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Full-Text Articles in Physical Sciences and Mathematics
The Enzymatic Oxidation Of Aldehydes By Xanthine Oxidase, Duane Beal Gregory
The Enzymatic Oxidation Of Aldehydes By Xanthine Oxidase, Duane Beal Gregory
All Master's Theses
As early as sixty years ago, the existence of an enzyme from mammalian tissues which catalyzed the oxidation of xanthine and hypoxanthine was recognized. The name given the enzyme was derived from its earliest recognized action, hence xanthine oxidase. Although little is known about the biological functions of the enzyme, the high affinity shown for xanthine and hypoxanthine may indicate that these are the most significant substrates biologically.
High Pressure Spectral Chemistry Of Selected Organic Compounds, Frank William Linsley
High Pressure Spectral Chemistry Of Selected Organic Compounds, Frank William Linsley
Theses and Dissertations
The series of compounds indicated by the formular C_6H_5-(CH=CH)n-C_6H_5 change in color from white (colorless) to yellow to orange to red to deep red as n increases from 1 to 12. Stilbene is the first compound of this series (n=1). Under pressure, exerted by a diamond anvil press, stilbene can be seen to change color from white to yellow to red as increasing pressure is applied. Similar color changes are observed for the compounds where n=2,3, and 4 when subjected to similar pressure. This study records and reports the spectra versus pressure for these compounds.
Acid-Base Catalysis Of The Enolization Of Acetone, Janet Louise Larson
Acid-Base Catalysis Of The Enolization Of Acetone, Janet Louise Larson
Undergraduate Honors Theses
Measurements are reported on the rate of iodination of acetone at 25°c in arsenate, phosphate, and diethylmalonic acid buffers at a constant ionic strength of 0.2. Unlike earlier results which indicate that in acetic acid buffer the expression for the reaction velocity contains an appreciable kinetic term involving the product of the concentrations of acid and anion, it has been found from the present work that such a term is experimentally immeasurable for the above mentioned buffers. This finding coupled with the relatively powerful catalysis by the phosphate and arsenate dianions could imply the simultaneous participation of these species in …