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Full-Text Articles in Physical Sciences and Mathematics
Photocycloaddition Of Allenes, Crystal Ward
Photocycloaddition Of Allenes, Crystal Ward
Theses and Dissertations
For the past ten years the Fleming research group has been involved in the research of allene compounds. We have explored the synthesis of allenes as well as several reactions involving allenes, such as oxidation and nitrene addition. Recently, we have explored the synthesis and photochemistry of allenic alcohols tethered to silicon. There are literature examples using allenes in synthesis, but very few examples exist using allenes in photochemical cycloaddition reactions. We have found that a diisopropylallenyloxy(cinnamyloxy)silane derivative undergoes [2+2] photochemical cycloaddition to produce a cyclobutylsilane product when irradiated for 60-75 minutes.
An Investigation Of Communication Patterns And Strategies Between International Teaching Assistants And Undergraduate Students In University-Level Science Labs, Barbara Elas Gourlay
An Investigation Of Communication Patterns And Strategies Between International Teaching Assistants And Undergraduate Students In University-Level Science Labs, Barbara Elas Gourlay
Master's Theses, Dissertations, Graduate Research and Major Papers Overview
Investigates communication between international teaching assistants and their undergraduate students in university-level chemistry labs. Qualitative and quantitative data from observations and interviews with study participants guide the analysis of laboratory interactions, which examines patterns of conversational listening. Results reveal that successful communication depends on teaching assistant listening comprehension skills and on the coordination of verbal and visual (gestural and physical resources) sources of information.
Reactivity Of Ptii "Pincer" Complexes With Carbon Monoxide, Margaret L. Scheuermann
Reactivity Of Ptii "Pincer" Complexes With Carbon Monoxide, Margaret L. Scheuermann
Scripps Senior Theses
ABSTRACT Upon addition of carbon monoxide (CO) to a solution of (k-N, C, N-2, 6-bis(diethylaminomethyl)-phenyl)methyl platinum(II),[NCN]PtMe,(1), a ligand arm is displaced to form [SP-4-2] ((k-N,C-2,6-bis(diethylaminomethyl)-phenyl) carbonmethyl platinum(II), N[CN]Pt(CO)(Me),(2). Addition of CO to a THF solution of 2 results in the formation of [SP-4-3]((k-N,C-2,6-bis(diethylaminomethyl)-phenyl)acylcarbonyl platinum(II),N[CN]pt(Ac)(CO),(3). In THF ,2 partially isomerizes in the presence of CO to form [SP-4-4]((k-N,C-2,6-bis(diethylaminomethyl)-phenyl)carbonylmethyl platinum(II), N[CN]Pt(Me)(CO).(2’).in equilibrium with 2(K=ca.2 at 100 degree celcius). In the absence of CO, only trace isomerization was observed. Thermolysis of 3 results in the formation of 2 and 2’ , while a reaction of 3 with trimethylamine N-oxide results exclusively in the …
Solution Processible Aromatic Polyimides Via Diels Alder Precursor, Saral Shah
Solution Processible Aromatic Polyimides Via Diels Alder Precursor, Saral Shah
Electronic Theses and Dissertations
Aromatic polyimides are interesting materials since they possess outstanding key properties such as thermoxidative stability, high mechanical strength, high modulus, excellent electrical properties, and superior chemical resistance. However, their low solubility makes them difficult to characterize, process and obtain high molecular weight polymer. In this report, we synthesized a series of precursor polymers that contains Diels-Alder (DA) adducts of anthracene. Different dienophiles were tried. These precursor polymers are soluble in common organic solvents such as chloroform and can be easily processed to thin films. Heating the film above 215 degree induce retro-DA reaction, which generated the fully aromatic polyimides in …