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Full-Text Articles in Physical Sciences and Mathematics
Steric Effects On The Formation Of Manganese Oxide Clusters And 2-Dimensional Ammonium Formate Architectures, Carl Oberle
Steric Effects On The Formation Of Manganese Oxide Clusters And 2-Dimensional Ammonium Formate Architectures, Carl Oberle
Dissertations
It has been demonstrated by the Beatty group that altering the identity of the ortho-substituent of a dianiline counterion affects the assembly and dimensionality of a cadmium-chloride layer from 2-D to 0-D. This work seeks to extend this finding to metal oxide and organic hydrogen-bonded materials. By systematically increasing the ortho-substituent’s size on the benzoate building block of reported manganese oxide clusters, of formula MnxOy(O2C-R)zLw (where R = Alkyl, L = neutral monodentate ligand), we aim to impact the self-assembly of these materials relative to their parent …
Cadmium Chloride Dimensionality Changes From Ortho-Substituted Anilines, Stephanie Cernicek
Cadmium Chloride Dimensionality Changes From Ortho-Substituted Anilines, Stephanie Cernicek
Dissertations
Inorganic-organic hybrid metal halide materials have been of great interest recently due to the useful properties offered by such a combination. The inorganic portions usually consisting of MX62- subunits, (M = Pb, Sn, Cd, Cu; X = Cl, Br, I) most often form 2-D perovskite layers where the metals are bridged by corner sharing halides. The organic portion, usually consisting of primary amines or anilines provides a template for the inorganic framework and in some cases, dictates the dimensionality (2-D, 1-D, 0-D) of the network. These materials have various applications in host-guest chemistry catalysis, and gas storage, or …
Nanocarbon Immobilized Membrane For Separation And Analysis, Madhuleena Bhadra
Nanocarbon Immobilized Membrane For Separation And Analysis, Madhuleena Bhadra
Dissertations
Membrane processes classically cover a wide range of applications associated with various aspects of separation and purification. Over the last few years, membrane based processes have received much interest due to their compact and modular architecture, low energy consumption and cost effective separation. With the development of diverse nanomaterials which can serve as nanosorbents, or provide specific morphology for selective solute transport, recent years have witnessed the emergence of nanocarbon based membranes that can address some of the limitations of conventional membrane processes and make feasible the next generation of breakthroughs.
The objective of this research is the exploration of …
Low Temperature Spectroscopic And Annealing Studies Of Disordered Organic Solids, Dwayne L. Labrake
Low Temperature Spectroscopic And Annealing Studies Of Disordered Organic Solids, Dwayne L. Labrake
Dissertations
No abstract provided.
Spin Label Studies Of Radical Reduction In Normal And Sickle Erythrocyte Membranes Associated With Antioxidants, Yin Zhang
Dissertations
No abstract provided.
Remote Dianions In The Synthesis Of Indolizidine Alkaloids, Diana L. C. Green Green
Remote Dianions In The Synthesis Of Indolizidine Alkaloids, Diana L. C. Green Green
Dissertations
No abstract provided.