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Full-Text Articles in Physical Sciences and Mathematics

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly Dec 2021

Influence Of Physical Variability Of Highly Weathered Sedimentary Rock On Nitrate In Area 3 Of The Enigma Field Research Site At Y-12, Erin Kelly

Masters Theses

Uranium processing and waste storage in unlined waste ponds leached contaminants into the groundwater at Y-12, Oak Ridge, Tennessee, from the 1950s to 1980s. Groundwater wells near the S-3 ponds have had the highest nitrate concentrations of groundwater anywhere in the world (>10,000 mg/L). For reference, the maximum contaminant level for nitrate in drinking water set by the U.S. Environmental Protection Agency is 10 mg/L. Since 2012, the ENIGMA (Ecosystems and Networks Integrated with Genes and Molecular Assemblies) group has been characterizing, monitoring, and conducting field experiments to understand the interactions between contaminants, microbes, and the subsurface. The goals …


High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon Aug 2020

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …


Potential Contamination Risk In Tennessee Aquifers From Oil And Gas Drilling, Emma Reed May 2019

Potential Contamination Risk In Tennessee Aquifers From Oil And Gas Drilling, Emma Reed

Chancellor’s Honors Program Projects

No abstract provided.


Memory Response: Exposure History Dependence Of Microbial Mediated Transformations Of Substrates In Groundwater, Charles Joseph Paradis Dec 2017

Memory Response: Exposure History Dependence Of Microbial Mediated Transformations Of Substrates In Groundwater, Charles Joseph Paradis

Doctoral Dissertations

The flow, transport, and reactivity of dissolved-phase constituents in an unconfined and shallow aquifer were characterized, in situ, by utilizing the single-well push-pull test method. In the first study, the re-oxidation/mobility of uranium, in the presence of nitrate oxidant, was shown to be mitigated by preferential oxidation/mobilization of solid-phase, reduced, sulfur-bearing species. These results indicated that establishing conditions conducive to uranium reduction and the formation of reduced sulfur-bearing species can increase the efficacy of sustained uranium reduction/immobility in the presence of re-mobilizing oxidants. In the second study, the analytical solution to describe the one-dimensional displacement of the center of …


Quantifying The Relationship Among Ground Penetrating Radar Reflection Amplitudes, Horizontal Sub-Wavelength Bedrock Fracture Geometries, And Fluid Conductivities, Carolyn Morgan Tewksbury-Christle May 2013

Quantifying The Relationship Among Ground Penetrating Radar Reflection Amplitudes, Horizontal Sub-Wavelength Bedrock Fracture Geometries, And Fluid Conductivities, Carolyn Morgan Tewksbury-Christle

Masters Theses

Accurate characterization of subsurface fractures is indispensible for contaminant transport and fresh water resource modeling because discharge is cubically related to the fracture aperture; thus, minor errors in aperture estimates may yield major errors in a modeled hydrologic response. Ground penetrating radar (GPR) has been successfully used to noninvasively estimate fracture aperture for sub-horizontal fractures at outcrop scale, but limits on vertical and horizontal resolution are a concern. Theoretical formulations and field tests have demonstrated increased GPR amplitude response with the addition of a saline tracer in a sub-millimeter fracture; however, robust verification of existing theoretical equations without an accurate …


Sources And Transport Pathways Of Fecal Bacteria And Pathogens To Aquifers In Rural Bangladesh, Peter S. K. Knappett Aug 2010

Sources And Transport Pathways Of Fecal Bacteria And Pathogens To Aquifers In Rural Bangladesh, Peter S. K. Knappett

Doctoral Dissertations

During the 1980’s millions of households in Bangladesh switched from drinking surface water to private groundwater wells to reduce their exposure to fecal microorganisms. Sadly, this switch to shallow groundwater resulted in the largest example of drinking water poisoning in history, with approximately 100 million people exposed to high concentrations of naturally occurring Arsenic in the groundwater. Spatial distribution of Arsenic in the shallow aquifers tends to be patchy, so the most economical mitigation option has been lateral switching from high Arsenic wells to nearby low Arsenic wells. The recently developed Arsenic flushing conceptual model, which explains the spatial distribution …