Physical Sciences and Mathematics Commons^™

Acetylacetone Oxidation At Room Temperature: A Multiplexed Photoionization Mass Spectrometric Investigation, Study Of The Russell Intermediates In Gas Phase Reactions, And The Investigation Of Oxidation Reaction Products Of Ethanol At Room Temperature, Sara Gallarati

Master's Theses

This thesis presents the combustion study of acetyl acetone using synchrotron radiation coupled with multiplexed photoionization mass spectrometry at 298 K. The experiments were performed at the Chemical Dynamics Beamline 9.0.2 at the Advanced Light Source of the Lawrence Berkeley National Laboratory. The reaction of acetyl acetone with chlorine (Cl) radicals was analyzed based on their photoionization spectra and reaction kinetic profiles.

Additionally, a study of the Russell intermediate has been performed. Previous to experimentation at the Advanced Light Source, computational analysis has been investigated to evaluate compounds that could possibly lead to the formation of a stable species. The …

Infiltration-Controlled Combustion Of Lithium And Magnesium Powders And Reactions Of Lithium With Oxygen And Carbon Dioxide, Kevin Samuel Estala Rodriguez

Open Access Theses & Dissertations

Chemical heat integrated power systems are of great interest for space missions where solar energy, nuclear energy, and batteries are not available or are not practical to use. A new concept of a power system is a metal combustor coupled with a chemical oxygen generator, where the generated oxygen infiltrates through the metal powder or combustion products. The combustion of lithium and magnesium powders under these conditions has not been studied yet. The present work investigates combustion of magnesium powder and stabilized lithium metal powder (SLMP) ignited by a laser inside a closed chamber filled with O2 or CO2. It …

Characterization Of A Flex-Fuel Oxy-Combustion System Through Experimental Investigation And Computational Modeling, Md Mohieminul I. Khan

Open Access Theses & Dissertations

Oxy-fuel combustion has the potential to offer high thermal efficiency and lower pollutants emission compared to other existing combustion technologies. More than 63% of the worldâ??s electricity is produced by fossil fuel combustion which also is the major reason for greenhouse gas emissions. Oxy combustion offers a solution to it. Oxy combustion uses pure oxygen as an oxidizer instead of air which eliminates the NOx and SOx products from the exhaust. In oxy-combustion flue gas mainly consists of CO2 and water vapor. Furthermore, combustion in presence of pure oxygen results in higher flame temperature and hence promises higher thermal efficiency. …

Direct Simulation And Reduced-Order Modeling Of Premixed Flame Response To Acoustic Modulation, Zheng Qiao

Theses and Dissertations

This dissertation introduces a general, predictive and cost-efficient reduced-order modeling (ROM) technique for characterization of flame response under acoustic modulation. The model is built upon the kinematic flame model–G-equation to describe the flame topology and dynamics, and the novelties of the ROM lie in i) a procedure to create the compatible base flow that can reproduce the correct flame geometry and ii) the use of a physically-consistent acoustic modulation field for the characterization of flame response. This ROM addresses the significant limitations of the classical kinematic model, which is only applicable to simple flame configurations and relies on ad-hoc models …