Physical Sciences and Mathematics Commons^™

Fate And Transport Of Toxoplasma Gondii Oocysts In Saturated Porous Media: Effects Of Electrolytes And Natural Organic Matter, Christian Pullano

All Theses

Toxoplasma gondii is a pathogenic microorganism that is currently a threat to public health. Understanding the fate and transport of T. gondii through the soil and groundwater is vital in determining the risk it poses to water resources and human health. The physico-chemical interactions between the groundwater and the bio colloid within an aquifer will dictate its mobility and its ability to infect humans. This research examines how various naturally occurring groundwater chemistries containing organic compounds and monovalent and divalent salt solutions will alter the fate and transport of T. gondii. Solutions containing various concentrations of humic acid, fulvic …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Quantification Of Septic System Contribution To Nutrient Loads In Surface Waters, Archana Tamang

Electronic Thesis and Dissertation Repository

Freshwater systems worldwide are threatened by excessive nutrient (nitrogen and phosphorus) loading. This study evaluated the contribution of septic systems to stream nutrient loads in nine subwatersheds. Stream sampling was conducted during low and high discharge conditions, with samples analyzed for total phosphorus (TP), soluble reactive phosphorus (SRP), nitrate (NO₃-N), and acesulfame (ACE; wastewater tracer). Higher septic effluent reached the subwatershed outlets during high discharge conditions. Subwatersheds with newer households had a lower percentage of septic effluent reaching the stream compared with subwatersheds with older households. Seasonal and event-based ACE concentration-discharge relationships revealed that the hydrological pathways delivering …

The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii

Graduate Theses and Dissertations

Organic matter (OM) in the environment acts as a nutrient, but may also act as a transport vector for harmful chemical compounds and bacteria. Acetate is a labile form of OM produced during fermentation in anaerobic lagoons used to store animal fecal-waste from concentrated animal feeding operations (CAFOs). Dry and liquid fertilizers from CAFOs pose a threat to groundwater by introducing excessive amounts of nutrients (e.g. OM, nitrate and ammonia), metals, and antibiotic compounds. In the epikarst of Northern Arkansas in the Buffalo River watershed additional input of labile dissolved organic carbon (DOC) from liquid CAFO waste-fertilizers was hypothesized to …

Silver Nanoparticle Transport Through Soil: Illuminating The Governing Pore-Scale Processes, Ian L. Molnar

Electronic Thesis and Dissertation Repository

Engineered nanoparticles are widely used and will eventually be released to the subsurface environment and contaminate groundwater resources. However, the transport of engineered nanoparticles through soil is currently not well understood and cannot be modelled in any fundamental manner, placing groundwater resources at risk from nanoparticle contamination. This inability to accurately simulate transport is due to a lack of experimental information on nanoparticle interactions in the pore spaces of real soils.

This thesis illuminates the pore-scale processes governing silver nanoparticle transport through soil. In addition, it examines the influence of surface chemistry and grain/pore distributions on those processes. For the …

An Assessment Of The Emas Pump And Its Potential For Use In Household Water Systems In Uganda, Jacob Daniel Carpenter

USF Tampa Graduate Theses and Dissertations

Rural improved water supply coverage in Uganda has stagnated around 64% for a number of years and at this point more than 10 million rural people do not have access to an improved drinking water source. It has been recognized that progress toward improved water supply coverage and increased service levels may be gained through Government and nongovernmental organization (NGO) support of private investment in household and shared water supplies, commonly known as Self-supply. Self-supply can be promoted by introducing and building local capacity in appropriate and affordable water supply technologies such as hand-dug wells, manually drilled boreholes, low-cost pumps, …

Drinking Water In The Developing World: Sources Of Fecal Contamination In Pitcher Pump Systems And Measurement Alternatives, Meghan Wahlstrom

USF Tampa Graduate Theses and Dissertations

It has been reported that globally we have achieved Millennium Development Goal (MDG) Target 7C, to halve the proportion of the population without access to safe drinking water; however, there is a major flaw with this statement. While Target 7C calls for access to `safe' drinking water, what is actually being measured and reported is access to an `improved' water source. The World Health Organization (WHO) maintains that they must use this proxy measure because the methods for water quality testing are too expensive and logistically complicated, but by doing so, they may be over reporting safe water coverage.

This …

Geochemistry And Inorganic Carbon Transport Of A Glacial Till Drumlin At A Road Salt Facility, Houbao Li

Open Access Dissertations

Investigations were conducted at a salt/premix storage facility lying on top of a glacial drumlin near the coastline in eastern Massachusetts, to characterize salt contaminated groundwater. Groundwater hydrogeochemical variations at different depths were determined based on ten years of monthly or quarterly water quality data from 54 monitoring wells. Groundwater was grouped in three water categories – shallow, middle and deep. Hydrogeochemical characterization indicates that the dominant water types are Na-Cl, Na-Ca-Cl and Ca-HCO3 from the shallow to deep water group. Rock weathering is the dominant hydrogeochemical process for deep water group, whereas salt water percolation and cation exchange control …

Implications Of Surface Runoff Recharge In Semi-Arid Regions On Groundwater Sustainability, Omar M. Al-Qudah

Open Access Theses & Dissertations

Amargosa Desert, Nevada regional groundwater studies show that the surface runoff infiltration occurring in the arroyos following runoff producing storms, and this infiltration is considered to be a major source of groundwater recharge. Groundwater infiltration through alluvium was investigated in the Amargosa Desert using borehole drill cuttings, groundwater chemistry, and applying a novel method for collecting runoff water. The sampling process included sediment, precipitation, and runoff water. In total, 176 runoff, 182 sediment, and 45 precipitation samples were collected between January, 2009 and January, 2011.Water chemistry, chloride concentrations, and stable isotopes of water collected from specially designed runoff samplers, placed …