alternative technique for numerically renormalizing quantum field theories based on their Hamiltonian formulation. This method is nonperturbative in nature and, therefore, exact to all orders. It does not require any correlation functions or Feynman diagrams. We illustrate this method for a model Yukawa-like theory describing the interaction of electrons and positrons with model photons in one spatial dimension. We show that, after mass renormalization of the fermionic and bosonic single-particle states, all other states in the Fock space have finite energies, which are independent of the momentum cutoff.
Enhancement Of Electron-Positron Pair Creation Due To Transient Excitation Of Field-Induced Bound States, M Jiang, Q Z. Lv, Z M. Sheng, Rainer Grobe, Qichang Su
Enhancement Of Electron-Positron Pair Creation Due To Transient Excitation Of Field-Induced Bound States, M Jiang, Q Z. Lv, Z M. Sheng, Rainer Grobe, Qichang Su
Faculty publications – Physics
We study the creation of electron-positron pairs induced by two spatially separated electric fields that vary periodically in time. The results are based on large-scale computer simulations of the time-dependent Dirac equation in reduced spatial dimensions. When the separation of the fields is very large, the pair creation is caused by multiphoton transitions and mainly determined by the frequency of the fields. However, for small spatial separations a coherence effect can be observed that can enhance or reduce the particle yield compared to the case of two infinitely separated fields. If the travel time for a created electron or positron …
Pair Creation For Bosons In Electric And Magnetic Fields, Q Z. Lv, A C. Su, M Jiang, Rainer Grobe, Qichang Su
Pair Creation For Bosons In Electric And Magnetic Fields, Q Z. Lv, A C. Su, M Jiang, Rainer Grobe, Qichang Su
Faculty publications – Physics
By solving the quantum field theoretical version of the Klein-Gordon equation numerically, we study the creation process for charged boson-antiboson pairs in static electric and magnetic fields. The fields are perpendicular to each other and spatially localized along the same direction, which permits us to study the crucial impact of the magnetic field's spatial extension on dynamics. If its width is comparable to that of the electric field, we find a magnetically induced Lorentz suppression of the pair-creation process. When the width is increased such that the created bosons can revisit the interaction region, we find a region of exponential …