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Full-Text Articles in Physical Sciences and Mathematics
Evaluation Of A Radium-Thorium Disequilibrium Sediment Method Used To Model And Assess Porewater And Submarine Groundwater Exchange In The Coastal Marsh, Madeline R. Bodine
Evaluation Of A Radium-Thorium Disequilibrium Sediment Method Used To Model And Assess Porewater And Submarine Groundwater Exchange In The Coastal Marsh, Madeline R. Bodine
Theses and Dissertations
Ground, pore, and surface water exchange has been extensively studied in beach and near shore environments but has been long neglected in saltmarsh systems due to their complexity. Saltmarsh systems are of particular importance as they are the interface between fresh and saltwater. Saltmarshes impact carbon exchange, release and sequestration, and they process particulate matter. Understanding the characteristics of a marsh system such as the nutrient and particulate loads in conjunction with the flux of water exchange through the marsh provides a deeper understanding of these systems and can impact our understanding of the global water and carbon cycles, as …
Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly
Masters Theses
Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …
Evaluation Of A Filtration Sorbent For Remediation Of Arsenic In Groundwater, Clement Do
Evaluation Of A Filtration Sorbent For Remediation Of Arsenic In Groundwater, Clement Do
Electronic Theses, Projects, and Dissertations
A commercially available product, PURA PhosLock, was identified and evaluated for use as a sorbent to remove dissolved arsenic (As) from drinking water. Although marketed as a product to remove phosphate in aquaria, it is composed of iron oxide hydroxide (i.e., FeO(OH)), which is also known to adsorb dissolved As species from water. Arsenic was measured using standard methods and Graphite Furnace Atomic Absorption Spectroscopy. A first rough filtration test was performed to see if the PhosLock adsorbed As well. About 50 g of PhosLock was used to filter 10 L of tap water containing 100 ppb As. No detectable …
The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii
The Role Of Organic Matter In The Fate And Transport Of Antibiotic Resistance, Metals, And Nutrients In The Karst Of Northwest Arkansas, Victor Lee Roland Ii
Graduate Theses and Dissertations
Organic matter (OM) in the environment acts as a nutrient, but may also act as a transport vector for harmful chemical compounds and bacteria. Acetate is a labile form of OM produced during fermentation in anaerobic lagoons used to store animal fecal-waste from concentrated animal feeding operations (CAFOs). Dry and liquid fertilizers from CAFOs pose a threat to groundwater by introducing excessive amounts of nutrients (e.g. OM, nitrate and ammonia), metals, and antibiotic compounds. In the epikarst of Northern Arkansas in the Buffalo River watershed additional input of labile dissolved organic carbon (DOC) from liquid CAFO waste-fertilizers was hypothesized to …
A Study Of The Degradative Capabilities Of The Bimetallic System: Mg(Pd/C) As Applied In The Destruction Of Decafluoropentane, An Environmental Contaminant, Douglas Tomlin
Electronic Theses and Dissertations
Pollution from hydrofluorocarbons (HFC) poses a serious challenge to the environmental community. Released from industrial operations, they have contaminated both the atmosphere and groundwater and are considered persistent in both media.1 For over the past 20 years, the practice of synthesizing hydrofluorocarbons as alternatives to chlorofluorocarbons (CFC) has been conducted in an effort to reverse the effects of stratospheric ozone layer depletion. 2,3 However, in doing so these new fluorinated compounds exhibited an unexpected property as a potent global warming greenhouse gas (GHG) with radiative forcing potentials in the range of 100 to 10,000 equivalents greater than carbon dioxide.4 Conversely, …
Investigation Of A Novel Method For Polonium-210 Determination In Groundwater, Tara Matheny
Investigation Of A Novel Method For Polonium-210 Determination In Groundwater, Tara Matheny
All Theses
A novel method was investigated for the quantification of 210Po in water as an alternative to the standard method of spontaneous plating onto Ag disks followed by quantification with an alpha spectrometer. The novel method concentrated a 0.5L sample by MnO2 co-precipitation followed by dissolution of the precipitate into a solution. Polonium-210 was separated from the solution and quantified in a column containing a 50:50 by volume mixture of Pb resin (Eichrom Technologies, Inc.) mixed with granulated CaF2:Eu scintillator. The column containing 210Po is quantified on a liquid scintillation counter without the introduction of liquid cocktail. The minimum detectable concentration …
Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner
Mass Transport Of Volatile Organic Compounds Between The Saturated And Vadose Zones, Monte S. Harner
Theses and Dissertations
Volatile organic compounds (VOCs) dissolved in the saturated zone are transported into the vadose zone primarily by gaseous phase diffusion. If the saturated zone is remediated, VOCs present in the vadose zone may become a secondary source of contamination for the groundwater. The amount of VOCs that remain in the vadose zone is dependent on site hydrology, soil properties, and the chemical properties of the contaminants. The purpose of this study was to determine what conditions caused VOC concentrations in the vadose zone to significantly recontaminate the saturated zone. A one-dimensional numerical model was developed to investigate the transport of …